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Abstrak :
ABSTRAK
Biogas diproduksi dari limbah cair kelapa sawit dengan proses digesting anaerob memiliki kadar CH4 dan CO2 masing-masing sebesar ± 86,2% dan ± 13,8 %. Pengotor pada biogas yaitu CO2 perlu dihilangkan, karena dapat menurunkan nilai kalor pada biogas dan bersifat korosif. Metode simultan absorpsi dan adsorpsi dipilih pada penelitian ini. Absorpsi menggunakan larutan Ca(OH)2 0,0619 M dan adsorpsi menggunakan dua kolom unggun tetap dan zeolit klinoptilolit termodifikasi sebagai adsorben. Zeolit Klinoptilolit dimodifikasi struktur dan luas permukaannya dengan menggunakan HCl (2M), NaOH (2M), kalsinasi pada suhu 450 oC dan pelapisan kitosan 0,5% (b/v). Karakterisasi adsorben dilakukan dengan analisis XRD, FTIR, SEM-EDX dan analisis permukaan dan porositas dengan BET dan analisis biogas dengan GC dan GC-MS. Efektivitas penyerapan CO2 dengan metode simultan absorpsi-adsorpsi dua kolom didapatkan sebesar 82,5% dengan waktu jenuh pada menit ke-30. Adsorben diregenerasi didapatkan hasil efektivitas penyerapan CO2 sebesar 74,3% dengan menggunakan NaOH 1,5 M dan pemanasan pada suhu 200oC.

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ABSTRACT
Biogas produced from palm oil mill effluent by digesting anaerobic contains of CH4 and CO2 each ± 86,2% and ± 13,8 %. Biogas purified necessary to remove impurity, that CO2 can reduce calorie value of biogas and corrosive. In this research biogas purified using simultaneous absorption-adsorption method because simply and applicative. Absorption using Ca(OH)2 0,0619 M and adsorption method using two fixed bed column and zeolite clinoptilolite as adsorbent. Structure and surface area of zeolite clinoptilolite can be modified using strong acid and strong base with concentration each 2 M, calcination at 450 oC and coated chitosan 0,5 %. Adsorbent characterization by XRD, FTIR, SEM-EDX, surface area and porosity analyse with BET and biogas analyse using GC and GC-MS.. Research result found 82,5% CO2 adsorption effectiveness of using simultaneous absorption-adsorption double column method with saturated time at 30 minute. Adsorbent can be regenerated founded CO2 adsorption effectiveness 74,3% with using NaOH 1,5 M and 200oC.

Abstrak :
ABSTRACT
Zeolite Clinoptilolite from Lampung, located in South of Sumatra, had been modified with surfactant hexadecyltrimethylammonium bromide (HDTMA-Br) as chromate anion exchanger. Surfactant modified zeolite (SMZ) Clinoptilolite in particle size range of 1.5 - 2.0 mm, which contained 196.7 mmol HDTMA-Br/kg zeolite, was used for anion exchange of chromate at neutral pH. This experiment was conducted in a glass column filled with 5 gram SMZ. The breakthrough chromate exchange capacity was found 1.262 mg/g SMZ, while the total capacity was found 2.107 mg/g SMZ. The regeneration of SMZ saturated with chromate was conducted using a mixed solutions of 0.28 M Na2CO3 and 0.5 M NaOH, compared with using a solution of 0.01 M Na2S2O4. The desorption of chromate achieved 92% with the mixed solutions of Na2CO3 and NaOH and 90% with the Na2S2O4 solution. The regenerated SMZ with Na2CO3-NaOH solutions was prior washed with HCl solution to remove the carbonate from SMZ, before being used for chromate sorption again. Its breakthrough capacity was reduced to 1.074 mg/g SMZ, and to 0.724 mg/g SMZ when regenerated with Na2S2O4 solution. These results indicated that regeneration of SMZ affected its exchange capacity for anion chromate. However, it is still could be acceptable, when Na2CO3/NaOH solutions were used for the regeneration of SMZ saturated with anion chromate.