Artikel Jurnal :: Kembali

Artikel Jurnal :: Kembali

Anion exchange capacity of chromate on modified zeolite clinoptilolite with HDTMA-Br and its regeneration

by Widajanti Wibowo, Tresye Utari and Rika Tri Yunarti (Direktorat Riset dan Pengabdian Masyarakat Universitas Indonesia, 2011)

 Abstrak

Zeolite Clinoptilolite from Lampung, located in South of Sumatra, had been modified with surfactant hexadecyltrimethylammonium bromide (HDTMA-Br) as chromate anion exchanger. Surfactant modified zeolite (SMZ) Clinoptilolite in particle size range of 1.5 - 2.0 mm, which contained 196.7 mmol HDTMA-Br/kg zeolite, was used for anion exchange of chromate at neutral pH. This experiment was conducted in a glass column filled with 5 gram SMZ. The breakthrough chromate exchange capacity was found 1.262 mg/g SMZ, while the total capacity was found 2.107 mg/g SMZ. The regeneration of SMZ saturated with chromate was conducted using a mixed solutions of 0.28 M Na2CO3 and 0.5 M NaOH, compared with using a solution of 0.01 M Na2S2O4. The desorption of chromate achieved 92% with the mixed solutions of Na2CO3 and NaOH and 90% with the Na2S2O4 solution. The regenerated SMZ with Na2CO3-NaOH solutions was prior washed with HCl solution to remove the carbonate from SMZ, before being used for chromate sorption again. Its breakthrough capacity was reduced to 1.074 mg/g SMZ, and to 0.724 mg/g SMZ when regenerated with Na2S2O4 solution. These results indicated that regeneration of SMZ affected its exchange capacity for anion chromate. However, it is still could be acceptable, when Na2CO3/NaOH solutions were used for the regeneration of SMZ saturated with anion chromate.

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Jenis Koleksi : Artikel Jurnal
No. Panggil : AJ-Pdf
Entri utama-Nama orang :
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Penerbitan : Depok: Direktorat Riset dan Pengabdian Masyarakat Universitas Indonesia, 2011
Sumber Pengatalogan : LibUI eng rda
ISSN : 23391995
Majalah/Jurnal : Makara : Sains
Volume : Vol.15, No.1, April 2011: hal.53-57
Tipe Konten : text
Tipe Media : unmediated
Tipe Carrier : volume
Akses Elektronik : http://journal.ui.ac.id/index.php/science/article/view/878/837
Institusi Pemilik : Universitas Indonesia
Lokasi : Direktorat Riset dan Pengabdian Masyarakat UI
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