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Abstrak :
In 2016, the mandatory use of biodiesel as a substitute fuel by up to 20%, as introduced by the Indonesian Ministry of Energy and Mineral Resources, forced vehicle manufacturers to invent suitable engines that would accept biodiesel. The use of biodiesel in such a large proportion is highly risky, particularly due to the formation of deposits in the combustion chamber engines. The previous method of fuel droplets are placed on a hot plate approach produces deposits are slightly different from those generated by a real engine, therefore to obtain realistic deposits it is necessary to modify this method so temperatures as hot as those in a real engine. In this study, the potential deposit formation of biodiesel fuel was examined by conducting the deposition process and the evaporation of fuel on a stainless-steel plate (SS), which was placed in a closed space. Deposit characterization was carried out on a hot plate using Scanning Electron Microscopy (SEM). The test results showed differences in the structures of the deposits produced by biodiesel and diesel fuel; fine structures were seen in the former, while those of the latter were rougher and more porous. Deposit results that are similar to what is seen in a real engine will be very helpful for knowing the patterns, structures, and mechanism of the formation of deposits in such an environment.

Abstrak :
In 2016, the mandatory use of biodiesel as a substitute fuel by up to 20%, as introduced by the Indonesian Ministry of Energy and Mineral Resources, forced vehicle manufacturers to invent suitable engines that would accept biodiesel. The use of biodiesel in such a large proportion is highly risky, particularly due to the formation of deposits in the combustion chamber engines. The previous method of fuel droplets are placed on a hot plate approach produces deposits are slightly different from those generated by a real engine, therefore to obtain realistic deposits it is necessary to modify this method so temperatures as hot as those in a real engine. In this study, the potential deposit formation of biodiesel fuel was examined by conducting the deposition process and the evaporation of fuel on a stainless-steel plate (SS), which was placed in a closed space. Deposit characterization was carried out on a hot plate using Scanning Electron Microscopy (SEM). The test results showed differences in the structures of the deposits produced by biodiesel and diesel fuel; fine structures were seen in the former, while those of the latter were rougher and more porous. Deposit results that are similar to what is seen in a real engine will be very helpful for knowing the patterns, structures, and mechanism of the formation of deposits in such an environment.

Abstrak :
Pada penelitian ini, dilakukan pengujian untuk mengetahui pembentukan deposit bahan bakar B20 yang saat ini sedang beredar di masyarakat berdasarkan instruksi Pemerintah. Dengan banyaknya sumber daya alam Indonesia yang bisa dimanfaatkan, dilakukan pengujian minyak atsiri yang dimanfaatkan sebagai zat aditif untuk mengetahui bagaimana potensinya dalam melakukan proses deformasi atau pelepasan deposit yang terjadi pada pengujian dengan tetes bahan bakar pada plat panas di hot room temperature test rig dengan kondisi temperatur yang mendekati kondisi yang sesungguhnya di dalam engine. Bioaditif yang digunakan diharapkan dapat mengubah struktur kimiawi bahan bakar guna membantu mempercepat laju pelepasan deposit pada plat panas. Penelitian ini bertujuan untuk melihat berapa konsentrasi optimal zat aditif untuk bekerja dengan baik. Terlihat dari hasil pengujian bahwa penambahan konsentrasi aditif yang paling rendah, yaitu pada konsentrasi 1 : 5.000 memberikan hasil yang paling baik dibanding dengan konsentrasi yang lebih pekat. Pada pengujian ini juga dapat dilihat adanya potensi proses pelepasan deposit pada pengujian yang menggunakan tambahan bioaditif. ......In this research, a test to determine the formation of deposits resulted by the usage of B20 biodiesel fuel that is currently circulating in Indonesia based on Government instructions. With the abundance of Indonesia 39 s natural resources that can be utilized, an essential oil test is utilized as an additive to know how its potential in performing deformation process or deposit release that occurs in testing by using fuel drop method on hot plate in hot room temperature test rig at temperature condition which is close to the real conditions inside the engine. Bioadditives used are expected to change the chemical structure of the fuel to help accelerate the rate of release of deposits on hot plate. This study aims to see how the optimal concentration of additives to work well. It can be seen from the test that the addition of the lowest additive concentration, ie at a concentration of 1 5,000, gives the best result compared to the concentrated concentration. In this test can also be seen the potential for the process of release of deposits on tests that use additional bioadditives.

Abstrak :
Pada penelitian ini, dilakukan pengujian untuk mengetahui pembentukan deposit bahan bakar B20 yang saat ini sedang beredar di masyarakat berdasarkan instruksi Pemerintah. Dengan banyaknya sumber daya alam Indonesia yang bisa dimanfaatkan, dilakukan pengujian minyak atsiri yang dimanfaatkan sebagai zat aditif untuk mengetahui bagaimana potensinya dalam melakukan proses deformasi atau pelepasan deposit yang terjadi pada pengujian dengan tetes bahan bakar pada plat panas di hot room temperature test rig dengan kondisi temperatur yang mendekati kondisi yang sesungguhnya di dalam engine. Bioaditif yang digunakan diharapkan dapat mengubah struktur kimiawi bahan bakar guna membantu mempercepat laju pelepasan deposit pada plat panas. Penelitian ini bertujuan untuk melihat berapa konsentrasi optimal zat aditif untuk bekerja dengan baik. Terlihat dari hasil pengujian bahwa penambahan konsentrasi aditif yang paling rendah, yaitu pada konsentrasi 1 : 5.000 memberikan hasil yang paling baik dibanding dengan konsentrasi yang lebih pekat. Pada pengujian ini juga dapat dilihat adanya potensi proses pelepasan deposit pada pengujian yang menggunakan tambahan bioaditif. ......In this research, a test to determine the formation of deposits resulted by the usage of B20 biodiesel fuel that is currently circulating in Indonesia based on Government instructions. With the abundance of Indonesia 39 s natural resources that can be utilized, an essential oil test is utilized as an additive to know how its potential in performing deformation process or deposit release that occurs in testing by using fuel drop method on hot plate in hot room temperature test rig at temperature condition which is close to the real conditions inside the engine. Bioadditives used are expected to change the chemical structure of the fuel to help accelerate the rate of release of deposits on hot plate. This study aims to see how the optimal concentration of additives to work well. It can be seen from the test that the addition of the lowest additive concentration, ie at a concentration of 1 5,000, gives the best result compared to the concentrated concentration. In this test can also be seen the potential for the process of release of deposits on tests that use additional bioadditives.

Abstrak :

Peningkatan populasi manusia yang bertambah setiap tahunnya, maka kebutuhkan energi pun meningkat di seluruh dunia. Hal tersebut akan berdampak pada ketersediaan energi yang menurun, salah satunya adalah bahan bakar. Diperlukan bahan bakar alternatif sebagai solusi dari masalah tersebut. Pemerintah telah mendorong penggunaan biodiesel sebagai bahan bakar alternatif dengan dikeluarkannya Peratunan Menteri Energi dan Sumber Daya Mineral No. 12/2015. Pada tahun 2020, telah ditetapkan bahwa penggunaan Biodiesel 30% (B30) menjadi mandat dari konsumsi energi nasional pada semua sektor. Namun, penggunaan biodiesel masih memiliki masalah terhadap ketahanan degradasi oksidatif selama penyimpanan. Penyimpanan bahan bakar dalam waktu lama dapat menyebabkan degradasi sifat bahan bakar yang mempengaruhi kualitas biodiesel itu sendiri. Studi dilakukan untuk menganalisa pengaruh penyimpanan biodiesel B30 terhadap pembentukan deposit. Sampel bahan bakar pada penelitian ini disimpan dalam tangki berbahan stainless steel selama 3 bulan. Variasi Storage Condition adalah : (1) Relative Humidity (RH) Tinggi, (2) RH Sedang, (3) RH Rendah. Pada penelitian ini dilakukan dengan metode tetes plat panas untuk mengetahui karakteristik pertumbuhan deposit pada masing-masing variasi kondisi penyimpanan bahan bakar yang diukur setiap bulan. Penelitian dilakukan dengan proses deposisi bahan bakar Diesel yang dilakukan secara berulang pada sebuah pelat panas. Pelat dipanaskan dengan variasi temperatur di dalam ruang tertutup, sehingga kondisinya hampir menyerupai kondisi pada titik-titik penting dalam sebuah mesin pembakaran dalam pada umumnya. Hasil studi menunjukan dalam periode 3 bulan pada kondisi penyimpanan RH Tinggi mengalami peningkatan massa deposit, sedangkan pada kondisi penyimpanan RH Sedang dan RH Rendah mengalami penurunan massa deposit. Jumlah massa deposit dipengaruhi oleh asam organik yang dihasilkan dari proses oksidasi berdasarkan hasil uji FTIR.

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As the human population increases each year, the need for energy increases throughout the world. This will have an impact on decreased energy reserves, one of which is fuel. Alternative fuels are needed as a solution to the problem. The government has launched the use of biodiesel as an alternative fuel by issuing Minister of Energy and Mineral Resources Regulation No. 12/2015. In 2020, the use of Biodiesel 30% (B30) has been determined to be the mandate of national energy consumption for all sectors. However, the use of biodiesel still has problems with oxidative degradation resistance during storage. Storage of fuel for a long time can cause degradation of the nature of the fuel which affects the quality of biodiesel itself. A study was conducted to analyze the storage condition effect on B30 biodiesel deposit formation. Fuel samples in this study were stored in stainless steel tanks for 3 months. Storage Conditions Variations are: (1) Relative Humidity (RH) High, (2) Medium RH, (3) Low RH. This research was carried out with hot plate drop method to determine the characteristics of deposit growth in each variation of fuel storage, mass deposits data were collected every month. The study was conducted with the process of deposition of diesel fuel which is done repeatedly on a hot plate. Plates are heated with variations in temperature in a closed room, so that conditions are easier depending on the important temperature points in the manufacture of machines in general. The study results show that in a period of 3 months the storage conditions of High RH condition shows an increased deposit masses, whereas in storage conditions Medium RH and Low RH shows a decreased deposit masses. The amount of mass of the deposit is influenced by organic acids produced from the oxidation process based on the results of the FTIR test.

Abstrak :
Pada penelitian ini, pembentukan deposit dari biodiesel B20-NA dengan penambahan Bioaditif Atsiri dengan variasi berbeda, yaitu B20 Atsiri 1:2000, B20 Atsiri 1:3000, B20 Atsiri 1:4000 dan B20 Atsiri 1:5000 yang dilakukan dengan metode tetes plat panas untuk mengetahui karakteristik dan mekanisme pembentukan deposit pada masing-masing variasi bahan bakar. Penelitikan dilakukan dengan proses deposisi dan evaporasi bahan bakar Diesel yang dilakukan secara berulang pada sebuah pelat panas. Pelat dipanaskan dengan variasi temperatur di dalam ruang tertutup sehingga kondisinya mendekati kondisi riil pada engine. Pengujian ini menggunakan hot chamber test rig. Penggunan bioaditif essential oil atsiri yang memiliki kandungan terpentin berperan mengikat kadar air dan residu pada bahan bakar biodiesel diharapkan dapat mempercepat proses terjadinya pelepasan deposit yang berlebih didalam ruang bakar. Penelitian ini bertujuan untuk menemukan variasi bahan bakar dan temperatur yang optimal agar proses pelepasan deposit dapat dipercepat. ......In this study, the deposit formation of B20 NA biodiesel with the addition of bioadditive Essential Oil with different variations, B20 Essential Oil 1 2000, B20 Essential Oil 1 3000, B20 Essential Oil 1 4000 and B20 Essential Oil 1 5000 method of hot plate drops to know the characteristics and mechanisms of deposit formation on each variation of fuel. The research is carried out by the deposition process and evaporation of Diesel fuels carried out repeatedly on a hot plate. The plate is heated with temperature variations inside the enclosed space so that the conditions are close to the real conditions of the engine. This test uses a hot chamber test rig. The use of bioadditive essential oils atsiri which have turpentine contents bind water content and residues in biodiesel fuel is expected to accelerate the process of excessive deposit release in the combustion chamber. This study aims to find the optimum fuel and temperature variations so that the deposit release process can be accelerated.

Abstrak :
ABSTRAK
Pada penelitian ini, pembentukan deposit dari biodiesel dengan variasi berbeda, yaitu B100, B100-NA dan B100-NAP dilakukan dengan metode tetes plat panas untuk mengetahui karakteristik dan mekanisme pembentukan deposit pada masing-masing variasi bahan bakar. Penelitikan dilakukan dengan proses deposisi dan evaporasi bahan bakar Diesel yang dilakukan secara berulang pada sebuah pelat panas. Pelat dipanaskan dengan variasi temperatur di dalam ruang tertutup sehingga kondisinya mendekati kondisi riil pada engine. Pengujian ini menggunakan hot room temperature test rig. Dengan perlakuan oksidasi yang berbeda pada B100, diharapkan dapat ditemukan perbedaan pembentukan deposit sehingga dapat melakukan kajian lebih lanjut untuk mengendalikan pembentukan deposit. Penelitian ini bertujuan untuk menemukan temperatur yang optimal agar pertumbuhan deposit dapat dikendalikan.

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ABSTRACT
In this study, forming of deposits from biodiesel with different variation, that are B100, B100 NA, and B100 NAP will be observed with hot surface plate methode to find their characteristics and growth mechanisms of deposits from every biodiesel variation. Repetitive process of diesel fuel deposition and evaporation on hot plate are done in this study. The plate was heated at various temperature in closed systems for approaching the real engine condition. This process was done in hot room temperature test rig. With different treatment of B100, distinction of deposit from each fuel can be found, so a more in depth studies can be conduct. The purpose of this research is to find optimum temperature in order to control the growth of deposit furnace.

Abstrak :
ABSTRAK
Pada penelitian ini, pembentukan deposit dari biodiesel dengan variasi berbeda, yaitu B100-NA, B100 BHT dan B100 PG dilakukan dengan metode tetes plat panas untuk mengetahui karakteristik dan mekanisme pembentukan deposit pada masing-masing variasi bahan bakar. Penelitikan dilakukan dengan proses deposisi dan evaporasi bahan bakar Diesel yang dilakukan secara berulang pada sebuah pelat panas. Pelat dipanaskan dengan variasi temperatur di dalam ruang tertutup sehingga kondisinya mendekati kondisi riil pada engine. Pengujian ini menggunakan hot room temperature test rig. Penggunan antioksidan dalam menghambat oksidasi pada biodiesel diharapkan dapat menjaga bilangan asam agar tetap rendah dan meningkatkan stabilitas oksidasi, dimana akan membantu dalam terjadinya pembentukan deposit yang berlebih didalam ruang bakar. Penelitian ini bertujuan untuk menemukan temperatur yang optimal agar pertumbuhan deposit dapat dikendalikan.

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ABSTRACT
This study, forming of deposits from biodiesel with different variation, that are B100 NA, B100 BHT, and B100 PG will be observed with hot surface plate methode to find their characteristics and growth mechanisms of deposits from every biodiesel variation. Repetitive process of diesel fuel deposition and evaporation on hot plate are done in this study. The plate was heated at various temperature in closed systems for approaching the real engine condition. This process was done in hot room temperature test rig. The addition of antioxidant in biodiesel to be expected for slowing the biodiesel from oxidation, so the acid number of biodiesel doesn rsquo t increase and increase oxidation stability, and it will be help for deposit for not over growing inside of combustion chamber. This research program was created to finding the optimum temperatur in order to decrease of deposits in combustion chamber.

Abstrak :
Penelitian ini dilakukan dengan proses deposisi dan evaporasi bahan bakar diesel yang dilakukan secara berulang pada sebuah pelat panas. Pelat dipanaskan dengan variasi temperatur di dalam ruang tertutup sehingga kondisinya mendekati kondisi riil pada engine. Pengujian ini menggunakan hot room temperature test rig. Dari pengujian ini, pengaruh temperatur terhadap pertumbuhan dan karakteristik deposit dapat diamati. Penelitian ini lebih mengarah ke jumlah deposit. Jumlah deposit yang berbeda di setiap temperatur dapat menunjukkan temperatur yang optimal untuk mengendalikan pertumbuhan deposit. ......Repetitive process of diesel fuel deposition and evaporation on hot plate are done in this study. The plate was heated at various temperature in closed systems for approaching the real engine condition. This process was done in hot room temperature test rig. Effect of temperature to deposits growth and characteristic could be observed through this repetitive process. Then, the aim of this study is more likely to total deposits. Total deposits structure at every temperature could show the optimum temperature to control the deposits growth.

Abstrak :
Pada penelitian ini, pembentukan deposit dari biodiesel dengan variasi biodiesel yang berbeda, yaitu B20-NA, B20 Bioaditif 1:2000, B20 Bioaditif 1:3000, B20 Bioaditif 1:4000, dan B20 Bioaditif 1:5000 dilakukan dengan metode tetes plat panas untuk mengetahui karakteristik dan mekanisme pembentukan deposit pada masing-masing variasi bahan bakar. Penelitikan dilakukan dengan proses deposisi bahan bakar Diesel yang dilakukan secara berulang pada sebuah pelat panas pada hot room temperature test rig dengan variasi suhu 250oC, 300oC, 350oC di dalam ruang ruang tertutup agar merepresentasikan kondisi nyata pada engine. Penambahan bioaditif diharapkan dapat mengubah struktur kimia bahan bakar untuk mempercepat laju pelepasan deposit pada plat panas. Penelitian ini bertujuan untuk menemukan konsentrasi optimal bioaditif terhadap bahan bakar B20 untuk bekerja dengan baik. ......This research investigated the characterization and formation mechanisms of biodiesel deposit with variations on bioadditive additions by hot plate drip method. Samples were prepared using B20 biodiesel fuel with variations of aetheric oil based bioadditive in 1 2000, 1 3000, 1 4000, and 1 5000 additive to base fuel ratio. The diesel fuel was deposited repetitively on heated plates in a hot temperature test rig with temperatures varied from 250oC, 300oC, 350oC to represent actual operational environment inside an engine. Bioadditive additions is predicted to alter the chemical structure of the biodiesel fuel, hence accelerating its deposition rate on heated plates. Optimal bioadditive concentration to enhance operating performance of B20 fuel is expected as an outcome.