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Abstrak :
Material magnet NdFeB banyak diketahui sebagai magnet permanen yang memiliki sifat magnetik yang superior ditandai dengan tingginya nilai saturasi magnetik dari bahan magnet tersebut. Namun pada bahan NdFeB memiliki nilai koersivitas yang dapat dipengaruhi fasa dari bahan, sehingga material NdFeB berpotensi digunakan sebagai material penyerap gelombang radar jika nilai koersivitas nya sekecil mungkin. Pada penelitian ini dibuat material Nd15-xFe77+xB8 (X= 0, 2 dan 5) dengan perbedaan waktu milling pada material selama 1, 3, 5 jam dan pemberian perlakuan panas terkontrol agar terjadi oksidasi parsial. Pasca pemberian perlakuan panas terkontrol, diperoleh hasil bahwa material Nd15-xFe77+xB8 dengan nilai x = 0, 2 dan 5 memiliki fasa campuran antara fasa magnetik Nd2Fe14B dan -Fe. , pada bahan yang telah diberikan perlakuan panas mengalami dekomposisi ditandai pada hasil XRD terdapat banyak unsur besi. Fasa tersebut sangat berpengaruh pada daya absorbsi bahan, untuk bahan sebelum diberi perlakuan panas akan menyerap gelombang radar sangat baik dengan nilai reflection loss maksimum sebesar 25,10 dB yaitu 94,44% gelombang radar diserap oleh bahan sedangkan pada bahan yang telah mengalami perlakuan panas menyerap gelombang radar sebesar 12,60 dB atau 76,56% gelombang radar diserap oleh bahan. Selain pada fasa semakin lama waktu milling membuat daya serap menjadi semakin baik. Maka dapat disimpulkan bahwa material NdFeB memiliki potensi untuk menjadi material penyerap gelombang radar. ......NdFeB magnetic material is widely known as a permanent magnet which has superior magnetic properties characterized by the high magnetic saturation value. However, NdFeB material has a coercivity value that can be influenced by phase of the material, so that NdFeB material has the potential to be used as a radar wave absorbing material if the coercivity value is as small as possible. In this study, the material Nd15-xFe77+xB8 (X= 0, 2 and 5) was made with a difference in milling time of 1, 3, 5 hours and controlled heat treatment to allow partial oxidation to occur. After giving controlled heat treatment, it was found that the material Nd15-xFe77+xB8 with values of x = 0, 2 and 5 had a mixed phase between the magnetic phase of Nd2Fe14B and α-Fe. , the material that has been given heat treatment experience decomposition marked on the XRD results there are lots of iron elements. This phase greatly affects the absorption of the material, for the material before being heat treated it will absorb radar waves very well with a maximum reflection loss value of 25.10 dB, which is 94.44% of the radar waves are absorbed by the material, while the material that has undergone heat treatment absorbs 12.60 dB or 76.56% of radar waves are absorbed by the material. In addition to the phase, the longer the milling time makes the absorption better. So it can be concluded that the NdFeB material has the potential to become a radar wave absorbing material.

Abstrak :
Series of Ti2+-Mn4+ ions substituted BaFe12-2xTixMnxO19 samples with x = 0.0–0.8 have been studied to find out the effect of ion substitution on their microstructure, magnetic, and microwave absorption characteristics. The materials were synthesized through the mechanical alloying process. X-ray diffraction pattern for all sintered samples confirmed that the materials are single phase materials with BaFe12O19 structure. Referring to the results, it is shown that all samples that are subject to ultrasonic irradiation treatment characterized by a crystallite size distribution with the width get slimmer and mean crystallite size get smaller as the substitution level increased from x = 0 to x = 0.8. A sample of latter composition has fine crystals between 10–200 nm with the mean size of 42 nm. The effect of ionic substitution also affected the magnetic properties in which coercivity decreased proportionally with an increase of x value. The saturation magnetization increased to 0.41 T at x = 0.4, and then decreased for higher x values. Hence, the increase occurred only in samples with low-level substitutions of Ti2+-Mn4+ ions. Microwave absorption characterization clearly shows that the reflection loss (RL) value of Ti2+-Mn4+ substituted BaFe12-2xTixMnxO19 samples was enhanced from 2.5 dB in a doped free sample (x = 0) to 22 dB (~92% absorption) in a sample with x = 0.6 in the frequency range 8–12 GHz.

Abstrak :
Material stronsium heksaferit memiliki karakteristik yang unik, diantaranya nilai temperature curie Tc sebesar 737K/463°C, nilai konstanta magnetokristain anisotropi K = 3,6 × 102 erg.cm-3, nilai koersivitas JHc = 444,5 kA/m, nilai magnetisasi remanen Mr sebesar 0,245 T dan nilai saturasi magnetisasinya Ms = 0,475 T. Investigasi terbaru pada SrFe11.9In0.1O19 telah menunjukkan nilai ratio antara magnetisasi remanen dan magnetisasi saturasi yang lebih besar dari 0,5, dimana penggunaannnya tepat untuk magnet permanen isotropik. Dalam penelitian ini, material SrFe12-xInxO19 (x = 0,05; 0,10; 0,20; dan 0,50) dengan nilai magnetisasi remanen tertinggi dimodifikasi dengan substitusi Fe+3 terhadap material SrFe11.9In0.1O19 dengan ion Mn dan Ti untuk mengurangi nilai koersivitasnya sehingga tepat untuk digunakan sebagai material absorber. Material magnetik dengan komposisi SrFe11,9-yMny/2Tiy/2In0,1O19 (y = 0; 0,30; 0,60; 1,00 dan 1,20) telah dibuat dengan proses mechanical alloying. Loop histeresis untuk sampel SrFe11,9-yMny/2Tiy/2In0,1O19 menunjukkan bahwa koersivitas berkurang secara progresif dari 292,6 kA/m untuk y = 0 menjadi 90,23 kA/m untuk y = 1,2 dengan nilai magnetisasi remanen yag cenderung konstan. Nilai reflection loss (RL) material penyerap ini terus bertambah besar seiring dengan meningkatnya fraksi ion subsitusi Mn+2 dan Ti+4 hingga mencapai nilai RL tertinggi didapatkan pada y = 1,20 yaitu sebesar 40,23 dB pada frekuensi 11,162 GHz. Dengan nilai RL tersebut gelombang elektromagnetik yang masuk kedalam material dapat diserap hingga mencapai lebih dari 99 % dan hanya kurang dari 1 % intensitas gelombang yang datang direfleksikan kembali. ......Strontium hexaferrite has attracted much attentions due to its unique properties with a large value of curie temperature Tc = 737K, a large magnetocrystalline anisotropy constant K = 3.6 x 106 erg.cm-3, a high coercivity value JHc = 444,5 kA/m, high remanent (Mr) and saturation magnetization (Ms) of 0,245 T and 0.475 T respectively. A recent investigation on In substituted SrFe11.9In0.1O19 has shown excellent remanence to the saturation magnetization ratio value of much greater than 0.5 which most suitable for isotropic permanent magnets. In this work, SrFe12-xInxO19 (x = 0.05; 0.10; 0.20; and 0.50) with the highest value of remanent magnetization was modified by the co-substitution of Fe+3 in SrFe11.9In0.1O19 with Mn+2 and Ti+4 ions to reduce the coercivity which is suitable for radar absorbing applications. A series of magnetic material with SrFe11.9-yMny/2Tiy/2In0,1O19 (y = 0; 0.30; 0.60; 1.00 and 1.20) compositions were prepared by mechanical alloying process. The hysteresis loop for SrFe11.9-yMny/2Tiy/2In0.1O19 samples showed that the coercivity was progressively reduced from 292.6 kA/m for y = 0 to 90.23 kA/m for y = 1.2 with the remanence remained significantly un-changed. The reflection loss (RL) value of such materials continues to increase along with the increase of Mn+2 and Ti+4 fraction until the highest RL value of 40.23 dB at a frequency of 11.162 GHz was obtained at y = 1.20. With this RL value, the electromagnetic waves that enter the material can be absorbed up to more than 99% and only less than 1% of the intensity of the incoming waves is reflected.

Abstrak :
Telah dilakukan karakterisasi parameter kristal, sifat kemagnetan dan serapan gelombang mikro pada material berbasis lanthanum-strontium manganite komposisi La1-xSrxMnO3 (x=0-1) serta efek subsitusi parsial ion Fe dan Ti pada material komposisi La0.7Sr0.3Mn1-yFey/2Tiy/2O3 (y = 0-1). Preparasi material dilaksanakan melalui metode pemaduan mekanik diikuti dengan sintering pada temperatur 1100C selama 2 jam. Hasil pengujian dengan XRD terhadap material pasca perlakuan sintering memastikan material terdiri dari fasa kristalin. Diketahui bahwa ion Sr tidak dapat mensubsitusi ion La sepenuhnya pada senyawa komposisi La1-xSrxMnO3 dengan batas kelarutan x = 0.3 tanpa terjadi perubahan sistem kristal dan fasa tunggal. Substitusi ion Fe terhadap ion Mn pada senyawa komposisi La0.7Sr0.3Mn1-yFeyO3 (y=0-1) tidak menyebabkan perubahan struktur kristal yaiu tetap berstruktur monoklinik dikarenakan jari-jari ion Fe3+(6.4 nm) dan Mn4+ (5.4 nm) tidak jauh berbeda. Namun, tidak demikian dengan efek subsitusi parsial ion Ti4+ pada komposisi La0.7Sr0.3Mn1-yTiyO3 (y=0-0.8) ditandai dengan perubahan struktur kristal monoklinik pada y = 0 menjadi orthorombik pada komposisi 0 0.5 material memiliki fasa kedua yang mengindikasikan terdapatnya batas maksimum fraksi ion Ti4+ (jari-jari 6.05 nm) menggantikan ion Mn4+. Efek subsitusi parsial ion Fe, Ti serta subsitusi bersama ion Fe dan Ti terhadap ion Mn menyebabkan perubahan struktur magnetik dari keteraturan ferromagnetik menjadi paramagnetik melalui suatu mekanisme interaksi pertukaran spin elektron. Perubahan sifat kemagnetan material ini diketahui dari loop hysteresis magnet melalui evaluasi menggunakan perangkat permeameter. Senyawa material berbasis lanthanum strontium manganite berbagai komposisi yang menjadi objek penelitian ini semua memiliki kemampuan menyerap gelombang elektromagnetik paling tidak pada jangkauan frekuensi 9–15 GHz yang diketahui berdasarkan analisis hasil pengujian dengan vector network analysis atau VNA. Hasil evaluasi menunjukkan material fasa tunggal komposisi La0.7Sr0.3Fe0.2Mn0.4Ti0.4O3 dengan ketebalan 2.05 mm dan bersifat paramagnetik memiliki nilai return loss maksimum sebesar -9.13 dB atau mampu menyerap gelombang mikro sebesar 65.05% pada frekuensi 10.9 GHz dan lebar frekuensi penyerapan optimum sebesar 4 GHz. ......Crystal parameter as well as magnetic properties and microwave absorption characteristics of material based on lanthanum-strontium manganese with La1- xSrxMnO3 (x = 0-1) compositions have been characterized. These are including the effects of partial substitution of Fe ions in La0.7Sr0.3Mn1-yFey/2Tiy/2O3 (y=0-1) series. Material preparation was carried out through mechanical alloying method followed by sintering at a temperature of 1100 0C for 2 hours. Identification study of x-rays traces for sintered materials ensured that all materials consisted of crystalline phases. It is shown that Sr ion can completely substitutes La ion in the La1-xSrxMnO3 (x = 0.3) compositions with no change in the crystal system and remains as single phase materials. Similarly, there was also no crystal structure changing observed when Fe ion substituted the Mn ion in the La0.7Sr0.3Mn1-yFeyO3 (y=0-1) compositions. Apparently, the crystal structure was maintained due to almost similar size of ionic radii between Fe3+ (6.4 nm) and Mn4+ (5.4 nm). However, a different case occurred in Ti substituted La0.7Sr0.3Mn1-yTiyO3 (y=0-0.8) in which the crystal structure of monoclinic for y = 0 changed to orthorhombic for 0 0.5 which indicated that there must be a maximum ionic fraction limit of Ti4+ in replacing Mn4+ due to larger ionic radii (6.05 nm) than that of Mn4+. It was also found that substitution of respectively Fe and Ti ions in La0.7Sr0.3Mn1- y(Fe,Ti)yO3 (y=0-1) series as well as co-substitution of Fe and Ti ions for Mn in La0.7Sr0.3Mn1yFey/2Tiy/2O3 series have lead to the magnetic structure changing from ferromagnetic order to paramagnetic through a mechanism of electron spin exchange interactions. The change in magnetic structure was seen from the hysteresis loop obtained by means of permeameter measurement. The lanthanum-strontium manganese-based materials of various compositions which were the objects of this study have shown the ability to absorb electromagnetic waves at least in the frequency range of 9-15 GHz. This was confirmed by results of analysis based on vector network analyzer (VNA). It is concluded that a paramagnetic single-phase material of La0.7Sr0.3Fe0.2Mn0.4Ti0.4O3 composition with 2.05 mm thickness has a maximum return loss value of 9.13 dB, which capable to absorb 65.05% of incident microwaves intensity at a frequency 10.9 GHz with the absorption width was 4 GHz.