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Abstrak :
Telah dilakukan sintesis bahan perovskite manganites La1-xAgx 0,8Ca0,2MnO3 yang disubtitusi dengan Ag pada site La dengan x = 0; 0,03; 0,07; 0,1; 0,2; 0,3; 04 dan 0,5. Pembuatan sampel dilakukan dengan metode sol-gel pada temperatur sintering 900 C. Prekursor yang digunakan adalah La2O3, AgNO3, Ca NO3 2.6H2O dan Mn NO3 2.4H2O. Hasil karakterisasi XRD untuk x < 0,1 menunjukkan fasa tunggal dengan struktur kristal orthorombik dan space group pnma. Pada x = 0,2; 0,3 dan 0,4 terdapat puncak Ag dan x = 0,5 terdapat puncak Ag, Ca dan nitrat. Pengujian nilai efek magnetoresistan di fokuskan pada x < 0,1. Ukuran rata-rata grain dari hasil karakterisasi SEM pada sampel yaitu dalam skala nanometer. Hasil kemurnian sampel telah dikonfirmasi menggunakan karektersasi EDX, dimana tidak terdapat pengotor atau impuritas. Hasil karakterisasi VSM menunjukkan bahwa nilai koersivitas semakin meningkat dengan meningkatnya doping Ag, nilai tertinggi HC = 234 Oe dengan sifat soft magnetik. Nilai optimum MR = 61,5 pada x = 0,07, temperatur 50 K di bawah pengaruh medan magnet luar sebesar 2T.

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The synthesis of perovskite manganites La1 xAgx 0.8Ca0,2MnO3 was substituted with Ag on La site with x 0 0.03 0.07 0.1 0.2 0.3 04 and 0.5. Sample preparation was done by sol gel method at sintering temperature 900 C. The precursors are La2O3, AgNO3, Ca NO3 2.6H2O and Mn NO3 2.4H2O. The XRD characterization results for x 0.1 showed a single phase with orthorombic crystal structure and pnma space group. There is Ag peak at x 0.2 0.3 and 0.4 and at x 0.5 there are Ag and Ca peaks. The magnetoresistance effect value test was focused on x 0.1. The average size of grain from SEM characterization results in the sample is in the nanometer scale. The results of the purity of the sample have comfirmed using EDX characterization. VSM characterization results showed that coercivity value increases with increasing Ag doping, the highest value of Hc 234 Oe with soft magnetic properties. The optimum value of MR 61,5 at x 0.07, temperature 50 K under the influence of the external magnetic field of 2T.

Abstrak :
Pada zaman sekarang perkembangan teknologi berkembang pesat. Adanya modifikasi material perovskite berbasis manganit telah diteliti untuk diterapkan pada Colossal Magnetoresistance. Penelitian yang telah dilakukan mengenai struktur mikro dan sifat magnetik material perovskite manganites La0.67Sr0.33Mn1-xZnxO3 (x= 0; 0,15; 0,2; 0,4) yang disintesis dengan metode solid state bertujuan untuk melihat pengaruh yang ditimbulkan Zn pada material La0.67Sr0.33Mn1-xZnxO3 (x= 0; 0,15; 0,2; 0,4) berupa struktur morfologi dan sifat kemagnetannya. Karakterisasi XRD menunjukan bahwa struktur kristal material berbentuk rhombohedral pada space group R-3c dengan rata-rata ukuran kristal 106 nm, 103 nm, 101 nm dan 96 nm. Karakterisasi SEM dan EDS menunjukan perubahan ukuran grain dan memperlihatkan keberadaan unsur Zn sebagai pendoping. Ukuran grain mengecil seiring bertambahnya konsentrasi Zn dengan rata-rata ukuran grain 148 nm, 134 nm, 127 nm dan 117 nm. Karakterisasi VSM menunjukan kurva histeresis yang memperlihatkan material bersifat feromagnetik ketika 0 ≤ x < 0,2 dan berubah menjadi paramagnetik ketika x > 0,2 yang terlihat dengan menurunnya nilai magnetisasi dari 65,1 emu/gram, 14,4 emu/gram, 8,2 emu/gram dan 1,7 emu/gram. ......In this day and age, technological development is developing rapidly. The existence of modifications to manganese-based perovskite materials has been studied to be applied to Colossal Magnetoresistance. Research that has been conducted on the microstructure and magnetic properties of manganites perovskite material La0,67Sr0,33Mn1-xZnxO3 (x= 0; 0.15; 0.2; 0.4) synthesized by the solidstate method aims to see the influence that Zn has on the material La0,67Sr0,33Mn1-xZnxO3 (x= 0; 0.15; 0.2; 0.4) in the form of morphological structure and magnetisme properties. XRD characterization shows that the crystal structure of rhombohedral-shaped materials in the R-3c space group with an average crystal size of 106 nm, 103 nm, 101 nm and 96 nm. SEM and EDS characterizations show a change in grain size and show the presence of Zn elements as doping. Grain size decreases as Zn concentration increases with average grain sizes of 148 nm, 134 nm, 127 nm and 117 nm. VSM characterization shows a hysteresis curve that shows the material is ferromagnetic when 0 ≤ x < 0.2 and turns paramagnetic when x > 0.2 which is seen by decreasing the magnetization value of 65.1 emu/gram, 14.4 emu/gram, 8.2 emu/gram and 1.7 emu/gram.

Abstrak :
Telah dilakukan penelitian sifat listrik, sifat magnet, dan efek magnetoresistan bahan perovskite manganites La0,67Sr0,33Mn1-XNixO3. Sampel dibuat dengan metode sol gel. Hasil karakterisasi XRD menunjukkan bahwa sampel sudah memiliki fase tunggal dengan struktur rhombohedral dan space group R-3c. Pemberian doping Ni tidak mengubah struktur kristal namun menurunkan nilai parameter kisi kristal. Karakterisasi SEM-EDX menunjukkan bahwa unsur Ni sudah masuk ke dalam sampel dan adanya perubahan morfologi sampel ketika doping Ni divariasikan. Data resistivitas sebagai fungsi temperatur menunjukkan bahwa doping Ni meningkatkan besar resistivitas bahan dan menggeser temperatur transisi metal-isolator ke temperatur yang lebih rendah. Efek magnetoresistan yang diberikan menunjukkan adanya peningkatan persen magnetoresistan saat doping Ni dinaikkan. Sedangkan kurva histerisis yang dihasilkan menunjukkan bahwa pemberian doping Ni menurunkan sifat kemagnetan bahan yang ditunjukkan oleh penurunan magnetisasi bahan.

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The electrical properties, magnetic properties, and magnetoresistance effect of perovskite manganites La0,67Sr0,33Mn1-XNixO3 material have been studied. Samples were synthesized by using sol gel method. The result of XRD characterization showed that samples were single phase with Rhombohedral structure and R-3c space group. Ni doped did not change crystal structure but decreased lattice parameter. SEM-EDX characterization showed that Ni was included in the samples as a doping and the morphology of samples changed with various Ni doped. Resistivity as temperature function showed that Ni doped increased the resistivity and decreased the metal-insulator transition temperature. Magnetoresistance effect of samples relatively enhanced with increased of Ni doping. While the hysteresis curve from VSM characterization showed that Ni doped decreased magnetic properties of samples.

Abstrak :
Modern technology for refrigerators and coolers is based on the chemical gas Chlorofluorocarbon (CFC) compression method that is indicative of a high consumption of electricity. The CFC is also understood as a reason for global warming. One of the solutions to this issue is magnetic refrigeration technology, which is environmentally friendly because it does not use any hazardous chemicals or ozone depleting/greenhouse gases. Magnetic refrigeration technology is based on the magnetocaloric effect of magnetic refrigerant materials. Exploring the magnetocaloric effect of magnetic refrigerant materials is important because these contain many of the physical properties needed for magnetic refrigeration technology. Herein, the present work reports on the magnetocaloric effect of La0.7Ca0.3Mn1?xSnxO3 (x = 0.0, x = 0.02 and x = 0.04) compound samples produced with the solid state reaction technique. Curie temperature TC obtained for the La0.7Ca0.3Mn1?xSnxO3 (x = 0.0, x = 0.02 and x = 0.04) are 260 K, 176 K and 170 K with -?SM max of 4.32 J×kg-1×K-1, 1.61 J×kg-1×K-1 and 1.24 J×kg-1×K-1 and a refrigerant capacity of 48 J/kg, 41.43 J/kg and 28.53 J/kg for x = 0.0, x = 0.02 and x = 0.04, respectively. A small addition of Sn-doped resulted in a significant decrease of more than 80 K on the Curie temperature scale compared to that of La0.7Ca0.3MnO3. The large gap in the decreasing magnetic temperature phase transition might be useful as an option of metal/transition metal doped for tuning the Curie temperature of magnetic refrigerant materials.