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Ditemukan 6 dokumen yang sesuai dengan query
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Davin Philo
2012
LP-pdf
UI - Laporan Penelitian  Universitas Indonesia Library
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Moh. Azhar
Abstrak :
[ABSTRAK
Telah dilakukan penelitian pembuatan beton ringan atau lightweight concrete (LWC) menggunakan batu apug (BA) dan abu sekam padi (ASP). Sampel beton ringan yang dibuat mengandung BA dengan fraksi berbeda, adapun material semen, pasir, dan abu sekam padi volumenya dijaga tetap. Terdapat dua parameter utama yang menentukan sifat mekanik sampel LWC masing-masing adalah densitas sampel dan rasio air/semen (w/c). Sifat mekanik yang paling utama dari LWC adalah kekuatan tekan. Pada campuran dengan fraksi volume batu apung terbesar (100%) menghasilkan densitas dan kekuatan tekan paling rendah masing-masing sebesar (1389,6 kg/m3 dan 11,1 MPa). Diketahui bahwa makin rendah fraksi batu apung dalam sampel beton makin tinggi nilai densitas dan kekuatan tekannya, disebabkan oleh tingginya nilai fraksi pori baik pori terbuka maupun pori tertutup dalam sampel beton. Observasi terhadap fotomikro SEM batu apung menunjukkan bahwa terdapat sejumlah besar pori dengan bentuk memanjang ke bagian dalam dari permukaan sampel beton. Pori hadir dengan kerapatan jumlah pori relatif besar serta dengan ukuran yang bervariasi. Fakta ini menjelaskan mengapa batu apung besifat ringan karena memiliki densitas massa yang rendah. Pola difraksi sinar X sampel beton ringan memperlihatkan dominasi fasa kristalin diidentifikasi sebagai fasa quartz (SiO2). Namun dapat dipastikan sampel beton ringan terdiri dari fasa campuran antara fasa kristalin dan dengan sedikit fasa amorph. Fotomikro SEM beton ringan menunjukkan bahwa senyawa Kalsium Silikat Hidrat (CSH) mulai tumbuh pada waktu awal proses hidrasi dan terus berkembang sampai umur beton mencapai umur hidrasi 28 hari yang ditandai dengan sifat fisik yang padat dan peningkatan kekuatan beton. Dapat dipastikan bahwa senyawa CSH ini memiliki peranan penting terhadap pengaturan sifat mekanik seperti kekuatan tekan. Penelitian ini menyimpulkan bahwa batu apung dan abu sekam padi adalah material berbasis silika amorph yang memiliki densitas lebih rendah terutama dibandingkan dengan material pembentuk beton lainnya. Baik densitas dan kekuatan tekan sampel beton ringan ditentukan oleh rasio antara batu apung dan abu sekam padi. Ditemukan rasio terkecil BA/ASP yaitu 8 menghasilkan nilai densitas dan kekuatan tekan optimal, masing-masing pada usia beton 28 hari sebesar 1891 kg/m3 dan 23 MPa. Komposisi beton ringan yang terbaik diperoleh dari hasil penelitian ini adalah komposisi campuran PCC (1,00) : Pasir (1,00) : ASP (0,05) : BA (0,50) dengan nilai Slump 8 cm ditandai oleh nilai rasio antara kuat tekan dan densitas tertinggi adalah 1285.;
ABSTRACT
Research studies on the manufacture of lightweight concrete (LWC) using pumice and rice husk ash (RHA) materials have been done. LWC samples were made of pumice materials with a different mass fraction, while the cement, sand, and rice husk ash materials were keep fixed. It was found that there are two main parameters that determine the mechanical properties of LWC which are density and the water and cement ratio (w/c ratio). The main mechanical properties of LWC sample is the power press. Samples with the largest volume fraction of pumice (100%) resulted in lightest density (1389.6 kg/m3) and the smallest strength of LWC (11.1 MPa). It was found that, the lower the mass fraction of pumice in LWC samples, the higher the density values and compressive strength were obtained. This was caused by the high mas fraction value of pores, which were both open and closed pores. Scanning electron micorscopy (SEM) images for the pumice showed that the there are a large number of regular and structured pores extending deep inside the surface of the sample. It was observed that pores present with pore size does not vary significantly but with the density of the relatively large number of pores, indicating pumice has a low mass density. The XRD pattern of the lightweight concrete samples indicated that the samples were dominated by crystalline phases in which the quartz (SiO2) is the main phase and a small fraction of amorphous phase was also obtained. SEM images of lightweight concrete samples showed that the structure of Calcium Silicate Hydrates (CSH) started growing at the beginning of hydration time and continue to evolve into a more solid structure until the age of 28 days, where the compound has an important role to the mechanical properties such as compressive strength. The study concluded that the pumice and rice husk ash is are amorphous silica-based material which has a lower density compared to other concrete forming material such as cement and sands. Both density and light weight concrete compressive strength are determined by the ratio between pumice and rice husk ash, in which the smallest ratio 8 resulted in the largest density and compressive strength, which are 1890.5 kg/m3 and 23.2 MPa respectively at the age of 28 days. The study concluded that the best composition for lightweight concrete samples was the following: PCC (1,00): Sand (1,00): ASP (0,05): BA (0,50) with a slump value of 8 cm resulted in the largest value of a ratio between compressive strength and density of 1285.;Research studies on the manufacture of lightweight concrete (LWC) using pumice and rice husk ash (RHA) materials have been done. LWC samples were made of pumice materials with a different mass fraction, while the cement, sand, and rice husk ash materials were keep fixed. It was found that there are two main parameters that determine the mechanical properties of LWC which are density and the water and cement ratio (w/c ratio). The main mechanical properties of LWC sample is the power press. Samples with the largest volume fraction of pumice (100%) resulted in lightest density (1389.6 kg/m3) and the smallest strength of LWC (11.1 MPa). It was found that, the lower the mass fraction of pumice in LWC samples, the higher the density values and compressive strength were obtained. This was caused by the high mas fraction value of pores, which were both open and closed pores. Scanning electron micorscopy (SEM) images for the pumice showed that the there are a large number of regular and structured pores extending deep inside the surface of the sample. It was observed that pores present with pore size does not vary significantly but with the density of the relatively large number of pores, indicating pumice has a low mass density. The XRD pattern of the lightweight concrete samples indicated that the samples were dominated by crystalline phases in which the quartz (SiO2) is the main phase and a small fraction of amorphous phase was also obtained. SEM images of lightweight concrete samples showed that the structure of Calcium Silicate Hydrates (CSH) started growing at the beginning of hydration time and continue to evolve into a more solid structure until the age of 28 days, where the compound has an important role to the mechanical properties such as compressive strength. The study concluded that the pumice and rice husk ash is are amorphous silica-based material which has a lower density compared to other concrete forming material such as cement and sands. Both density and light weight concrete compressive strength are determined by the ratio between pumice and rice husk ash, in which the smallest ratio 8 resulted in the largest density and compressive strength, which are 1890.5 kg/m3 and 23.2 MPa respectively at the age of 28 days. The study concluded that the best composition for lightweight concrete samples was the following: PCC (1,00): Sand (1,00): ASP (0,05): BA (0,50) with a slump value of 8 cm resulted in the largest value of a ratio between compressive strength and density of 1285., Research studies on the manufacture of lightweight concrete (LWC) using pumice and rice husk ash (RHA) materials have been done. LWC samples were made of pumice materials with a different mass fraction, while the cement, sand, and rice husk ash materials were keep fixed. It was found that there are two main parameters that determine the mechanical properties of LWC which are density and the water and cement ratio (w/c ratio). The main mechanical properties of LWC sample is the power press. Samples with the largest volume fraction of pumice (100%) resulted in lightest density (1389.6 kg/m3) and the smallest strength of LWC (11.1 MPa). It was found that, the lower the mass fraction of pumice in LWC samples, the higher the density values and compressive strength were obtained. This was caused by the high mas fraction value of pores, which were both open and closed pores. Scanning electron micorscopy (SEM) images for the pumice showed that the there are a large number of regular and structured pores extending deep inside the surface of the sample. It was observed that pores present with pore size does not vary significantly but with the density of the relatively large number of pores, indicating pumice has a low mass density. The XRD pattern of the lightweight concrete samples indicated that the samples were dominated by crystalline phases in which the quartz (SiO2) is the main phase and a small fraction of amorphous phase was also obtained. SEM images of lightweight concrete samples showed that the structure of Calcium Silicate Hydrates (CSH) started growing at the beginning of hydration time and continue to evolve into a more solid structure until the age of 28 days, where the compound has an important role to the mechanical properties such as compressive strength. The study concluded that the pumice and rice husk ash is are amorphous silica-based material which has a lower density compared to other concrete forming material such as cement and sands. Both density and light weight concrete compressive strength are determined by the ratio between pumice and rice husk ash, in which the smallest ratio 8 resulted in the largest density and compressive strength, which are 1890.5 kg/m3 and 23.2 MPa respectively at the age of 28 days. The study concluded that the best composition for lightweight concrete samples was the following: PCC (1,00): Sand (1,00): ASP (0,05): BA (0,50) with a slump value of 8 cm resulted in the largest value of a ratio between compressive strength and density of 1285.]
2015
D2054
UI - Disertasi Membership  Universitas Indonesia Library
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Imam Hidayat Nurwahid
Abstrak :
Pemanfaatan bahan yang berlimpah di alam sebagai bahan baku alternatif yang lebih ekonomis dan dapat pula mengurangi limbah padat yang dihasilkan oleh berbagai industri dengan mengubahnya menjadi produk yang bermanfaat. Pada penelitian ini, dilakukan ekstraksi SiO2 dari ampas tebu dan batu apung dengan menggunakan metode ekstraksi alkali suhu rendah dan proses presipitasi asam. SiO2 yang telah diekstraksi kemudian dikarakterisasi menggunakan X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), dan Ultraviolet/Visible Diffuse Reflectance Spectroscopy (UV/VIS DRS). Hasil yang diperoleh menunjukkan bahwa SiO2 telah berhasil diekstraksi dari ampas tebu dan batu apung dengan tingkat kemurnian yang tinggi, yang dikonfirmasi oleh hasil XRF (98,4% dan 96,3%). Data karakterisasi XRD dan FTIR mengkonfirmasi bahwa hasil ekstraksi SiO2 memiliki struktur amorf dan terdapat gugus siloksan dan silanol. Ukuran partikel SiO2 hasil ekstraksi dari ampas tebu dan batu apung adalah 4,95 nm dan 6,19 nm. Modifikasi SiO2 dilakukan dengan penambahan logam perak untuk membentuk katalis Ag2O/SiO2. Hasil modifikasi dikarakterisasi menggunakan XRD, FTIR, SEM, Transmission Electron Microscopy (TEM), dan UV/VIS DRS. Katalis yang telah disintesis digunakan dalam aplikasi reduksi 4-nitrophenol (4-NP) yang menunjukkan bahwa waktu yang diperlukan untuk mereduksi 4-NP dengan katalis Ag2O/SiO2 dari batu apung lebih cepat dibandingkan dengan katalis Ag2O/SiO2 dari ampas tebu. Aktivitas katalitiknya yang diamati menggunakan spektroskopi UV/VIS (Ultraviolet/Visible) dan dihasilkan bahwa katalis Ag2O/SiO2 dari batu apung lebih baik daripada katalis Ag2O/SiO2 dari ampas tebu. ...... Utilization of materials that are abundant in nature as an alternative raw material that is more economical and can also reduce solid waste generated by various industries by turning it into a useful product. In this study, SiO2 was extracted from sugarcane bagasse and pumice stone by using a low-temperature alkaline extraction method and acid precipitation process. The extracted SiO2 was then characterized using X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), and Ultraviolet/Visible Diffuse Reflectance Spectroscopy (UV/VIS DRS). The results obtained showed that SiO2 was successfully extracted from sugarcane bagasse and pumice stone with high purity, which was confirmed by XRF results (98.4% and 96.3%). The XRD and FTIR characterization data confirm that the extraction of SiO2 has an amorphous structure and has siloxane and silanol groups. The particle size of SiO2 extracted from sugarcane bagasse and pumice stone is 4.95 nm and 6.19 nm. Modification of SiO2 is done by adding silver metal to form Ag2O/SiO2 catalyst. The modification results were characterized using XRD, FTIR, SEM, Transmission Electron Microscopy (TEM), and UV/VIS DRS. The synthesized catalyst is used in the 4-nitrophenol (4-NP) reduction which shows that the time needed to reduce 4-NP with Ag2O/SiO2 catalyst from pumice stone is faster than Ag2O/SiO2 catalyst from sugarcane bagasse. The catalytic activity was observed using UV/VIS (Ultraviolet/Visible) spectroscopy and it was found that the Ag2O/SiO2 catalyst from pumice stone was better than the Ag2O/SiO2 catalyst from sugarcane bagasse.
Depok: Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Indonesia, 2020
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UI - Skripsi Membership  Universitas Indonesia Library
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Sigit Pranowo Hadiwardoyo
Depok: Fakultas Teknik Universitas Indonesia, 1993
LP-pdf
UI - Laporan Penelitian  Universitas Indonesia Library
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Catur Nitya Vinaya Natawidha
Abstrak :
ABSTRAK
Pengaruh fotokatalis komposit berbasis TiO2 dan batu apung dalam mendegradasi senyawa Linear Alkilbenzena Sulfonat (LAS) telah diinvestigasi. Prekursor yang digunakan adalah TiO2 P25 yang diberi dopan C dan CuO serta penggunaan batu apung sebagai penyangga. Penelitian ini mencakup variasi dopan, komposisi CuO, perbedaan sumber foton, dan waktu degradasi agar didapat fotokatalis yang aktif serta bekerja optimal untuk degradasi LAS. Konsentrasi LAS sesudah degradasi dianalisis dengan Spektrofotometer UV-Vis dengan metode MBAS (Methtylene Blue Active Substance). Hasil analisis menunjukkan fotokatalis 1%CuO-TiO2 adalah fotokatalis dengan komposisi CuO yang paling optimal dengan tingkat degradasi lebih dari 94% setelah 20 menit reaksi menggunakan sinar UV-A. Dopan C mampu meningkatkan aktivitas TiO2 di bawah sinar tampak dengan tingkat degradasi lebih dari 85% setelah 20 menit reaksi menggunakan lampu merkuri sebagai sumber foton.
ABSTRACT
Effects of composite photocatalysts based on TiO2 and pumice stone for degradation of Linear Alkylbenzene Sulfonate (LAS) compound had been investigated in this research. The precursor was TiO2 P25 doped by carbon and CuO and also used pumice stone as support. This research investigated dope variation, CuO composition, different photon source, and degradation time to get photocatalyst which are active and give optimum work for degradation of Linear Alkylbenzene Sulfonate. The concentration of Linear Alkylbenzene Sulfonate after degradation was analyzed by UV-Vis Spectrophotometre with MBAS (Methtylene Blue Active Substance) method. The results showed that 1%CuOTiO2 photocatalyst is the most optimum CuO doped photocatalyst with degradation degree was more than 94% after 20 minutes reaction with UV-A light. C doped could enhance TiO2 actvity under visible light with degradation degree was more than 85% after 20 minutes reaction with mercury lamp.
Depok: Fakultas Teknik Universitas Indonesia, 2012
S43758
UI - Skripsi Open  Universitas Indonesia Library