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Abstrak :
Kemampuan inhibitor Triazine dalam menginhibisi baja karbon API-5L X60 dalam lingkungan NaCl 3.5% diinvestigasi dengan menggunakan metode Polarisasi Linier Linier Polarization Resistance (LPR) dalam berbagai variasi konsentrasi. Konsentrasi yang digunakan pada penelitian kali ini adalah 0 ppm, 50 ppm, 10 ppm, 150 ppm, 200 ppm, dan 250 ppm. Hasil pengujian menunjukkan bahwa konsentrasi optimum dalam menurunkan laju korosi terdapat pada 150 ppm dengan laju korosi sebesar 0,4457841 mm/year, sedangkan nilai Rp terus meningkat dan optimum pada konsentrasi 250 ppm dengan nilai sebesar 838,85 Ohm. Kurva laju korosi vs konsentrasi inhibitor menunjukkan bahwa konsentrasi optimum inhibitor Triazine dalam menurunkan laju korosi terdapat pada konsentrasi 150 ppm. Efisiensi terbesar terdapat pada konsentrasi 150 ppm dengan nilai 63,94% dan berdasarkan Rp nilai efisiensi optimum pada konsentrasi 250 ppm dengan nilai sebesar 55,16%. Kinerja inhibitor pada pengujian ini masih kurang baik karena masih jauh dari efisiensi inhibitor yang baik yaitu rentang nilai 85-90%. ......The performance of Triazine based commercial corrosion inhibitor on carbon stel API 5L X60 on NaCl 3.5 % solution was investigated using Linear Polarization Resistance Method or LPR. The Inhibitor concentration that used in this experiment were 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm, and 250 ppm. Experimental results showed that the optimum concentration to decrease the corrosion rate is 150 ppm with the corrosion rate in 0,4457841 mm/year , while the optimum polarization resistance is 838,85 Ohm at 250 ppm. The plot of corrosion rate vs inhibitor concentration show the optimum Triazine inhibitor concentration for decreasing corrosion rate is 150 ppm. There optimum efficiency at a concentration of 150 ppm of 63.94 % and Rp optimum efficiency at a concentration of 250 ppm of 55.16 % . Inhibitor performance is still not good because it is still far from a good inhibitor efficiency is 85-90 % range of values.

Abstrak :
[ABSTRAK Kemampuan inhibitor Triazine dalam menginhibisi baja karbon API 5L X60 dalam lingkungan NaCl 3.5% diinvestigasi dengan menggunakan metode Polarisasi Tafel dalam berbagai variasi konsentrasi. Konsentrasi yang digunakan pada penelitian kali ini adalah 0 ppm, 50 ppm, 10 ppm, 150 ppm, 200 ppm, dan 250 ppm. Efisiensi optimum yang didapatkan adalah sebesar 50.28% dengan konsentrasi inhibitor triazine sebesar 150 ppm. Dengan pengujian FTIR, maka dibuktikan bahwa senyawa triazine mampu menginhibisi permukaan baja API 5L X60. Penelitian ini juga membuktikan bahwa inhibitor triazine merupakan inhibitor korosi karena mampu menurunkan laju korosi.Inhibitor triazine termasuk kedalam jenis inhibitor campuran.

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ABSTRACT The corrosion rate from Triazine-based inhibitors on API 5-L X60 steel at NaCl 3,5% environtment were investigated using the Tafel Polarization method. The Triazine compounds that successfully absorbed onto steel surface were investigated using the Fourier Transform Infra Red (FTIR). Triazine?s efficiency depends on the concentration that given onto environtment. The highest efficiency of Triazine inhibitor is 50.28% with the optimize concentration 150 ppm. The investigated Triazine inhibitors were proven as the corrosion inhibitors because it can reduces the corrosion rate. Triazine inhibitors are also mixed type inhibitors.;The corrosion rate from Triazine-based inhibitors on API 5-L X60 steel at NaCl 3,5% environtment were investigated using the Tafel Polarization method. The Triazine compounds that successfully absorbed onto steel surface were investigated using the Fourier Transform Infra Red (FTIR). Triazine?s efficiency depends on the concentration that given onto environtment. The highest efficiency of Triazine inhibitor is 50.28% with the optimize concentration 150 ppm. The investigated Triazine inhibitors were proven as the corrosion inhibitors because it can reduces the corrosion rate. Triazine inhibitors are also mixed type inhibitors. , The corrosion rate from Triazine-based inhibitors on API 5-L X60 steel at NaCl 3,5% environtment were investigated using the Tafel Polarization method. The Triazine compounds that successfully absorbed onto steel surface were investigated using the Fourier Transform Infra Red (FTIR). Triazine’s efficiency depends on the concentration that given onto environtment. The highest efficiency of Triazine inhibitor is 50.28% with the optimize concentration 150 ppm. The investigated Triazine inhibitors were proven as the corrosion inhibitors because it can reduces the corrosion rate. Triazine inhibitors are also mixed type inhibitors. ]

Abstrak :
Kemampuan inhibitor Imidazoline dalam menginhibisi baja karbon API 5L Grade B dalam lingkungan NaCl 3.5 % diinvestigasi dengan menggunakan metode Polarisasi Tahanan Linier atau Linier Polarization Resistance (LPR) dalam berbagai variasi konsentrasi. Konsentrasi yang digunakan pada penelitian kali ini adalah 0 ppm, 50 ppm, 10 ppm, 150 ppm, 200 ppm, dan 250 ppm. Hasil pengujian menunjukkan bahwa konsentrasi optimum dalam menurunkan laju korosi terdapat pada 200 ppm dengan laju korosi sebesar 0,0005 mm/year, sedangkan nilai Rp terus meningkat dan optimum pada konsentrasi 250 ppm dengan nilai sebesar 579,042 Ohm. Kurva laju korosi vs konsentrasi inhibitor menunjukkan bahwa konsentrasi optimum inhibitor imidazoline dalam menurunkan laju korosi terdapat pada konsentrasi 200 ppm. ......The performance of Imidazoline based commercial corrosion inhibitor on carbon stel API 5L Grade B on NaCl 3.5 % solution was investigated using Linear Polarization Resistance Method or LPR. The Inhibitor concentration that used in this experiment were 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm, and 250 ppm. Experimental results showed that the optimum concentration to decrease the corrosion rate is 200 ppm with the corrosion rate is 0,0005 mm/year , while the optimum polarization resistance is 579,042 Ohm at 250 ppm. The plot of corrosion rate vs inhibitor concentration show the optimum imidazoline inhibitor concentration for decreasing corrosion rate is 200 ppm.

Abstrak :
Pelat lambung kapal merupakan bagian konstruksi kapal yang akan mengalami kerusakan akibat serangan korosi di lingkungan air laut pertama kali. Salah satu metode pengendalian korosi pada pelat lambung kapal adalah dengan menerapkan sistem proteksi katodik, seperti menggunakan anoda korban. Akan tetapi, banyaknya pilihan anoda korban yang tersedia membuat para pemilik kapal kesulitan dalam menentukan anoda korban yang memiliki kinerja optimal untuk memproteksi struktur pelat lambung kapal. Oleh karena itu, penelitian ini bertujuan untuk melakukan evaluasi kinerja dua produk (X dan Y) anoda korban paduan aluminium Al-Zn-In yang memiliki komposisi kimia berbeda pada pelat baja kapal AH 36 di lingkungan air laut dengan melakukan analisis pada nilai laju korosinya. Metode yang dilakukan dalam penelitian, yaitu melakukan observasi lapangan pada kapal dengan mengumpulkan data pengurangan ketebalan pelat kapal yang telah berlayar selama 2,5 tahun dan sedang menjalani pengedokan di galangan kapal. Selain itu, juga dilakukan pengujian laboratorium dengan metode weight loss dan linear polarization resistance pada spesimen uji pelat baja AH 36, dua produk anoda korban paduan aluminium Al-Zn-In yang memiliki komposisi kimia berbeda dan menggunakan elektrolit berupa air laut dengan salinitas 33,00 o/oo. Pada observasi lapangan didapati bahwa penggunaan anoda korban paduan aluminium X untuk memproteksi pelat baja lambung kapal yang telah beroperasi selama 2,5 tahun dapat menurunkan laju korosi rata-rata yang dialami pelat lambung kapal menjadi sebesar 0,108 mm/tahun. Selain itu, berdasarkan hasil pengujian laboratorium yang dilakukan, diperoleh bahwa laju korosi paling rendah dialami spesimen baja yang diproteksi dengan anoda korban paduan aluminium Y, dimana diperoleh nilai laju korosi rata-ratanya sebesar 0,1265 mm/tahun (metode weight loss) dan 0,0983 mm/tahun (metode linear polarization resistance). Kemudian, disusul pada urutan kedua oleh spesimen baja yang diproteksi dengan anoda korban paduan aluminium X, dimana didapati nilai laju korosi rata-ratanya sebesar 0,1646 mm/tahun (metode weight loss) dan 0,1982 mm/tahun (metode linear polarization resistance). Untuk laju korosi yang paling tinggi dialami oleh spesimen baja Z yang tidak diproteksi dengan anoda korban paduan aluminium, dimana diperoleh nilai laju korosi rata-ratanya sebesar 0,2138 mm/tahun (metode weight loss) dan 0,2551 mm/tahun (metode linear polarization resistance). Sehingga, dapat diketahui bahwa anoda korban paduan aluminium Y memiliki kinerja paling optimal dalam memproteksi pelat baja kapal AH 36 dari kerusakan akibat serangan korosi di lingkungan air laut. ......The hull plates are part of the construction that will be damaged by corrosion attack in the seawater environment for the first time. One way to control corrosion on ship plates is to apply a cathodic protection system, such as the use of a sacrificial anode. However, the many choices of sacrificial anodes available make it difficult for ship owners to determine which sacrificial anode has the optimal performance to protect the hull plate structure. Therefore, this study aims to evaluate the performance of two products (X and Y) of the aluminium alloy sacrificial anode Al-Zn-In with different chemical compositions on the steel plate of the AH 36 ship in a seawater environment by analyzing the corrosion rate value. The method used in this research is to conduct field observations on ships by collecting plate reduction data on ships that have been sailing for 2,5 years and are undergoing docking at the shipyard. In addition, laboratory tests were also carried out using weight loss and linear polarization resistance methods on test specimens of AH 36 steel plate, two aluminium alloy sacrificial anode products Al-Zn-In which have different chemical compositions and use electrolytes in the form of seawater with a salinity of 33, 00 o/oo. On-field observations, it was found that the use of aluminium alloy X sacrificial anode to protect the hull steel plate operating for 2,5 years can reduce the average corrosion rate experienced by the hull plate to 0,108 mm/year. Based on the results of laboratory tests, it was found that the lowest corrosion rate was experienced by steel protected with aluminium alloy sacrificial anode Y, where the average corrosion rate was 0,1265 mm/year (weight loss method) and 0,0983 mm/year (linear polarization resistance method). Then, followed in second place by steel specimens protected with aluminium alloy X sacrificial anode, where the average corrosion rate values ​​were 0,1646 mm/year (weight loss method) and 0,1982 mm/year (linear polarization resistance method). The highest corrosion rate was experienced by Z steel specimens that were not protected with an aluminium alloy sacrificial anode. The average corrosion rate was 0,2138 mm/year (weight loss method) and 0,2551 mm/year (linear polarization resistance method). Thus, it can be seen that the aluminium alloy sacrificial anode Y has the most optimal performance in protecting the steel plate of the AH 36 ship from damage due to corrosion attacks in the seawater environment.