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Abstrak :
Penelitian mengenai kandungan logam berat timbal (Pb), kadmium (Cd) dan seng (Zn) pada spons Neopetrosia sp. di Pulau Pramuka, Kepulauan Seribu telah dilakukan. Logam berat merupakan unsur beracun jika konsentrasinya berada di dalam tubuh. Tujuan dilakukan penelitian, yaitu untuk mengetahui perbedaan konsentrasi logam berat (Pb, Cd, dan Zn) pada spons Neopetrosia sp. di 3 stasiun penelitian yang berbeda di perairan Pulau Pramuka serta mengetahui korelasi kandungan logam berat Pb, Cd, dan Zn pada spons Neopetrosia sp. dengan air dan sedimen. Konsentrasi logam berat (Pb, Cd dan Zn) pada spons Neopetrosia sp., sedimen dan air di Pulau Pramuka dideteksi menggunakan alat Inductively Coupled Plasma-mass Spectrometry (ICP-MS). Hasil rata-rata konsentrasi logam berat Pb, Cd, dan Zn pada Neopetrosia sp. secara berurut berkisar 957,54--2.560,43 ppb; 6,41--7,99 ppb; 2.431,87-- 4.577,91 ppb. Hasil rata-rata konsentrasi logam berat Pb, Cd, dan Zn pada sedimen secara berurut berkisar 132,35--783,96 ppb; 11,08--18,18 ppb; 681,48--5.179,02 ppb. Hasil rata-rata konsentrasi logam berat (Pb, Cd, dan Zn) pada air secara berurut berkisar 0,33--0,85 ppb; 0,00--0,01 ppb; 5,81--9,28 ppb. Data kemudian dianalisis menggunakan korelasi Spearman. Hasil menunjukan bahwa tidak terdapat korelasi antara kandungan logam berat (Pb, Cd, Zn) pada spons Neopetrosia sp. dan sedimen, maupun logam berat (Pb, Cd, dan Zn) pada spons Neopetrosia sp. dan air

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Research on heavy metals (Pb, Cd, and Zn) in sponge Neopetrosia sp. on Pramuka Island, Thousand Islands has been carried out. Heavy metals are toxic element if the concentration is existed in the body. The purpose of this research was to determine the differences of heavy metals Pb, Cd, and Zn concentrations in sponge Neopetrosia sp. in 3 different research stations in Pramuka Island and to know the correlation of heavy metal content of Pb, Cd, and Zn in sponge Neopetrosia sp. with water and sediment. The concentrations of heavy metals Pb, Cd, and Zn in Neopetrosia sp., sediment and water in Pramuka Island were detected with Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) tool. The results of the average concentrations of heavy metals (Pb, Cd, and Zn) in Neopetrosia sp. sequentially ranges from 957.54--2.560.43 ppb; 6.41--7.99 ppb; 2,431.87--4,577.91 ppb. The average concentration of Pb, Cd, and Zn in the sediment ranged from 132.35 to 783.96 ppb; 11.08--18.18 ppb; 681.48--5,179.02 ppb. The results of the average concentrations of Pb, Cd, and Zn in water, respectively, ranged from 0.33--0.85 ppb; 0.00--0.01 ppb; 5.81--9.28 ppb. The data were analyzed using the Spearman correlation. The results have shown that there was no correlation between heavy metals content (Pb, Cd, Zn) in the sponge Neopetrosia sp. and sediments, as well as heavy metals (Pb, Cd, and Zn) on the sponge Neopetrosia sp. and water

Abstrak :
Telah dilakukan penelitian terkait analisis kandungan logam berat Pb, Cd dan Zn pada spons Stylissa massa, air laut, dan sedimen di perairan Pulau Pramuka dan Pulau Semak Daun, Kepulauan Seribu. Sampel S. massa dikering-bekukan, dan dimaserasi menggunakan larutan HNO3 pekat selama 48 jam untuk mendapatkan larutan ekstraksi. Sampel air laut diekstraksi menggunakan HNO3 pekat sedangkan sampel sedimen diekstraksi menggunakan larutan HF. Larutan ekstraksi S. massa, air laut dan sedimen selanjutnya dianalisis menggunakan alat ICP-MS (Inductively Coupled Plasma – Mass Spectrometry) untuk mengetahui kandungan Pb, Cd dan Zn. Hasil analisis logam berat pada S. massa, air laut dan sedimen menunjukkan bahwa kandungan Pb, Cd dan Zn pada perairan Pulau Pramuka lebih tinggi dibandingkan Pulau Semak Daun. Logam berat Zn memiliki konsentrasi tertinggi pada setiap sampel S. massa, air laut, dan sedimen. Konsentrasi Zn pada spons yaitu sebesar 11.603,2 ppb untuk sampel Pulau Pramuka dan 8.406,29 ppb untuk sampel Pulau Semak Daun, pada air laut sebesar 9,52 ppb untuk Pulau Pramuka dan 2,68 ppb untuk Pulau Semak Daun, sedangkan pada sedimen sebesar 2.968,38 ppb untuk Pulau Pramuka dan sebesar 1.312,95 ppb untuk Pulau Semak Daun. Sementara itu, konsentrasi Pb pada sampel spons Pulau Pramuka sebesar 498,08 ppb dibanding spons Pulau Semak Daun sebesar 313,46 ppb. Pb pada air laut Pulau Pramuka sebesar 0,51 ppb dan Pulau Semak Daun sebesar 0,43 ppb, sedangkan pada sedimen Pulau Pramuka sebesar 583,73 ppb dan 364,01 ppb pada sedimen Pulau Semak Daun. Konsentrasi Cd pada spons Pulau Pramuka yaitu sebesar 62,33 ppb dibanding Pulau Semak Daun sebesar 62,06 ppb. Pada air laut, Cd terkandung sebesar 0,02 ppb di Pulau Pramuka dan sebesar 0,03 ppb di Pulau Semak Daun, sedangkan sedimen Pulau Pramuka mengandung Cd sebesar 16,05 ppb dan 4,58 ppb pada sedimen Pulau Semak Daun ......Research related to the analysis of the heavy metal content Pb, Cd and Zn on Stylissa massa sponge, seawater and sediment in the waters of Pramuka Island and Semak Daun Island, Seribu Islands have been carried out. The S. massa samples were freeze-dried, and macerated using HNO3 solution for 48 hours to obtain the extraction solution. Seawater samples were extracted using HNO3 solution, while sediment samples were extracted using HF solution. The extraction solution of S. massa, seawater and sediment were then analyzed using the ICP-MS (Inducively Coupled Plasma - Mass Spectrometry) to see the content of Pb, Cd and Zn. The result of heavy metals analysis on S. massa, seawater and sediment showed that the content of Pb, Cd and Zn in Pramuka Island were higher than Semak Daun Island. Heavy metal Zn had the highest concentration in each sample of S. massa, seawater, and sediment. The Zn concentration in the sponge amounted to 11.603,2 ppb for the Pramuka Island’s sample and 8.406,29 ppb for the Semak Daun Island’s sample, in seawater Zn amounted to 9,52 ppb for Pramuka Island and 2,68 ppb for the Semak Daun Island, while in sediment was 2.968,38 ppb for Pramuka Island and 1.312,95 ppb for Semak Daun Island. Meanwhile, the Pb concentration in the Pramuka Island’s sponge amounted to 498,08 ppb compared to the Semak Daun Island’s sponge amounted to 313,46 ppb. Pb in Pramuka Island’s seawater was 0,51 ppb and Semak Daun Island’s was 0,43 ppb, while in Pramuka Island’s sediment amounted to 583,73 ppb and 364,01 ppb in Semak Daun Island’s sediment. The concentration of Cd in Pramuka Island’s sponge was 62,33 ppb compared to Semak Daun Island’s sponge, which was 62,06 ppb. In seawater, Cd amounted to 0,02 ppb in Pramuka Island and 0,03 ppb in Semak Daun Island, while Pramuka Island’s sediment contained 16,05 ppb of Cd and 4,58 ppb in the Semak Daun Island’s sediment

Abstrak :
ABSTRAK
Chelating resin-packed minicolumn preconcentration was used for multielement determination of trace metals in seawater by inductively coupled plasma mass spectrometry (ICP-MS). The chelating resin-packed minicolumn was constructed with two syringe filters (DISMIC 13HP and Millex-LH) and an iminodiacetate chelating resin (Chelex 100, 200-400 mesh), with which trace metals in 50 mL of original seawater sample were concentrated into 0.50 mL of 2 M nitric acid, and then 100-fold preconcentration of trace metals was achieved. Then, 0.50 mL analysis solution was subjected to the multielement determination by ICP-MS equipped with a MicroMist nebulizer for micro-sampling introduction. The preconcentration and elution parameters such as the sample-loading flow rate, the amount of 1 Mammonium acetate for elimination of matrix elements and the amount of 2 M nitric acid for eluting trace metals was optimized to obtain good recoveries and analytical detection limits for trace metals. The analytical results for V, Mn, Co, Ni, Cu, Zn, Mo, Cd, Pb, and U in three kinds of seawater certified reference materials (CRMs; CASS-3, NASS-4, and NASS-5) agreed well with their certified values. The observed values of rare earth elements (REEs) in the above seawater CRMs were also consistent with the reference values. Therefore, the compiled reference values for the concentrations of REEs in CASS-3, NASS-4, and NASS-5 were proposed based on the observed values and reference data for REEs in these CRMs.