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Ditemukan 3 dokumen yang sesuai dengan query
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S. Divakara Shetty
"Inhibition is one of the
mechanisms used for mitigating the metallic corrosion, particularly in an acid environment. The present work aims to
investigate the
inhibiting effect of N-benzyl-N/-phenyl thiourea (BPTU) on the
corrosion of low carbon steel in a 0.1 M hydrochloric acid (HCl) solution using a Tafel
extrapolation and linear polarization techniques. The study reveals that BPTU
acts as an excellent anodic inhibitor for low carbon steel in a HCl
solution. The protective efficiency of the compound was found to be more than
97% even at higher temperatures. The study demonstrated that BPTU gets adsorbed
on the steel surface, following Temkin?s adsorption isotherm and the inhibition
is controlled by a chemisorption
mechanism. The investigation shows that the results obtained from the Tafel
extrapolation and linear polarization techniques for the corrosion of mild
steel in HCl medium were in good agreement. The influence of temperatures and
concentrations of BPTU on the corrosion of low carbon steel are also
examined in the present work."
2016
J-Pdf
Artikel Jurnal  Universitas Indonesia Library
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S. Divakara Shetty
"Inhibition is one of the mechanisms used for mitigating the metallic corrosion, particularly in an acid environment. The present work aims to investigate the inhibiting effect of N-benzyl-N/-phenyl thiourea (BPTU) on the corrosion of low carbon steel in a 0.1 M hydrochloric acid (HCl) solution using a Tafel extrapolation and linear polarization techniques. The study reveals that BPTU acts as an excellent anodic inhibitor for low carbon steel in a HCl solution. The protective efficiency of the compound was found to be more than 97% even at higher temperatures. The study demonstrated that BPTU gets adsorbed on the steel surface, following Temkin’s adsorption isotherm and the inhibition is controlled by a chemisorption mechanism. The investigation shows that the results obtained from the Tafel extrapolation and linear polarization techniques for the corrosion of mild steel in HCl medium were in good agreement. The influence of temperatures and concentrations of BPTU on the corrosion of low carbon steel are also examined in the present work."
Depok: Faculty of Engineering, Universitas Indonesia, 2016
UI-IJTECH 7:5 (2016)
Artikel Jurnal  Universitas Indonesia Library
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S. Divakara Shetty
"Since inhibition is the simplest mechanism used for mitigating the corrosion of metals and alloys, particularly in acidic environments, the present work aims to investigate the inhibiting effect of N-benzyl-N?-phenyl thiourea (BPTU) and N-cyclohexyl-N?-phenyl thiourea (CPTU) on mild steel corrosion in 0.1M HCl medium using the Tafel extrapolation technique. Tafel experiments were conducted with ±250 mV vs. rest potential (RP) in steps of 20 mV from the cathodic side for recording the corrosion currents, and then, the Tafel plot of potential vs. current was drawn for determining the corrosion current density (icorr). The linear polarization method was also used for validating the Tafel results. It was performed by polarizing the specimen with ±20 mV vs. RP in steps of 5 mV, and the corrosion currents were noted. The plot of potential vs. current was drawn for calculating icorr. The study reveals that both BPTU and CPTU act as anodic inhibitors for mild steel in the HCl medium, and good inhibition efficiency (>97%) was evidenced from both the compounds even at elevated temperatures. The study also reveals that the investigated compounds get adsorbed quickly on the steel surface, following Temkin’s adsorption isotherm. The kinetic parameters obtained from the study indicated that the inhibition was governed by a chemisorption mechanism and the presence of inhibitors substantially reduced the metal dissolution in the studied temperature range. The investigation shows that there was a good correlation between the Tafel extrapolation and linear polarization results."
Depok: Faculty of Engineering, Universitas Indonesia, 2017
UI-IJTECH 8:5 (2017)
Artikel Jurnal  Universitas Indonesia Library