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"Self-contained textbook covering the essential aspects of the corrosion behavior of metals in aqueous environments. Provides an overview of aqueous corrosion, electrode reactions, and electrode kinetics. DLC: Electrolytic corrosion."

"Inhibition is one of themechanisms used for mitigating the metallic corrosion, particularly in an acid environment. The present work aims toinvestigate theinhibiting effect of N-benzyl-N/-phenyl thiourea (BPTU) on thecorrosion of low carbon steel in a 0.1 M hydrochloric acid (HCl) solution using a Tafelextrapolation and linear polarization techniques. The study reveals that BPTUacts as an excellent anodic inhibitor for low carbon steel in a HClsolution. The protective efficiency of the compound was found to be more than97% even at higher temperatures. The study demonstrated that BPTU gets adsorbedon the steel surface, following Temkin?s adsorption isotherm and the inhibitionis controlled by a chemisorptionmechanism. The investigation shows that the results obtained from the Tafelextrapolation and linear polarization techniques for the corrosion of mildsteel in HCl medium were in good agreement. The influence of temperatures andconcentrations of BPTU on the corrosion of low carbon steel are alsoexamined in the present work."

"Inhibition is one of the mechanisms used for mitigating the metallic corrosion, particularly in an acid environment. The present work aims to investigate the inhibiting effect of N-benzyl-N/-phenyl thiourea (BPTU) on the corrosion of low carbon steel in a 0.1 M hydrochloric acid (HCl) solution using a Tafel extrapolation and linear polarization techniques. The study reveals that BPTU acts as an excellent anodic inhibitor for low carbon steel in a HCl solution. The protective efficiency of the compound was found to be more than 97% even at higher temperatures. The study demonstrated that BPTU gets adsorbed on the steel surface, following Temkin’s adsorption isotherm and the inhibition is controlled by a chemisorption mechanism. The investigation shows that the results obtained from the Tafel extrapolation and linear polarization techniques for the corrosion of mild steel in HCl medium were in good agreement. The influence of temperatures and concentrations of BPTU on the corrosion of low carbon steel are also examined in the present work."

"Hyperduplex Stainless Steel 3207 (SAF 3207 HD) is one of the materials used in the oil and gas industry, especially for umbilical, which is a system to connect cables or instrumental setups between control platforms and wellhead station. It is used in deep water containing high chloride ion (Cl-), so it needs high tensile strength and must be a highly corrosion-resistant material. In this research, several corrosion resistance tests were conducted on 3207 hyperduplex stainless steel such as polarization and weight loss testing. Roughness surface tests were carried out to observe alterations to the surface caused by underwater corrosion. SAF 3207 HD can form a passive layer due to an environmental reaction; to observe this phenomenon, an EIS test was conducted at the interface of the material. The weight loss test was conducted on a particular sample, in accordance with ASTM G48-97 method B. The corrosion test was carried out at temperatures of 60-90°C (at 5°C intervals) in 6% FeCl3 solution. The results show that SAF 3207 HD has good crevice corrosion resistance, although crevices were not seen below temperatures of 70oC, which is known as critical crevice temperature. At this temperature, the corrosion rate reached 10.032 mm/year and the crevice depth was 1.034 ?m. This means that the operating temperature of the umbilical can be increased up to 70oC."

"Korosi yang disebabkan oleh karbondioksida (CO2) pada pipa baja karbon dan peralatan di pengolahan minyak dan gas sangat umum terjadi. CO2 larut dalam air menghasilkan asam karbonat (H2CO3) yang mempunyai sifat yang lebih korosif dibanding asam klorida (HCL) pada pH yang sama. Electrochemical impedance spectroscopy dan linear polarization resistance digunakan untuk mengetahui fenomena proses yang terjadi selama proses adsorbsi inhibitor di permukaan logam. Variasi temperature dan konsentrasi dari inhibitor dilakukan untuk mengetahui kemampuan inhibisi inhibitor dan mekanisme inhibisi. Penelitian ini dilakukan pada baja karbon A106 grB di dalam lingkungan 3% NaCl. Konsentrasi inhibitor bervariasi dari 0,5,15, dan 40 ppm dan dengan variasi temperature di 40 0C dan 90 0C. Pada temperature 40 0C laju korosi menunjukan 213,9 MPY pada lingkungan tanpa penambahan inhibitor , dan akan turun drastis ke 22,4 MPY ketika 5 ppm inhibitor ditambahkan ke lingkungan, dengan effisiensi inhibisi 90%. Penambahan konsentrasi inhibitor sampai 40 ppm meningkatkan effisiensi inhibisi sampai 98%. Penambahan konsentrasi inhibitor berbasis Imidazoline dari dari 0 ppm sampai 5 ppm pada temperature 90 0C dapat menghasilkan penurunan laju korosi yang signifikan yaitu dari 173,3 MPY menjadi 31,67 MPY, dengan effisiensi inhibisi 82%. Dengan penambahan konsentrasi inhibitor sebanyak 40 ppm akan menaikan effisiensi inhibisi sampai 99,99 %. Mekanisme penghambatan laju korosi terjadi sebagai akibat terbentuknya ikatan polar (O-H dan N-H) yang berikatan dengan permukaan logam melalui proses chemisorption.

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Corrosion caused by carbon dioxide (CO2) in carbon steel pipes and equipment in oil and gas processing is very common. Water soluble CO2 produces carbonic acid (H2CO3) which has more corrosive properties than hydrochloric acid (HCL) at the same pH. Electrochemical impedance spectroscopy and linear polarization resistance are used to determine the processes that occur during the adsorbs inhibitor process on the metal surface. Variation of concentration of the inhibitor is conducted to determine the ability of inhibitor inhibition and inhibition mechanism. This research was conducted on A106 gr. B carbon steel in an environment of 3% NaCl. The inhibitor concentration varies from 0,5,15, and 40 ppm at 40 0C. At temperatures of 400C the corrosion rate shows 213.9 MPY in the environment without the addition of inhibitors, and will drop dramatically to 22.4 MPY when 5 ppm inhibitors are added to the environment. Electrochemical Impedance Spectroscopy is used to study inhibition mechanism. Increasing the concentration of Imidazoline based inhibitors from 0 ppm to 5 ppm at 90 0C can produce a significant decrease in corrosion rate from 173.3 MPY to 31.67 MPY, with 82% inhibition efficiency. With the addition of inhibitor concentrations up to 40 ppm will increase inhibition efficiency to 99,99 %. The mechanism of inhibition of corrosion rate occurs as a result of the formation of polar bonds (O-H and N-H) that bind to the metal surface through a chemisorption process."