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"Adanya kecenderungan masyarakat Indonesia untuk mengonsumsi makanan mengandung minyak dan lemak menjadi pemicu peningkatan timbulan limbah minyak dan lemak serta nilai COD dan VS air limbah. Penelitian ini bertujuan untuk mengetahui potensi biogas dan rasio limbah minyak dan lemak dengan sampah makanan yang paling optimum.Penelitian dilaksanakan selama 42 hari inkubasi pada suhu 37˚C dengan tiga variasi rasio VS limbah minyak dan lemak dan sampah makanan yaitu 1:7, 1:2, dan 1:1 dengan metode biochemical methane potential. Limbah minyak dan lemak memiliki karakteristik COD 148 g/L, TS 763 g/L, dan VS 759 g/L.Penelitian ini menunjukkan bahwa limbah minyak dan lemak memiliki potensi menghasilkan biogas tertinggi melalui proses anaerobic co- digestion dengan sampah makanan dan menghasilkan 485 mLCH4/grVS dari variasi 1:7. Sementara variasi rasio limbah minyak dan lemak dengan sampah makanan 1:2 dan 1:1 hanya menghasilkan 128 dan 4 mLCH4/grVS.

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Tendency of Indonesian people to eat foods containing oils dan fats trigger increasing in generation of fat, oil, and grease waste and increasing in wastewater?s COD and VS. This research is conducted to know potential of fat, oil, and grease and its ratio with food waste that obtain the highest biogas production through biochemical methane potential method.

The research was conducted over 42 days incubation at 37˚C including three variation of volatile solids (VS) ratio of fat, oil, and grease waste with food waste, that is 1:7, 1:2, and 1:1. As co- substrate of the anaerobic co- digestion process, fat, oil, and grease characteristics are COD 148 g/L, TS 763 g/L, and VS 759 g/L.

Result showed that fat, oil, and grease waste has potential to produce biogas through anaerobic co- digestion process with food waste and produce 485 mLCH4/grVS as the highest methane yield of 1:7 ratio. While the variation of ratio fat, oil, and grease waste with food waste at 1:2 and 1:1 only produce 128 and 4 mLCH4/grVS, respectively."

"Pengelolaan limbah lumpur tinja yang sangat terbatas dapat ditingkatkan dengan memanfaatkannya menjadi biogas. Penelitian ini bertujuan untuk mengoptimalkan potensi biogas pada lumpur tinja dengan menambahkan sampah makanan dan sampah taman. Sistem yang digunakan berupa Anaerobic Co-digestion dengan variasi konsentrasi lumpur tinja, yaitu sebesar 25% dan 50% berdasarkan nilai Volatile Solids (VS). Inokulum yang digunakan adalah rumen sapi. Penelitian dilakukan menggunakan reaktor batch skala lab berukuran 51 L dengan masa operasi selama 42 hari. Biogas yang dihasilkan pada konsentrasi lumpur tinja sebesar 25% adalah 0,30 m3CH4/kg VS dengan destruksi VS sebesar 71,93% dan COD sebesar 72,42%. Sedangkan, biogas yang dihasilkan pada konsentrasi lumpur tinja sebesar 50% adalah 0,56 m3CH4/kg VS dengan destruksi VS sebesar 92,43% dan COD sebesar 87,55%. Penelitian ini menyimpulkan bahwa potensi biogas pada konsentrasi lumpur tinja sebesar 50% lebih besar dibandingkan pada konsentrasi lumpur tinja sebesar 25%.

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Faecal sludge management can be optimized by converting the sludge into biogas. The purpose of this study is to optimize the biogas potential of faecal sludge with food waste and garden waste. The system use Anaerobic Co-digestion with variation of 25% and 50% concentration of faecal sludge based on Volatile Solids (VS). Inoculum used was cow?s rumen. The study was operated using lab-scale batch reactor 51 L for 42 days. Biogas produced from 25% concentration of faecal sludge is 0,30 m3CH4/kg with 71,93% VS and 72,42% COD destruction. Meanwhile, 50% concentration of faecal sludge produced 0,56 m3CH4/kg VS biogas with 92,43% VS and 87,55% COD destruction. This study concludes that biogas potential from 50% concentration of faecal sludge is greater than 25% concentration of faecal sludge."

"Pengadukan dalam Anaerobic Digestion AD dapat dikontrol untuk meningkatkan kinerja proses AD. Penelitian ini bertujuan untuk mengetahui pengaruh intensitas pengadukan terhadap kinerja proses AD, transfer panas di dalam digester dan untuk menganalisis kesetimbangan energi. Penelitian dilakukan menggunakan Continuous Stirred Tank Reactor CSTR dengan volume terisi 400 L yang beroperasi pada suhu rata-rata 27,8 1,07oC. Penelitian operasi skenario pertama dilakukan dengan input substrat sampah makanan dengan Organic Loading Rate OLR 10 kg VS/m3 selama 43 hari dan diaduk menggunakan variasi intensitas pengadukan 30 rpm dan 60 rpm selama 4 jam/hari untuk melihat kinerja proses AD. Operasi skenario kedua dilakukan menggunakan substrat sampah makanan dan kotoran sapi banding limbah Fat Oil and Grease FOG sebesar 10:1 dengan OLR 10 kg VS/m?3 dan dilakukan variasi pengadukan berkala 30 rpm, 15 menit/1,5 jam dan kontinu 30 rpm, 4 jam/hari untuk melihat tansfer panas dalam digester. Hasil penelitian operasi skenario pertama menunjukkan terdapat perbedaan yang signifikan pada kedua intensitas pengadukan.

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Mixing in Anaerobic Digestion AD can be controlled to improve the performance of the AD process. This study aims to determine the effect of mixing intensity on the performance of the AD process, heat transfer in the digester and to analyze the energy balance. The study was conducted using a Continuous Stirred Tank Reactor CSTR with 400 L working volume which operates at an average temperature of 27,8 1,07 C. In the first scenario operation study, reactor was fed with food waste with Organic Loading Rate OLR 10 kg VS m3 for 43 days and mixed using variation of mixing intensity 30 rpm and 60 rpm for 4 hours day to see AD process performance. The second operation was carried out using food and cow dung with Fat Oil and Grease FOG waste ratio 10 1 and mixed intermittent 30 rpm, 15 min 1.5 hour and continuous 30 rpm, 4 hour day to see heat transfer in the digester. The results of the first scenario operation study showed that there was a significant difference in both mixing intensity p."

"Limbah organik yang berpotensi menjadi sumber energi dengan metode anaerobic digestion seringkali mengalami ketidaksabilan karena konsentrasi VFAs yang tinggi. Tujuan dari penelitian ini adalah meningkatkan produksi metana pada AD dengan kombinasi dua substrat yaitu limbah organik (LO) dan kotoran sapi (KS) yang berperan sebagai buffer dengan uji biochemical methane potential (BMP). Uji BMP dilakukan selama 35 hari pada suhu ±35⁰C dengan mengukur volume dan persentase biogas setiap minggu serta pengujian karakteristik awal dan akhir sampel. Volume metana pada setiap variasi perbandingan sampel tidak menunjukkan adanya perbedaan pada minggu ke-5 kecuali pada perbandingan LO /KS :12/1 dengan 3/1, dimana sampel dengan perbandingan 3/1 memiliki potensi yang paling besar yaitu 0,58±0,015(n=3) LCH4/grVS. Penambahan kotoran sapi juga membuat keseluruhan variasi perbandingan stabil selama pengujian BMP terutama sampel 6:1 dengan VFAs/alkalinitas yang <0,3 walaupun rasio C/N <20.

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Organic waste that could potentially be a source of energy by anaerobic digestion methods are often unstable because of the high concentration of VFAs. The purpose of this research is to increase the production of methane by anaerobic digestion with two substrates combination The combination is between organic waste and cow manure which acted as a buffer with a biochemical methane potential testing. BMP testing conducted over 35 days at a temperature of ± 35⁰C by measuring the volume and percentage of biogas every week and testing the characteristics of the beginning and end of the sample. The result of the sample variation is that the volume of methane did not show any difference in the 5th week except in comparison organic waste / cow manure: 12/1 to 3/1, but the sample with a ratio of 3/1 has the greatest potential, namely 0,58 ± 0.015 (n = 3) LCH4 / grVS. With the addition of cow manure also makes the conditiin of overall variation is stable during testing BMP with VFAs / alkalinity <0.3 although C / N ratio of each variation is <20."

"Sampah makanan mengemisikan biogas yang mengandung CH4. Penelitian ini bertujuan untuk mengetahui karakteristik sampah makanan Kantin FTUI dan potensi kuantitas metana yang dihasilkan. Penelitian dilakukan dengan reaktor anaerobik batch selama 43 hari dengan variasi C/N kisaran 25-30 dan 22-25. Selama operasi reaktor tidak dihasilkan metana karena nilai VFA/TA 0,68 dan 0,75 yang menandakan proses tidak berjalan baik. Namun degradasi zat organik tetap terjadi dengan penurunan nilai VS yang berkisar 12,42 ?45,94% selama proses. Penelitian BMP dilakukan selama 31 hari dengan variasi inokulum, yakni rumen dan feses sapi. BMP sampah makanan dengan inokulum feses sapi menghasilkan lebih banyak metana dengan produksi biogas 0,14 mL CH4/g VS; 29,85 mL saat volume puncaknya (hari ke - 20) dan destruksi VS total 80,06%. Sedangkan BMP sampah makanan dengan rumen sapi sebagai inokulum memiliki produksi biogas 0,014 mL CH4/g VS; volume sebesar 3 mL (hari ke ? 10) saat puncak dan destruksi VS total 70,34%.

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Food waste emits biogas which contains CH4. This study aims to acknowledge food waste characteristics from FTUI cafeteria and its methane potential. The study was conducted in batch reactors for 43 days with C/N variation: 25-30 and 22-25. The result showed no methane was produced because of its VFA/TA 0,68 and 0,75 that indicated the process did not go well. But, the degradation of organic matters still happened with VS value declined in a range of 12,42-45,94%.

BMP was conducted for 31 days with inoculum variation: rumen and cow dung. BMP of food wastes with cow dung inoculum produced more methane, with biogas production 0,14 mL CH4/g VS; 29,85 mL on its peak volume (day 20) and 80,06% VS reduction. Meanwhile BMP of, food wastes with rumen fluid as its inoculum has biogas production 0,014 mL CH4/g VS; 3 mL of volume on its peak (day 10) and 70,34% as its VS reduction."

"Kinerja anaerobic digestion (AD) sebagai solusi teknologi pengolahan sampah organik dapat ditingkatkan dengan pra-pengolahan mekanis, pencacahan. Tujuan penelitian adalah menganalisis pengaruh ukuran partikel sampah organik terhadap potensi pembentukan gas CH4 serta menganalisis ukuran partikel optimumnya dalam skala laboratorium BMP. Parameter yang diuji yaitu TS, VS, COD, C/N, VFA, pH, dan alkalinitas. Penelitian dilakukan selama 35 hari dengan suhu 35°C.Hasil penelitian menunjukkan bahwa ukuran partikel memiliki pengaruh pada proses hidrolisis, tetapi tidak begitu berpengaruh pada proses metanogenesis. Partikel berukuran 13-10 mm menghasilkan gas CH4 dengan rata-rata 114,7 mL atau sebesar 72,82% dari biogas dengan potensi 0,277 L CH4/gr VS, ukuran 10-4,76 mm dengan rata-rata 101,7 mL atau sebesar 76,04% dari biogas memiliki potensi 0,208 L CH4/gr VS, dan ukuran 4,76-2 mm dengan rata-rata 110,9 mL atau sebesar 75,14% dari biogas memiliki potensi 0,229 L CH4/gr VS. Perbedaan ukuran partikel nyatanya memiliki pengaruh yang besar dalam proses hidrolisis, hal ini dibuktikan dari perbedaan nilai VFA yang dihasilkan secara signifikan. Partikel 13-10 mm menghasilkan VFA sebanyak 19,25 mg/L, sementara partikel 4,76-2 mm menghasilkan VFA sebanyak 118,1 mg/L.Dengan demikian, dapat disimpulkan bahwa ukuran partikel memberi pengaruh besar pada laju hidrolisis dan asidogenesis, namun tidak begitu berpengaruh pada potensi pembentukan gas CH4. Melihat kepada volume gas CH4 yang dihasilkan maupun potensi gas CH4 yang dapat tercipta dari VS, tidak ada satupun rentang partikel yang lebih unggul dibandingkan yang lain, sehingga tidak terdapat ukuran partikel yang optimum dalam pembentukan gas CH4. Tetapi jika melihat kepada aspek biaya dan energi yang diperlukan untuk mencacah, maka partikel dengan rentang 13-10 mm merupakan ukuran yang paling menguntungkan.

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Performance anaerobic digestion (AD) of organic waste processing technology solutions can be improved by pre-mechanical processing, chopping. The research objective was to analyze the effect of particle size of organic waste to the potential formation of CH4 and analyze the optimum particle size in a laboratory scale BMP. The parameters examined are TS, VS, COD, C/N, VFA, pH, and alkalinity. The study was conducted for 35 days with a temperature of 35°C.

The results showed that the particle size has an influence on the process of hydrolysis, but not so influential in the process of methanogenesis. Particles size 13-10 mm produce CH4 gas with an average of 114.7 mL or by 72.82% of the biogas and potential of 0.277 L CH4 / g VS, size 10-4.76 mm with an average of 101.7 mL or amounting to 76.04% of the biogas has the potential of 0.208 L CH4 / g VS, and size 4.76-2 mm with an average of 110.9 mL or by 75.14% of the biogas has the potential of 0.229 L CH4 / g VS. Differences in particle size in fact has a great influence in the process of hydrolysis, it is evident from the difference in value generated significant VFA. VFA from particles 13-10 mm produce as much as 19.25 mg / L, while particles of 4.76-2 mm produce VFA as much as 118.1 mg / L.

Thus, it can be concluded that the particle size to give a major influence on the rate of hydrolysis and asidogenesis, but not so influential on the potential formation of CH4. Looking at the volume of gas produced and the potential CH4 gas that can be created from VS, none of the range of particles that are superior to the others, so there is no optimum particle size in the formation of CH4. But if you look at the aspect of cost and energy needed for chopping, then the particles with a size range of 13-10 mm is the most profitable."

"Organic waste mostly comes from food waste, which has characteristics of high concentrations of nitrogen and fat, and high humidity. Domestic waste in Indonesia has a high organic content, which is suitable for anaerobic conditions. Waste oil and fat can be used as co-substrates and are helpful in yielding biogas in an anaerobic digestion (AD) process. The aim of this research is to analyze the performance of a food waste dry anaerobic digestion reactor after the addition of fat oil and grease (FOG) waste. The research was conducted using a semi-continuous stirred tank reactor (SCSTR) with an active volume of 400 L, operated at an average temperature of 27.8±1.07oC. Two experimental scenarios were performed, using varying types of food waste, food waste with cow dung as substrate, and FOG waste as co-substrate. The experiment was conducted using an Organic Loading Rate (OLR) of approximately 10 kg VS/m3, with a constant mixing intensity of 30 rpm. The results show that there was a significant difference between the input of food waste substrate with and without the addition of FOG (p<0.05). The average reduction of volatile solids (VS) and chemical oxygen demand (COD) removal in the substrate input with FOG addition was higher than without the addition. The mean percentages of COD removal and VS reduction in the substrate input with FOG addition were 63.3±2.71% and 89.30±1.55%, whereas those for substrate input without FOG addition were 59.45±4% and 77.65±1.46%, respectively. The study concludes that the use of FOG as a co-substrate in a dry AD food waste reactor is not only beneficial in reducing FOG waste generation, but also has a significant impact on reducing COD and VS, which can enhance potential biogas yield."

"Sampah organik sebagian besar berasal dari sampah makanan yang menyebabkan karakteristiknya memiliki konsentrasi nitrogen dan lemak tinggi, kelembaban tinggi. Limbah domestik di Indonesia memiliki karakteristik kandungan organik yang sesuai dengan kondisi anaerobik. Limbah minyak dan lemak dapat membantu dalam proses AD yang dijadikan sebagai ko-substrat.Penelitian ini bertujuan untuk menganalisis kinerja reaktor dry anaerobic digestion sampah makanan dan menganalisis pengaruh penambahan limbah minyak dan lemak terhadap kinerja reaktor dry anaerobic digestion. Penelitian dilakukan menggunakan Continuous Stirred Tank Reactor CSTR dengan volume terisi 400 L yang beroperasi pada suhu rata-rata 27,8 1,07oC.Penelitian operasi skenario pertama dilakukan dengan input substrat sampah makanan dengan Organic Loading Rate OLR 10 kg VS/m3 selama 43 hari dan diaduk menggunakan variasi intensitas pengadukan 30 rpm dan 60 rpm secara konstan.Operasi skenario kedua dilakukan selama 59 hari menggunakan substrat sampah makanan dan kotoran sapi banding limbah Fat Oil and Grease FOG dengan Organic Loading Rate OLR yang sama dengan skenario pertama dan diaduk menggunakan intensitas 30 rpm secara konstan.Hasil penelitian menunjukkan terdapat perbedaan yang signifikan antara input substrat sampah makanan dengan penambahan limbah minyak dan lemak.

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Organic waste mostly comes from food waste that has characteristics of high concentrations of nitrogen and fat, high humidity. Domestic waste in Indonesia has characteristics of organic content which is suitable with anaerobic conditions. Waste oil and fat can help in the process of AD which is used as co substrate.

This research is intended to analyze the performance of dry anaerobic digestion reactor of food waste and analyze the effect of oil and waste addition on dry anaerobic digestion reactor performance. The research was conducted using Continuous Stirred Tank Reactor CSTR with a volume of 400 L applied at an average temperature of 27.8 1.07oC.

The first scenario operation study was performed with food waste substrate input with Organic Loading rate OLR is 10 kg VS m3 for 43 days and stirred using constantly strirring intensity variation of 30 rpm and 60 rpm.

The second scenario operation was conducted for 59 days using food waste and cow dung substrate of Fat Oil and Grease waste FOG with Organic Loading Rate OLR which is similar to the first scenario and stirred using constant 30 rpm intensity.

The results of study showed that there was a significant difference between the input of food waste substrate with the addition of Fat Oil and Grease p."

"Kulit kakao adalah produk sampingan utama dari industri kakao, serai digunakan untuk memasak rempah-rempah di Indonesia, namun hanya batangnya yang digunakan, daunnya adalah limbah, dan ampas kopi adalah sisa dari biji kopi setelah digiling dan diseduh, di mana ia juga dianggap sebagai limbah Limbah biomassa ini berpotensi digunakan untuk produksi biogas melalui ko-pencernaan dengan kotoran sapi, karena ko-pencernaan antara limbah pertanian dan kotoran hewan memberikan efek sinergis yang akan menghasilkan hasil biogas lebih tinggi. Namun, limbah biomassa ini adalah bahan lignoselulosa, karena sulit untuk limbah biomassa diuraikan dalam pencernaan anaerob. Cairan rumen sapi telah diusulkan untuk metode biodegradasi biomassa lignoselulosa. Penelitian ini akan menggunakan limbah biomassa dan akan dicerna bersama dengan kotoran sapi dengan 4 variasi, yaitu: 1: 3, 1: 1, 3: 1, dan 1: 0. Cairan rumen sapi juga akan ditambahkan dalam empat variasi berbeda yaitu 0 g, 50 g, 100 g, dan 200 g. Kondisi operasi untuk produksi biogas juga akan bervariasi pada 25oC, 37 oC, 50 oC, dan 70 oC. Pencernaan anaerob akan dilakukan selama 168 jam, berdasarkan hasil, rasio optimal kulit kakao, serai, ampas kopi dengan kotoran sapi masing-masing adalah 1: 1, 1: 1, dan 1: 3, sedangkan jumlah rumen sapi yang optimal fluida 100 g, dan suhu kondisi pengoperasian optimal pada 37oC. Hasil metana untuk setiap limbah biomassa optimal adalah 46,05 ml, 33,88 ml, dan 346,3 ml dengan komposisi metana puncak yang sesuai masing-masing 16,64%, 8,45%, dan 57,89% untuk kulit buah kakao, serai, dan ampas kopi. Sementara perbandingan limbah biomassa dan kotoran sapi optimal yang sama tanpa penambahan cairan rumen menghasilkan 1,74 ml, 0,1 ml, dan 3,42 ml metana dengan komposisi metana puncak yang sesuai yaitu 1,56%, 0,03%, dan 23,32% untuk sekam kakao, serai, dan ampas kopi co-digestion masing-masing. Oleh karena itu, hasilnya menyiratkan bahwa penambahan cairan rumen sapi berhasil menurunkan biomassa lignoselulosa dan mempercepat produksi biogas.

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Cocoa husk is the primary by-product from the cocoa industry, lemongrass is used for cooking spices in Indonesia, however only the trunks are used, the leaves are waste, and coffee grounds is the reside from coffee beans after it is milled and brewed, where it is also considered as waste These biomass waste has the potential of being used for biogas production by co-digestion with cow manure, as co-digestion between agricultural waste and animal manure gives synergistic effect which would produce higher biogas yield. However, these biomass wastes are lignocellulosic materials, as it is difficult to for the waste biomass to be decomposed in anaerobic digestion. Cow rumen fluid has been proposed for method for biodegradation of lignocellulosic biomass.

The research will use the biomass waste and it will be co-digested with cow manure with 4 variation, which are as follows, 1:3, 1:1, 3:1, and 1:0. Cow rumen fluid will also be added in four different variations which are 0 g, 50 g, 100 g, and 200 g. The operating condition for the biogas production will also be varied at 25oC, 370C, 50oC, and 70oC.

Anaerobic digestion will be conducted for 168 hours, based on the results the optimum ratio of cocoa husk, lemongrass, coffee grounds to cow manure are 1: 1, 1: 1, and 1: 3, respectively, while the optimum amount of cow rumen fluid is 100 g, and the optimum operating condition temperature is at 37oC. The methane yield for each optimum biomass waste are 46.05 ml, 33.88 ml, and 346.3 ml with corresponding peak methane composition at 16.64%, 8.45%, and 57.89% for cocoa husk, lemongrass, and coffee grounds, respectively. While the same optimum waste biomass to cow manure ratio with no addition of rumen fluid produces 1.74 ml, 0.1 ml, and 3.42 ml of methane with corresponding peak methane composition at 1.56%, 0.03%, and 23.32% for cocoa husk, lemongrass, and coffee grounds co-digestion respectively. Therefore, the results imply that the addition of cow rumen fluid is successful in degrading the lignocellulose biomass and accelerate biogas production."

" ABSTRAK

Sampah rumah tangga yang sebagian besar berupa sampah makanan masih mendominasi timbulan sampah di Indonesia. Di sisi lain, Indonesia juga mengalami krisis energi. Oleh karena itu, diperlukan suatu teknologi ramah lingkungan yang dapat mengatasi permasalahan dan menghasilkan energi terbarukan. Salah satu alternatif penyelesaian permasalahan ini adalah dengan penerapan dry Anerobic Digester (AD). Pemilihan sistem dry utamanya adalah karena kebutuhan airnya yang lebih sedikit dibandingkan dengan sistem lain. Penelitian dilakukan dengan reaktor anaerobik batch selama 45 hari dengan volume 130 liter. Suhu operasi reaktor adalah pada rentang mesofilik. Substrat yang digunakan adalah sampah makanan kantin dan inokulum yang digunakan adalah efluen anaerobic digester. Terjadi penurunan produksi metana teoritis seiring dengan peningkatan konsentrasi amonia. Adanya indikasi toksisitas amonia dimana konsentrasi amonia mencapai 1.088 mg/L pada pH 7,9. Didapatkan efektifitas reaktor dry anaerobic digester adalah sebesar 43,85% destruksi volatile solid (VS) dan 27,34% destruksi chemical oxygen demand (COD). Rata-rata produksi metana adalah 0,14 L CH4 / gram VS feedstock.

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ABSTRAK

Household waste which consist largely amount of food waste, still dominates waste generation in Indonesia. On the other hand, Indonesia is also experiencing an energy crisis. Therefore environmentally friendly technology that can solve problems and generate renewable energy is needed. One alternative that can solve the problems is by the application of dry Anerobic Digester (AD). Selection of dry system is mainly because of its water reqirements is less than with other systems. Research carried out by anaerobic batch reactor for 45 days with a volume of 130 liters. The substrate used was cafeteria food waste and inoculum used is the anaerobic digester effluent. The theoretical methane production decrease due to the increased concentration of ammonia. The indication of the toxicity of ammonia in which the ammonia concentration reached 1088 mg / L at pH 7.9. Obtained effectiveness of dry anaerobic digester reactor was amounted to 43.85% VS destruction and 27.34% COD destruction. The average theoretical methane production was 0.14 L CH4 / g VS feedstock."