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"Mekanisme inhibisi korosi dari inhibitor berbahan dasar triazine pada baja API 5L Grade X60 di lingkungan NaCl 3,5% diinvestigasi dengan menggunakan metode model adsorpsi yang didapat dari hasil pengujian Tafel Polarisasi, Linier Polarisasi dan Electrochemical Impedance Spectroscopy (EIS) dengan menggunakan variasi konsentrasi 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm dan 250 ppm. Senyawa triazine yang teradsorpsi pada permukaan logam diinvestigasi dengan menggunakan pengujian Fourier Transform InfraRed (FTIR). Hasilnya didapatkan bahwa proses adsorpsi inhibitor triazine terjadi secara spontan mengikuti mode adsorpsi Langmuir isoterm. Berdasarkan nilai Nilai Goads berada pada rentang -11.0697 kJ/mol sampai -19.7833 kJ/mol menunjukkan bahwa inhibitor triazine menginhibisi korosi dengan cara adsorpsi fisika (interaksi elektrostatis antara muatan molekul inhibitor dengan muatan permukaan logam) membentuk lapisan tunggal di permukaan logam sehingga dapat menghambat proses korosi. Besarnya efisiensi inhibisi inhibitor berbahan dasar triazine bergantung pada konsentrasi inhibitor. Efisiensi inhibisi tertinggi diperoleh pada konsentrasi triazine 150 ppm sebesar 68,674% berdasarkan hasil pengujian Electrochemical Impedance Spectroscopy.

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Corrosion inhibition mechanism of triazine-based corrosion inhibitor on API 5L Grade X60 steel in 3.5% NaCl environment was investigated by using adsorption method from the results of tafel polarization, linier polarization resistance (LPR), and Electrochemical Impedance Spectroscopy (EIS) tests with 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm and 150 ppm concentration variation. Triazine compounds which adsorbed on metal surface was also investigated by Fourier Transform InfraRed (FTIR) test. It was found that adsorption process of triazine-based inhibitor occurs spontaneously and follow the Langmuir adsorption isotherm. From the calculation of Goads (around -11.0697 kJ/mol to -19.7833 kJ/mol), it indicates that the inhibitor inhibited corrosion by physisorption (involving electrostatic attraction between the charged of inhibitor molecules and the charged of metal surface) to form a monolayer on the metal surface so that corrosion will be obstructed. Inhibition efficiency of triazine-based inhibitor was concentration dependent. The optimum inhibition efficiency is 68,674% in 150 ppm concentration of triazine as a result of Electrochemical Impedance Spectroscopy test."

"Kemampuan inhibitor triazine dalam menginhibisi baja karbon API 5L X60 dalam lingkungan NaCl 3.5% diinvestigasi dengan menggunakan metode Electrochemical Impedance Spectroscopy (EIS) dalam berbagai variasi konsentrasi. Konsentrasi yang digunakan pada pada penelitian kali ini adalah 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm, 250 ppm. Hasil pengujian menunjukkan bahwa ketika melewati konsentrasi optimum (150 ppm), nilai Rct dan efisiensi inhibitor akan berada pada nilai yang konstan, yang masing-masing nilainya adalah 581 Ω dan 68.6 %. Plot impedansi vs frekuensi yang ditunjukkan oleh kurva Bode Modulus mendukung hasil analisis data sebelumnya yang menunjukkan nilai ketahanan pada konstrasi 150 ppm memiliki ketahanan yang paling besar pada frekuensi rendah maupun tinggi.

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The performance of Triazine based commercial corrosion inhibitor on carbon steel API 5L X60 on NaCl 3.5% solutions was investigated using Electrochemical Impedance Spectroscopy methods. Inhibitor concentration which used in these experiments was 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm, and 250 ppm. Experimental results showed that when the concentration is above the optimum?s one (150 ppm), Rct and inihibitor efficiency value would be on a constant value, which each value is 581 Ω and 68.6 %. Plot of impedance vs frequency which showed by Bode Modulus curve support the previous data analysis, that the impedance value on 150 ppm had the highest impedance, at the low and high frequency."

"Kemampuan inhibitor Triazine dalam menginhibisi baja karbon API-5L X60 dalam lingkungan NaCl 3.5% diinvestigasi dengan menggunakan metode Polarisasi Linier Linier Polarization Resistance (LPR) dalam berbagai variasi konsentrasi. Konsentrasi yang digunakan pada penelitian kali ini adalah 0 ppm, 50 ppm, 10 ppm, 150 ppm, 200 ppm, dan 250 ppm. Hasil pengujian menunjukkan bahwa konsentrasi optimum dalam menurunkan laju korosi terdapat pada 150 ppm dengan laju korosi sebesar 0,4457841 mm/year, sedangkan nilai Rp terus meningkat dan optimum pada konsentrasi 250 ppm dengan nilai sebesar 838,85 Ohm. Kurva laju korosi vs konsentrasi inhibitor menunjukkan bahwa konsentrasi optimum inhibitor Triazine dalam menurunkan laju korosi terdapat pada konsentrasi 150 ppm. Efisiensi terbesar terdapat pada konsentrasi 150 ppm dengan nilai 63,94% dan berdasarkan Rp nilai efisiensi optimum pada konsentrasi 250 ppm dengan nilai sebesar 55,16%. Kinerja inhibitor pada pengujian ini masih kurang baik karena masih jauh dari efisiensi inhibitor yang baik yaitu rentang nilai 85-90%.

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The performance of Triazine based commercial corrosion inhibitor on carbon stel API 5L X60 on NaCl 3.5 % solution was investigated using Linear Polarization Resistance Method or LPR. The Inhibitor concentration that used in this experiment were 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm, and 250 ppm. Experimental results showed that the optimum concentration to decrease the corrosion rate is 150 ppm with the corrosion rate in 0,4457841 mm/year , while the optimum polarization resistance is 838,85 Ohm at 250 ppm. The plot of corrosion rate vs inhibitor concentration show the optimum Triazine inhibitor concentration for decreasing corrosion rate is 150 ppm. There optimum efficiency at a concentration of 150 ppm of 63.94 % and Rp optimum efficiency at a concentration of 250 ppm of 55.16 % . Inhibitor performance is still not good because it is still far from a good inhibitor efficiency is 85-90 % range of values."

"Mekanisme inhibisi korosi dari inhibitor berbahan dasar imidazoline pada baja API 5L Grade B di lingkungan NaCl 3,5% diinvestigasi dengan menggunakan metode model adsorpsi yang didapat dari hasil pengujian Tafel Polarisasi, Linier Polarisasi dan Electrochemical Impedance Spectroscopy (EIS) dengan menggunakan variasi konsentrasi 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm dan 250 ppm. Senyawa imidazoline yang teradsorpsi pada permukaan logam diinvestigasi dengan menggunakan pengujian Fourier Transform InfraRed (FTIR). Hasilnya didapatkan bahwa proses adsorpsi inhibitor imidazoline terjadi secara spontan mengikuti mode adsorpsi Langmuir isoterm. Berdasarkan nilai Goads antara -16,2 kJ/mol sampai -17,5 kJ/mol menunjukkan bahwa inhibitor imidazoline menginhibisi korosi dengan cara adsorpsi fisika (interaksi elektrostatis antara muatan negatif molekul inhibitor dengan muatan positif permukaan logam) membentuk lapisan tunggal di permukaan logam sehingga dapat menghambat proses korosi. Besarnya efisiensi inhibisi inhibitor berbahan dasar imidazoline bergantung pada konsentrasi inhibitor. Efisiensi inhibisi tertinggi diperoleh pada konsentrasi imidazoline 250 ppm sebesar 72,69% berdasarkan hasil pengujian Linier polarisasi.

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Corrosion inhibition mechanism of imidazoline-based corrosion inhibitor on API 5L Grade B steel in 3.5% NaCl environment was investigated by using adsorption method from the results of tafel polarization, linier polarization resistance (LPR), and Electrochemical Impedance Spectroscopy (EIS) tests with 0 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm and 150 ppm concentration variation. Imidazoline compounds which adsorbed on metal surface was also investigated by Fourier Transform InfraRed (FTIR) test. It was found that adsorption process of imidazoline-based inhibitor occurs spontaneously and follow the Langmuir adsorption isotherm. From the calculation of Goads (around -16,2 kJ/mol to -17,5 kJ/mol), it indicates that the inhibitor inhibited corrosion by physisorption (involving electrostatic attraction between the negative charged of inhibitor molecules and the positive charged of metal surface) to form a monolayer on the metal surface so that corrosion will be obstructed. Inhibition efficiency of imidazoline-based inhibitor was concentration dependent. The optimum inhibition efficiency is 72,69% in 250 ppm concentration of imidazoline as a result of LPR test."

"[ABSTRAKKemampuan inhibitor Triazine dalam menginhibisi baja karbon API 5L X60 dalam lingkungan NaCl 3.5% diinvestigasi dengan menggunakan metode Polarisasi Tafel dalam berbagai variasi konsentrasi. Konsentrasi yang digunakan pada penelitian kali ini adalah 0 ppm, 50 ppm, 10 ppm, 150 ppm, 200 ppm, dan 250 ppm. Efisiensi optimum yang didapatkan adalah sebesar 50.28% dengan konsentrasi inhibitor triazine sebesar 150 ppm. Dengan pengujian FTIR, maka dibuktikan bahwa senyawa triazine mampu menginhibisi permukaan baja API 5L X60. Penelitian ini juga membuktikan bahwa inhibitor triazine merupakan inhibitor korosi karena mampu menurunkan laju korosi.Inhibitor triazine termasuk kedalam jenis inhibitor campuran.

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ABSTRACT

The corrosion rate from Triazine-based inhibitors on API 5-L X60 steel at NaCl 3,5% environtment were investigated using the Tafel Polarization method. The Triazine compounds that successfully absorbed onto steel surface were investigated using the Fourier Transform Infra Red (FTIR). Triazine?s efficiency depends on the concentration that given onto environtment. The highest efficiency of Triazine inhibitor is 50.28% with the optimize concentration 150 ppm. The investigated Triazine inhibitors were proven as the corrosion inhibitors because it can reduces the corrosion rate. Triazine inhibitors are also mixed type inhibitors.;The corrosion rate from Triazine-based inhibitors on API 5-L X60 steel at NaCl 3,5% environtment were investigated using the Tafel Polarization method. The Triazine compounds that successfully absorbed onto steel surface were investigated using the Fourier Transform Infra Red (FTIR). Triazine?s efficiency depends on the concentration that given onto environtment. The highest efficiency of Triazine inhibitor is 50.28% with the optimize concentration 150 ppm. The investigated Triazine inhibitors were proven as the corrosion inhibitors because it can reduces the corrosion rate. Triazine inhibitors are also mixed type inhibitors. , The corrosion rate from Triazine-based inhibitors on API 5-L X60 steel at NaCl 3,5% environtment were investigated using the Tafel Polarization method. The Triazine compounds that successfully absorbed onto steel surface were investigated using the Fourier Transform Infra Red (FTIR). Triazine’s efficiency depends on the concentration that given onto environtment. The highest efficiency of Triazine inhibitor is 50.28% with the optimize concentration 150 ppm. The investigated Triazine inhibitors were proven as the corrosion inhibitors because it can reduces the corrosion rate. Triazine inhibitors are also mixed type inhibitors. ]"

"Aluminium 2024 (Al 2024) merupakan salah satu jenis paduan aluminium komersil dengan tembaga sebagai paduan utamanya. Jenis paduan ini sudah sejak lama digunakan dalam industri otomotif, penerbangan, dan militer. Keberadaan unsur Cu sebagai paduan utama memberikan efek penguatan pada segi mekanis tetapi melemahkan sifat korosinya. Anodisasi merupakan salah satu metode perlindungan aluminium paduan dari korosi menggunakan prinsip elektrokimia yang cepat, sederhana dan ekonomis. Variasi tegangan dan waktu dilakukan untuk melihat pengaruh parameter terhadap ketebalan serta ketahanan korosi Al 2024. Proses anodisasi dilakukan pada larutan H2SO4 30% pada temperatur ruang.Hasil dari material anodisasi kemudian diuji pada medium korosif NaCl 3,5% selama 6 hari melalui proses immersion test. Ketebalan lapisan oksida paling efektif diperoleh pada anodisasi dengan parameter tegangan 15 V dan waktu 10 menit. Sebagian besar sampel uji menunjukkan trend yang sama dan indikasi terjadinya korosi sumuran (pitting corrosion) disertai munculnya endapan pada permukaan. Perlakuan anodisasi yang memberikan proteksi berupa lapisan oksida dibuktikan dengan kehadiran fasa α-Al2O3 and ɣ-Al2O3 dalam pengujian XRD. Pengamatan SEM dan mikroskop optik memperlihatkan penampakan permukaan Al 2024 setelah 6 hari immersion test pada larutan NaCl 3,5%.

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Aluminium Alloy 2024 (Al 2024) is one of commercial alloy with copper as the main alloy. This alloy has been used in many industrial application such as automotive, aerospace, and military. Copper as a major alloying elements gives a mechanical strengthening effect but weaken the corrosion resistance. Anodizing is fast, simple, and economical method to protect aluminium from corrosion with the principal of electrochemical. The variations of anodizing voltage and time have been done with 30% H2SO4 electrolyte at room temperature to analyze its influence on thickness and corrosion behaviour of Al 2024.

Results of anodizing were then tested by immerse the samples in 3,5% NaCl solution for 6 days. The thickness of the oxide layer is most effective with the parameters obtained in anodizing voltage of 15 V and 10 minutes. Most of samples show the similar trend and indications of pitting corrosion along with the presence of deposition on its surface. Anodizing proccess gives the protection layer aluminium oxide which is proved by the presence of α-Al2O3 and ɣ-Al2O3 phase in XRD testing. SEM and optical microscope observation show the surface appearence of Al 2024 after immersion test for 6 days in 3,5% NaCl solution."

"Penelitian tentang perilaku dan ketahanan korosi pada baja tahan karat austenitik seri 304L telah dilakukan pada variasi konsentrasi larutan NaCl terkait dengan ketahanannya pada korosi sumuran. Penelitian dilakukan dengan metode polarisasi siklik pada temperatur ruang untuk mengevaluasi perilaku korosi yang terjadi dengan mempertimbangkan faktor potensial korosi Ecor dan potensial proteksi Ep . Larutan NaCl yang digunakan pada pengujian memakai konsentrasi sebesar 1 , 2 , 3.5 , 4 , dan 5. Representasi hasil percobaan polarisasi siklik didapatkan melalui grafik polarisasi siklik baja tahan karat austenitik seri 304L yang menunjukkan nilai dari potensial korosi Ecor dan potensial proteksi Ep.Hasil yang didapatkan akan dipengaruhi oleh faktor konsentrasi NaCl, komposisi kimia material, dan konsentrasi oksigen terlarut pada larutan NaCl. Urutan hasil ketahanan korosi dari yang paling rendah ke yang paling tinggi adalah 3.5 , 4 , 5 , 2 , dan 1 . Ketahanan korosi terendah didapatkan pada konsentrasi NaCl 3.5 dimana hampir sama dengan keadaan air laut dengan kelarutan oksigen pada larutan dalam keadaan maksimum.

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Corrosion behavior of austenitic stainless steels type 304L in various concentrations of aqueous sodium chloride solutions were investigated related to its pitting corrosion resistance. Experimental testing was carried out by using cyclic polarization method at room temperature 27oC to evaluate the corrosion mechanism by considering breakdown potential Ecor and protection potential Ep. Aqueous sodium chloride solutions were prepared with various concentration i.e. 1 , 2 , 3.5 , 4 and 5 w v. The testing results were represented by cyclic potentiodynamic polarization curves for both alloys which showed potentials that indicated the onset of potentials Ecor and Ep respectively.

The results were influenced by sodium chloride concentrations and the chemical composition of alloys. Rank of the values of Ecor and Ep of 304L and 316L at various sodium chloride concentrations from the highest to the lowest were 1 , 2 , 5 , 4 , 3,5 w v NaCl consecutively. It was observed that the lowest corrosion resistance of both alloys was at 3,5 w v NaCl which was similar to typical seawater solution with maximum dissolved oxygen solubility."

"Korosi merupakan kegagalan yang sering terjadi pada industri minyak dan gas bumi Menghambat terjadinya korosi dengan mengisolir logam dari lingkungan terkorosi pada industri minyak dan gas bumi merupakan salah satu cara efektif untuk menghindari terjadi kegagalan korosi. Penggunaan inhibitor alami menjadi pihan utama belakang ini karena aman murah dan yang terpenting bahan tersebut biodegradable dan tidak berbahaya bagi lingkungan. Penelitian ini dilakukan untuk melihat efek dari penambahan teh rosella merah terhadap inhibitor ubi ungu yang memang dapat digunakan menjadi inhibitor pada baja API 5L pada lingkungan NaCl 3 5. Pengujian ini dilakukan dengan menggunakan metode kehilangan berat dan polarisasi untuk melihat laju korosi yang terjadi pada logam lalu dilengkapi dengan data tambahan yaitu pengujian Electrochemical Impedance Spectroscopy untuk melihat tahan permukaan yang berbubah pada penelitian tersebut. Pengujian Fourier Transform Infra Red juga dilakukan untuk melihat kandungan yang menginhibisi dari ubi ungu ataupun campuran ubi ungu dan teh rosella merah Pemilihan teh rosella merah dan ubi ungu berdasarkan kandungan antocyanin dan asam askorbat yang dimiliki kedua bahan tersebut Kandungan tersebut bersifat anti oksidan yang berarti dapat menghambat terjadi proses oksidasi yang berarti juga dapat mencegah korosi. Kandungan anti oksidan tersebut bekerja dengan cara adsoprsi pada permukaan logam membentuk lapisan tipis untuk mencegah kontak antara permukaan logam dengan lingkungan korosif. Salah satu faktor pembentukan lapisan tipis pada permukaan adalah konsentrasi kandungan tersebut sehingga pengaruh konsentrasi dijadikan acuan pada penelitian ini. Penelitian ini akan dibandingkan dengan inhibitor ubi ungu yang hanya dicampur dengan kandungan asam askorbat saja.

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Corrosion is major cause failure in oil ad gas industry Isolate the metal from corrosion of materials is the most effective way to prevent corrosion for this industry. Nowadays the use of green corrosion inhibitor become a new alternative to achieve that goal it happen because the green inhibitor is safe cheap biodegradable and especially environmental friendly.

This study was conducted to study the effect of addition rosella red tea in purple sweet potato inhibitor which is can be use as inhibitor at API 5L in NaCl 3 5 solution. This study use weight loss and polarization method to see that effect and Electrochemical Impedance Spectroscopy test to prove alteration surface resistance when we add the inhibitor.

Fourier Transform Infra Red test also perform in this study to see which one the chemical substance in purple sweet potato and mixture rosella red tea and purple sweet potato can inhibit corrosion. Purple sweet potato and rosella red tea are selected as corrosion inhibitor in this study because they contain antocyanin and ascorbid acid. They are antioxidant compound which is can inhibit oxidation process it means they can prevent corrosion process. That substance inhibit metal by forming layer and isolate metal surface On the important factor to forming thin layer is concentration of the substance so the concentration substance become variable in this study. In the end this study will compared with the addition ascorbid acid in purple sweet potato"

"Perilaku korosi dari baja tahan karat duplex 2205 dan feritik 410s diamati dalam berbagai konsentrasi larutan sodium klorida. Rangkaian pengujian dilakukan dengan menggunakan metode Electrochemical Impedance Spectroscopy pada suhu ruang. Metode ini dilakukan untuk mengamati impedansi dari material uji. Konsentrasi larutan klorida disiapkan dengan variasi 1, 2, 3, 4 dan 5 w.t. Hasil pengujian terhadap kedua sampel menyatakan bahwa sistem dengan ketahanan korosi paling rendah adalah sistem yang menggunakan 3,5 w.t sodium klorida, yang serupa dengan kandungan klorida air laut. Hasil pengujian juga menyatakan bahwa baja tahan karat duplex 2205 secara umum lebih tahan korosi dibandingkan dengan feritik 410s pada setiap konsentrasi klorida.

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Corrosion behaviour of SS 2205 and SS 410s were investigated in various concentrations of aqueous sodium chloride solutions. Experimental work was carried out by using electrochemical impedance spectroscopy method at room temperature to evaluate the impedance of the system. Sodium chloride solutions were prepared with various concentration i.e. 1, 2, 3.5, 4 and 5 w.t. The testing results were represented by Nyquist plot for both alloys. It was observed that the lowest corrosion resistance of both alloys was at 3,5 w.t NaCl which was similar to typical seawater solution. It was also observed that SS 2205 had better corrosion resistance along with greater impedance than the SS 410s in every NaCl concentration."

"ABSTRAKLaju korosi dari inhibitor dengan bahan dasar Imidazoline pada baja API 5-L Grade B dalam lingkungan NaCl 3,5% diinvestigasi dengan menggunakan metode polarisasi Tafel. Senyawa Imidazoline yang berhasil teradsorpsi ke permukaan logam diselidiki dengan menggunakan pengujian FTIR. Efisiensi inhibisi inhibitor Imidazoline bergantung pada konsentrasi inhibitor yang diberikan. Efisiensi optimum yang diperoleh 64,80 % dengan konsentrasi optimum 150 ppm. Inhibitor Imidazolin yang diselidiki merupakan jenis inhibitor campuran. Inhibitor Imidazoline juga dikatakan sebagai inhibitor korosi karena terbukti dapat menurnkan laju korosi.

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ABSTRACTThe corrosion rate from Imidazoline-based inhibitors on API 5-L Grade B steel at NaCl 3,5% environtment were investigated using the Tafel Polarization method. The Imidazoline compounds that successfully absorbed onto steel surface were investigated using the Fourier Transform Infra Red (FTIR). Imidazolin’s efficiency depends on the concentration that given onto environtment. The highest efficiency of Imidazoline inhibitor is 64,80% with the optimize concentration 150 ppm. The investigated Imidazoline inhibitors were proven as the corrosion inhibitors because it can reduces the corrosion rate. Imidazoline inhibitors are also mixed type inhibitors."