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Samuel Christian Giovanni
Modifikasi bitumen dengan lignin dan kantong kresek high density polyetylene (HDPE) = Modification of bitumen with lignin and high density polyetylene (HDPE) plastic
"[ABSTRAK
Pada aplikasinya, konstruksi jalan masih memiliki banyak kelemahan antara lain mudah rusak pada saat terdapat genangan air sehingga akan memperpendek umur pakai jalan. Pada penelitian ini akan dilakukan modifikasi dari bitumen yang merupakan bahan utama pembuatan jalan dengan cara penambahan High Density Polyehtylene (HDPE) dan liginin pada campuran bitumen pen 60/70. Hal ini dapat menurunkan nilai penetrasi sehingga menjadikan bitumen lebih keras dan tahan ketika diberikan beban kendaraan yang berulang, meningkatkan titik lembek, dan menurunkan daktilitas. Selain itu, penambahan lignin sebagai coupling agent dapat meningkatkan kompaktibilitas antara HDPE dengan bitumen karena lignin yang memiliki gugus polar dan non-polar. Kadar lignin yang digunakan yaitu 0,1%, 0,3%, dan 0,5%. Selain itu, penelitian ini juga ingin mengetahui pengaruh temperatur proses yaitu 140˚C, 160˚C dan 180˚C dan waktu pencampuran yaitu 15, 30, dan 45 menit terhadap sifat bitumen hasil modifikasi. Untuk itu dilakukan pengujian mekanik dan karakterisasi campuran untuk melihat kekuatan dari bitumen dan kompatibilitas antara bitumen, HDPE, dan lignin. Pengujian dilakukan melalui uji daktilitas, penetrasi, dan titik lembek. Sedangkan, karakterisasi dilakukan dengan menggunakan Fourier Transform Infrared (FTIR), Thermo Gravimetric Analyzer (TGA), dan Differential Scaning Calorimetry (DSC). Dari hasil pengujian menunjukkan semakin tinggi kadar dari liginin dan semakin tinggi temperatur proses yang digunakan maka semakin tinggi juga kekuatan bitumen modifikasi dalam menahan beban serta semakin tinggi ketahanan termalnya. Kompatibilitas yang baik didapat pada penambahan lignin 0,5% dan temperatur proses 180&#deg;C.
ABSTRACT
In the application, road construction still has some weakness such as easily damaged, especially when wet patch of water exists. In this case, it will shorten the lifespan of the road. In this study, therefore, the main purpose is to modify the bitumen, which is the main ingredient of asphalt for road construction. The work was performed by adding high density polyethylene (HDPE) and lignin into the bitumen mix pen 60/70. It was expected that it could decrease the penetration?s value so it will make the asphalt harder and resistant to the load, increase the softening point, and thus lower the ductility. The addition of lignin was expected to function as a coupling agent and could increase the compatibility between HDPE and bitumen. This can be understood since lignin has a polar and a non-polar groups. Concentration of lignin used was 0.1, 0.3, and 0.5 wt.% at processing temperature of 140oC, 160oC and 180oC and mixing times of 15, 30, and 45 minutes. Characterization was performed by using a Fourier Transform Infrared (FTIR), Thermogravimetric Analyzer (TGA), and Differential Scanning Calorimetry (DSC), whereas the mechanical testing of the modified bitumen was performed through ductility testing, penetration, and softening point. The results showed that high level of lignin and high temperature of the process resulted in high strength of the modified bitumen and so does the thermal resistance. The best result was obtained in the addition of 0.5 wt.% lignin at a process temperature of 180°C.;In the application, road construction still has some weakness such as easily damaged, especially when wet patch of water exists. In this case, it will shorten the lifespan of the road. In this study, therefore, the main purpose is to modify the bitumen, which is the main ingredient of asphalt for road construction. The work was performed by adding high density polyethylene (HDPE) and lignin into the bitumen mix pen 60/70. It was expected that it could decrease the penetration?s value so it will make the asphalt harder and resistant to the load, increase the softening point, and thus lower the ductility. The addition of lignin was expected to function as a coupling agent and could increase the compatibility between HDPE and bitumen. This can be understood since lignin has a polar and a non-polar groups. Concentration of lignin used was 0.1, 0.3, and 0.5 wt.% at processing temperature of 140oC, 160oC and 180oC and mixing times of 15, 30, and 45 minutes. Characterization was performed by using a Fourier Transform Infrared (FTIR), Thermogravimetric Analyzer (TGA), and Differential Scanning Calorimetry (DSC), whereas the mechanical testing of the modified bitumen was performed through ductility testing, penetration, and softening point. The results showed that high level of lignin and high temperature of the process resulted in high strength of the modified bitumen and so does the thermal resistance. The best result was obtained in the addition of 0.5 wt.% lignin at a process temperature of 180oC., In the application, road construction still has some weakness such as easily damaged, especially when wet patch of water exists. In this case, it will shorten the lifespan of the road. In this study, therefore, the main purpose is to modify the bitumen, which is the main ingredient of asphalt for road construction. The work was performed by adding high density polyethylene (HDPE) and lignin into the bitumen mix pen 60/70. It was expected that it could decrease the penetration’s value so it will make the asphalt harder and resistant to the load, increase the softening point, and thus lower the ductility. The addition of lignin was expected to function as a coupling agent and could increase the compatibility between HDPE and bitumen. This can be understood since lignin has a polar and a non-polar groups. Concentration of lignin used was 0.1, 0.3, and 0.5 wt.% at processing temperature of 140oC, 160oC and 180oC and mixing times of 15, 30, and 45 minutes. Characterization was performed by using a Fourier Transform Infrared (FTIR), Thermogravimetric Analyzer (TGA), and Differential Scanning Calorimetry (DSC), whereas the mechanical testing of the modified bitumen was performed through ductility testing, penetration, and softening point. The results showed that high level of lignin and high temperature of the process resulted in high strength of the modified bitumen and so does the thermal resistance. The best result was obtained in the addition of 0.5 wt.% lignin at a process temperature of 180oC.]"
Depok: Fakultas Teknik Universitas Indonesia, 2016
S61894
UI - Skripsi Membership  Universitas Indonesia Library
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Yermia Andri Prawira
Modifikasi bitumen dengan penambahan high density polyethylene (HDPE) dan polypropylene serta lignin melalui metode hot melt mixing = Modified bitumen with addition of high density polyethylene (HDPE) and polypropylene and lignin through hot melt mixing method
"Penelitian ini bertujuan mencari solusi permasalahan seperti kerusakan aspal, pencemaran lingkungan oleh limbah plastik dan lignin. Melalui studi literatur, ditemukan plastik dapat menguatkan sifat aspal yang lemah terhadap air. Namun, aspal dan plastik tidak kompatibel karena sifat aspal yang hidrofilik dan sifat plastik yang hidropobik. Oleh karena itu, lignin yang mempunyai kedua sifat tersebut digunakan sebagai coupling agent. Bitumen pen 60/70 dimodifikasi dengan menambahkan plastik Polipropilena PP dan High Density Polyethylene HDPE lalu dicampur melalui metode Hot Melt Mixing. Variabel tetapnya ialah waktu, temperatur proses, dan putaran alat pengaduk yaitu 30 menit, 180oC, dan 60 rpm. Variabel bebasnya ialah komposisi campuran PP yaitu 3wt, 4wt, 5wt, HDPE yaitu 5wt, 6wt, 7wt dan lignin. Putaran pertama proses sampel tidak ditambahkan lignin, putaran kedua sampel ditambahkan lignin 0,3wt. Setelah itu, hasil proses campuran yang disebut Polymer Modified Bitumen PMB, dikarakterisasi. Karaterisasi sifat kimia campuran menggunakan Fourier Transform Infrared FTIR, Thermo Gravimetric Analyzer TGA, dan Differential Scanning Calorimetry DSC dan karakterisasi mekanik sifat penetrasi, daktilitas, dan titik lembek. Hasil pengujian menunjukkan Polyblend PP/HDPE menambah sifat mekanik bitumen, lignin meningkatkan kompatibilitas antara bitumen dan plastik, serta diperlukan coupling agent tambahan untuk menyatukan antar plastik PP dan HDPE yang viskositasnya berbeda.
This study aims to find solutions to problems such as damage to the asphalt, pollution of environment by plastic waste and lignin. Through literature, discovered the plastic can strengthen the weak nature of the asphalt to water. However, asphalt and plastics are not compatible because of the nature of the asphalt hydrophilic and hydrophobic properties of the plastic. Therefore, lignin which has both these properties is used as a coupling agent. 60 70 bitumen modified by adding plastic Polypropylene PP and High Density Polyethylene HDPE and then mixed with Hot Melt Mixing method. Fixed variable is time, process temperature, and mixer rotation which are 30 minutes, 180 C, and 60 rpm. The independent variables are the composition of the mixture of PP i.e. 3wt, 4wt, 5wt, HDPE i.e. 5wt, 6wt, 7wt and lignin. The first round of the sample is not added lignin, the second round of sample was added lignin 0,3wt. After that, the process results, a mixture called Polymer Modified Bitumen PMB, characterized. Chemical properties characterization of the mixture using a Fourier Transform Infrared FTIR, Thermo Gravimetric Analyzer TGA, and Differential Scanning Calorimetry DSC and the characterization of the mechanical properties of penetration, ductility, and the softening point. The test results showed polyblend PP HDPE adds to the mechanical properties of bitumen, lignin improve the compatibility between bitumen and plastic, as well as additional coupling agent is required to bring together between PP and HDPE plastic which different viscosity."
Depok: Fakultas Teknik Universitas Indonesia, 2016
S65605
UI - Skripsi Membership  Universitas Indonesia Library
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Richa Syahwalia
Modifikasi bitumen dengan penambahan high density polyethylene hdpe atau polypropylene pp dengan metode hot melt mixing = Modification of bitumen by high density polyethylene hdpe or polypropylene pp with hot melt mixing
"[ ABSTRAK
Bitumen merupakan bahan penyusun aspal serta memiliki fungsi sebagai binder pada aspal. Sifat dari bitumen mempengaruhi kinerja dari aspal. Aspal merupakan material yang biasanya digunakan untuk infrastruktur seperti aplikasi pada jalanan. Aspal merupakan material yang relatif murah namun aspal memiliki beberapa kelemahan karena sifat material penyusunya dan kondisi lingkungan sehingga dibutuhkan langkah untuk menangani kelemahan pada aspal tersebut. Salah satu metode yang dapat dilakukan untuk menangani masalah tersebut adalah melakukan pencampuran bitumen (bahan pengikat pada aspal) dengan limbah plastik kresek (high density polyehtylene atau polypropylene) untuk membentuk suatu komposit Polymer Modified Bitumen (PMB) sehingga perfoma dari aspal dapat meningkat dan membuat limbah plastik lebih berguna kembali. Percobaan ini mengunakan 2 buah jenis plastik kresek dan 3 buah variabel berbeda yaitu konsentrasi plastik kresek, waktu, dan temperatur pencampuran. Plastik kresek yang digunakan adalah HDPE dan PP. Konsentrasi High Density Polyethyelene (HDPE) yang digunakan adalah 4%, 5%, dan 6%, konsentrasi Polypropylene (PP) yang digunakan adalah 3%, 4%, dan 5%, waktu pencampuran yang digunakan adalah 15, 30, dan 45 menit, dan juga temperatur pencampuran yang digunakan adalah 140oC sampai dengan 200oC. Metode pencampuran basah digunakan untuk mencampurkan kedua material tersebut. Hasil atau kualitas komposit diketahui dengan melakukan investigasi melalui pengujian penetrasi, daktilitas, titik lembek, Scanning Electron Microscope (SEM), Fourier Transform Infrared (FTIR), Thermo Gravimetric Analyzer (TGA), dan Differential Scaning Calorimetry (DSC). Hasil penelitian mengenai PMB menyimpulkan bahwa kompatibiltas antara plastik kresek baik HDPE dan PP kurang baik terhadap bitumen namun penambahaan plastik kresek terhadap bitumen meningkatkan sifat mekanik dan kestabilan termal bitumen.
ABSTRACT Bitumen is a binder and one of constituents of asphalt so the characteristic of bitumen affects asphalt perfomance. Asphalt is a material that usually used in road application. However, there are also drawbacks of asphalt as material on pathway because of its constituents and environment condition. For the examples, asphalt is brittle in low temperature and will be soften when temperature increase so the action is needed to address this problems. One solution to solve these problems by adding wasted plastic bags made by High Density Polyethylene (HDPE) or Polypropylene (PP) to bitumen so it can increase asphalt efficiency and make wasted plastic bag more useful. This experiment used two type of plastic bags and three variables (concentration of plastic bags, mixing time, and mixing temperature). HDPE concentrations used were 4%, 5%, and 6%, PP concentrations used were 3%, 4%, and 5%, mixing times used were 15, 30, and 45 minutes, and also mixing temperatures were 140oC up to 200oC. Hot melt mixing method was used to mix those material. The quality of mixing material (composite) was tested by some instruments like ductility tester, softening point tester, penetration testing, Scanning Electron Microscope (SEM), Fourier Transform Infrared (FTIR), Thermo Gravimetric Analyzer (TGA) and Differential Scaning Calorimetry (DSC). The result is compatibilty of HDPE or PP to bitumen is not that enough, however, modification of bitumen by plastic bags increases mechanical properties and thermal resistance of bitumen.;Bitumen is a binder and one of constituents of asphalt so the characteristic of bitumen affects asphalt perfomance. Asphalt is a material that usually used in road application. However, there are also drawbacks of asphalt as material on pathway because of its constituents and environment condition. For the examples, asphalt is brittle in low temperature and will be soften when temperature increase so the action is needed to address this problems. One solution to solve these problems by adding wasted plastic bags made by High Density Polyethylene (HDPE) or Polypropylene (PP) to bitumen so it can increase asphalt efficiency and make wasted plastic bag more useful. This experiment used two type of plastic bags and three variables (concentration of plastic bags, mixing time, and mixing temperature). HDPE concentrations used were 4%, 5%, and 6%, PP concentrations used were 3%, 4%, and 5%, mixing times used were 15, 30, and 45 minutes, and also mixing temperatures were 140oC up to 200oC. Hot melt mixing method was used to mix those material. The quality of mixing material (composite) was tested by some instruments like ductility tester, softening point tester, penetration testing, Scanning Electron Microscope (SEM), Fourier Transform Infrared (FTIR), Thermo Gravimetric Analyzer (TGA) and Differential Scaning Calorimetry (DSC). The result is compatibilty of HDPE or PP to bitumen is not that enough, however, modification of bitumen by plastic bags increases mechanical properties and thermal resistance of bitumen.;Bitumen is a binder and one of constituents of asphalt so the characteristic of bitumen affects asphalt perfomance. Asphalt is a material that usually used in road application. However, there are also drawbacks of asphalt as material on pathway because of its constituents and environment condition. For the examples, asphalt is brittle in low temperature and will be soften when temperature increase so the action is needed to address this problems. One solution to solve these problems by adding wasted plastic bags made by High Density Polyethylene (HDPE) or Polypropylene (PP) to bitumen so it can increase asphalt efficiency and make wasted plastic bag more useful. This experiment used two type of plastic bags and three variables (concentration of plastic bags, mixing time, and mixing temperature). HDPE concentrations used were 4%, 5%, and 6%, PP concentrations used were 3%, 4%, and 5%, mixing times used were 15, 30, and 45 minutes, and also mixing temperatures were 140oC up to 200oC. Hot melt mixing method was used to mix those material. The quality of mixing material (composite) was tested by some instruments like ductility tester, softening point tester, penetration testing, Scanning Electron Microscope (SEM), Fourier Transform Infrared (FTIR), Thermo Gravimetric Analyzer (TGA) and Differential Scaning Calorimetry (DSC). The result is compatibilty of HDPE or PP to bitumen is not that enough, however, modification of bitumen by plastic bags increases mechanical properties and thermal resistance of bitumen.;Bitumen is a binder and one of constituents of asphalt so the characteristic of bitumen affects asphalt perfomance. Asphalt is a material that usually used in road application. However, there are also drawbacks of asphalt as material on pathway because of its constituents and environment condition. For the examples, asphalt is brittle in low temperature and will be soften when temperature increase so the action is needed to address this problems. One solution to solve these problems by adding wasted plastic bags made by High Density Polyethylene (HDPE) or Polypropylene (PP) to bitumen so it can increase asphalt efficiency and make wasted plastic bag more useful. This experiment used two type of plastic bags and three variables (concentration of plastic bags, mixing time, and mixing temperature). HDPE concentrations used were 4%, 5%, and 6%, PP concentrations used were 3%, 4%, and 5%, mixing times used were 15, 30, and 45 minutes, and also mixing temperatures were 140oC up to 200oC. Hot melt mixing method was used to mix those material. The quality of mixing material (composite) was tested by some instruments like ductility tester, softening point tester, penetration testing, Scanning Electron Microscope (SEM), Fourier Transform Infrared (FTIR), Thermo Gravimetric Analyzer (TGA) and Differential Scaning Calorimetry (DSC). The result is compatibilty of HDPE or PP to bitumen is not that enough, however, modification of bitumen by plastic bags increases mechanical properties and thermal resistance of bitumen., Bitumen is a binder and one of constituents of asphalt so the characteristic of bitumen affects asphalt perfomance. Asphalt is a material that usually used in road application. However, there are also drawbacks of asphalt as material on pathway because of its constituents and environment condition. For the examples, asphalt is brittle in low temperature and will be soften when temperature increase so the action is needed to address this problems. One solution to solve these problems by adding wasted plastic bags made by High Density Polyethylene (HDPE) or Polypropylene (PP) to bitumen so it can increase asphalt efficiency and make wasted plastic bag more useful. This experiment used two type of plastic bags and three variables (concentration of plastic bags, mixing time, and mixing temperature). HDPE concentrations used were 4%, 5%, and 6%, PP concentrations used were 3%, 4%, and 5%, mixing times used were 15, 30, and 45 minutes, and also mixing temperatures were 140oC up to 200oC. Hot melt mixing method was used to mix those material. The quality of mixing material (composite) was tested by some instruments like ductility tester, softening point tester, penetration testing, Scanning Electron Microscope (SEM), Fourier Transform Infrared (FTIR), Thermo Gravimetric Analyzer (TGA) and Differential Scaning Calorimetry (DSC). The result is compatibilty of HDPE or PP to bitumen is not that enough, however, modification of bitumen by plastic bags increases mechanical properties and thermal resistance of bitumen.]"
Depok: Fakultas Teknik Universitas Indonesia, 2016
S62223
UI - Skripsi Membership  Universitas Indonesia Library
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Erlyna Armya Septimorien
Pengaruh lignin termodifikasi terhadap sifat mekanik HDPE modified bitumen melalui metode hot melt mixing = Effect of modified lignin to the mechanical properties in HDPE modified bitumen using hot melt mixing method
"Pada aplikasinya, konstruksi jalan masih memiliki banyak kelemahan antara lain mudah rusak saat musim hujan dengan kelembaban udara dan genangan air sehingga mengurangi umur pakai jalan. Penelitian ini memodifikasi bitumen yang merupakan bahan utama pembuatan jalan dengan cara penambahan High Density Polyehtylene HDPE dan liginin modifikasi pada campuran bitumen pen 60/70. Hal ini dapat menurunkan nilai penetrasi sehingga menjadikan bitumen lebih keras dan tahan ketika diberikan beban kendaraan yang berulang, dan menurunkan daktilitas. Selain itu, penambahan lignin modifikasi sebagai coupling agent meningkatkan kompatibilitas antara HDPE dengan bitumen karena lignin modifikasi memiliki gugus polar dan non-polar yang berimbang. Kadar lignin yaitu 0,1, 0,3, dan 0,5. Selain itu, penelitian ini juga ingin mengetahui pengaruh suhu proses yaitu 14°C, 16°C dan 18°C dan waktu pencampuran yaitu 30, 45, dan 60 menit terhadap sifat PMB HDPE. Dilakukan pengujian mekanik dan karakterisasi campuran untuk melihat kekuatan dari bitumen dan kompatibilitas antara bitumen, HDPE, dan lignin. Dilakukan uji daktilitas, dan penetrasi. Karakterisasi Fourier Transform Infrared FTIR dan SEM/EDS. PMB HDPE dengan lignin modifikasi memiliki sifat terbaik pada suhu 160°C dan lama pengadukan 60 menit. Komposisi lignin modifikasi dalam PMB HDPE memengaruhi kinerjanya, komposisi yang digunakan melebihi batas lignin modifikasi akan mengikat satu sama lain menjadi gumpalan.
In the application, road construction still has some weakness such as easily damaged, especially in raining season with high humidity and puddle of water, so it will shorten the lifespan of the road. Therefore, this study aims to modify the bitumen which is the main ingredient of bitumen modified for the road by the addition of High Density Polyethylene HDPE and modified lignin on the bitumen mix pen 60 70. It can decrease the penetration rsquo s value so it will makes the asphalt harder and resistant when given the load of vehicle, and lower ductility. Moreover, the addition of modified lignin as a coupling agent can increase compatibility between HDPE and bitumen because modified lignin has a better balanced polar and a non polar group. Concentration of lignin used is 0.1 wt, 0.3 wt and 0.5 wt. In addition, this study also wanted to know the effect of process temperature at 140°C, 160°C and 180°C and mixing times of 30, 45, and 60 minutes to the properties of modified bitumen. Then, mechanical testing and the characterization of modified bitumen aims to see the strength of asphalt and compatibility between bitumen, HDPE, and modified lignin. Testing is done through ductility test, and penetration test. Meanwhile, the characterization is done by using a Fourier Transform Infrared FTIR and SEM EDS. PMB HDPE with modified lignin has the best properties in the suhue of 160°C and stirring time of 60 minutes. The modified lignin composition in the HDPE PMB affects its performance when the composition used exceeds the limit will bind to each other to a lump of agglomerates."
Depok: Fakultas Teknik Universitas Indonesia, 2018
S-Pdf
UI - Skripsi Membership  Universitas Indonesia Library
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Bernhard Eko Hendrasetyawan
Limbah lignin sebagai coupling agent untuk modifikasi bitumen dan limbah polipropilena dengan metode hot melt mixing = Lignin waste as a coupling agent for modified bitumen and polypropylene waste with hot melt mixing method
"Kebutuhan bitumen sebagai bahan baku pembuatan jalan sangat tinggi, limbah kantong plastik dan limbah kertas lignin yang belum dimanfaatkan adalah latar belakang penelitian ini. Tujuan penelitian ini adalah melihat kemampuan limbah lignin sebagai coupling agent antara bitumen dan limbah kantong plastik polipropilena. Metode yang digunakan untuk mencampurkan material ini adalah hot melt mixing. Variabel bebas yang digunakan adalah komposisi lignin 0%, 0,1%, 0,3%, dan 0,5%; temperatur proses 160°C, 180°C, dan 200°C; dan waktu proses 15, 30, dan 45 menit. Karakteristik yang dilakukan adalah FE-SEM, FT-IR, STA, pengujian penetrasi, pengujian daktilitas, dan pengujian titik lembek. Dari hasil pengujian menunjukan bahwa lignin berpengaruh sebagai coupling agent.
Bitumen as raw material of road, untapped waste plastic bags and waste paper lignin is the background of this research. The purpose of this study is to see the ability of waste lignin as a coupling agent between bitumen and waste plastic bags polypropylene. The method used to mix all the materials is hot melt mixing. The independent variable used was the composition of lignin 0%, 0.1%, 0.3% and 0.5%; temperature of the process 160°C, 180°C and 200°C; and processing time of 15, 30 and 45 minutes. To view the properties FE-SEM, FT-IR, STA, penetration test, ductility test, and soft point test. The test results show that lignin has an effect as a coupling agent."
Depok: Fakultas Teknik Universitas Indonesia, 2016
S62968
UI - Skripsi Membership  Universitas Indonesia Library
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Ardellius Matteo
Pengaruh penambahan limbah plastik multilayer dengan lignin sebagai coupling agent terhadap morfologi visual dan sifat fisik polymer modified bitumen = The effects of addition of multilayer plastic waste with lignin as coupling agent on visual morphology and physical properties of polymer modified bitumen.
"Limbah plastik multilayer adalah jenis limbah yang terus bertambah dengan pesat karena tingginya gaya konsumsi masyarakat dan salah satu limbah yang sulit didaur ulang karena sifatnya. Akumulasi dan pembuangan limbah sembarangan dapat menyebabkan potensi risiko permasalahan lingkungan. Salah satu solusi dari permasalahan adalah untuk mengolah limbah plastik. Pengolahan limbah plastik dapat dilakukan dengan membuat Polymer Modified Bitumen (PMB). Namun pencampuran plastik dengan bitumen membutuhkan perantara karena sifat polaritasnya yang berbeda. Lignin yang merupakan hasi limbah kertas industri pulp dapat dijadikan sebagai coupling agent karena memiliki sifat hidrofilik dan hidrofobik. Penelitian ini bertujuan untuk mempelajari pengaruh penambahan limbah plastik multilayer dengan lignin sebagai coupling agent terhadap morfologi visual dan sifat fisik dari Polymer Modified Bitumen. Pembuatan PMB dilakukan dengan metode hot melt mixing pada temperatur 180°C selama 30 menit. Variabel bebas yang digunakan adalah variasi kadar plastik multilayer yang ditambahkan yaitu sebanyak 3%, 4%, dan 5%wt. Observasi morfologi akan dilakukan secara visual dan untuk sifat fisik akan dilakukan pengujian penetrasi, daktilitas, dan titik lembek. Hasil observasi menunjukkan bahwa penambahan plastik multilayer menimbulkan aglomerasi pada permukaan sampel dan meningkatkan kekerasan serta titik lembek namun menurunkan nilai daktilitas.
Multilayer plastic waste is a type of waste that continue to grow rapidly due to people’s consumption styles and is one of the difficult wastes to recycle because of its properties. The accumulation and indiscriminate disposal of waste can pose a potential risk of environmental problems. One solution to the problem is to process the plastic wastes. Plastic waste processing can be done by making Polymer Modified Bitumen (PMB). However, mixing plastic with bitumen requires an intermediary because of the different polarity properties. Lignin which is a waste product of the pulp industry can be used as a coupling agent because it has hydrophilic and hydrophobic properties. This study aims to learn the effects of adding multilayer plastic waste with lignin as a coupling agent on the visual morphology and physical properties of Polymer Modified Bitumen. PMB was made by hot melt mixing method at 180°C for 30 minutes. The independent variable used was the variation of the plastic multilayer content which is 3%, 4%, and 5%. Morphological observations will be carried out visually and for physical properties will be tested for penetration, ductility, and softening point. The results of the observations showed that the addition of multilayer plastic caused agglomeration on the surface of the sample which increased the hardness and softening point but decreased the ductility value."
Depok: Fakultas Teknik Universitas Indonesia, 2021
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UI - Skripsi Membership  Universitas Indonesia Library
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Ardhito Jehian Naindraputra
Pengaruh Penambahan Limbah Plastik Multilayer Berbasis Polipropilena dan Lignin dengan Variabel Waktu Pengadukan dalam Bitumen Menggunakan Metode Hot Melt Mixing Terhadap Sifat Campuran Polymer Modified Bitumen = Effect Addition of Multilayer Polypropylene Based Plastic Waste and Lignin Into Bitumen With Mixing Time Variation To Modified Bitumen Characteristics
"Kebutuhan bitumen sebagai bahan baku dalam pembuatan infrastuktur jalan sangat tinggi, limbah plastik multilayer dan limbah kertas lignin yang belum dimanfaatkan dengan baik adalah latar belakang penelitian ini. Tujuan penelitian ini adalah mempelajari pengaruh waktu pengadukan, penambahan komposisi plastik, dan penambahan lignin terhadap campuran bitumen. Variabel bebas yang digunakan adalah komposisi plastik 3%, 4%, dan 5%wt; waktu pengadukan 15, 30, dan 45 menit. Karakterisasi yang dilakukan adalah SEM, FTIR, TGA, dan Uji Sessile Drop. Hasil pengujian menunjukkan bahwa penambahan plastik multilayer sebagai filler mempengaruhi karakteristik campuran bitumen.
Bitumen needs as main components of asphalt was essential for developing infrastructure technology in Indonesia. Abandoned multilayer plastic and lignin waste are becoming the background of this research. The purpose of this study are to learn the effect of plastic multilayer and lignin addition, and the effect of mixing time variation. Plastic composition 3%, 4%, and 5% wt; mixing time 15, 30, 45 minutes are used as independent variables. Characterization of modified bitumen using SEM, FTIR, TGA, and Sessile Drop Test. The result if this study shows that plastik addition and variation of mixing time affect the characterization of modified bitumen."
Depok: Fakultas Teknik Universitas Indonesia, 2020
S-pdf
UI - Skripsi Membership  Universitas Indonesia Library
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Nofal Lazuardi
Pengaruh penambahan lignin termodifikasi pada campuran bitumen dan polipropilena dengan variabel komposisi, suhu, dan waktu pencampuran = The addition effect of modified lignin to mixture of bitumen and polypropylene with composition temperature and time variable
"ABSTRAK
Indonesia adalah negara penghasil sampah plastik terbesar kedua di dunia setelah China pada tahun 2010 dimana polipropilena adalah salah satu jenis kantong plastik yang banyak digunakan dan sangat non-biodegradable. Selain itu indstri kertas Indonesia banyak menghasilkan limbah pulp lignin yang dimana lignin memiliki sifat sebagai surfaktan dan sifat ini dapat dimodifikasi lebih lanjut. Disisi lain, Indonesia sedang sangat mempercepat pembangunan infrastruktur terutama jalan raya dan membutuhkan bitumen dengan kualitas baik. Sifat fisik bitumen dapat dimodifikasi dengan mencampurkan polimer membentuk polymer modified bitumen PMB . Penelitian ini membahas pengaruh pencampuran bitumen dengan limbah plastik PP sebagai zat pengisi dan lignin termodifikasi sebagai surfaktan penstabil campuran, diharapkan dapat dihasilkan produk bitumen yang memiliki nilai mekanis lebih baik. Pencampuran dilakukan dengan menggunakan alat hot melt mixer. Komposisi lignin termodifikasi yang digunakan adalah 0.1 , 0.3 , dan 0.5 . Suhu pengadukan dilakukan pada 160oC, 180oC, dan 200oC. Waktu dilakukan selama 15, 30, dan 45 menit. Untuk mengkarakterisasi hasil produk, dilakukan pengujian FE-SEM, FT-IR, STA, Sessile Drop Test, Uji Daktilitas, dan Uji Penetrasi. Dari hasil pengujian menunjukkan bahwa lignin termodifikasi memiliki kompabilitas yang lebih baik dari lignin murni. Karakterisasi produk menunjukkan bahwa semakin tinggi konsentrasi lignin termodifikasi maka sifat mekanik PMB semakin baik, suhu pengadukan meningkatkan dispersi dan distribusi plastik didalam matriks bitumen, dan waktu pengadukan paling efektif adalah 30 menit.
ABSTRACT
Indonesia is the second biggest plastic producer in the world after China in 2010 and polypropylene is one of the most used platic that is non biodegradable. Futhermore, Indonesia paper industry produce many paper waste known as pulp lignin . Lignin can be used as coupling agent and be modified to improve the properties. On the other hand Indonesia accelerate the infrastructure development especially roadways and hence need high quality bitumen. Bitumen physical properties can be enhanced by the addition of polymer, creating polymer modified bitumen PMB . By mixing polypropylene plastic waste as filler and modified lignin as surfactant to bitumen, the bitumen properties expected to be improved. The mixing done hot melt mixer. The composition of modified lignin used were 0.1 , 0.3 , and 0.5 . The mixing temperature were 160oC, 180oC, and 200oC, and the processing time were 15, 30, and 45 minutes. Characterization the properties of PMB used FE SEM, FT IR, STA, Sessile Drop Test, Ductility Test, and Penetration Test Method. The test results show that modified lignin has better compatibilty than normal lignin. More modified lignin added to PMB, More the properties improved. Mixing temperature at 200oC has better dispertion and distribution of filler than 180oC, and the optimum time of mixing is 30 minutes."
2017
S67217
UI - Skripsi Membership  Universitas Indonesia Library
cover
Mochamad Agus Hariyana
Studi karakteristik agregat kasar ringan buatan dari limbah botol plastik high density polyethylene (HDPE) dan pengaruhnya terhadap sifat-sifat mekanis beton ringan = Study of lightweight coarse aggregate properties made from waste plastic high density polyethylene (HDPE) bottle and its effect to the mechanical properties of lightweight concrete
"Kebutuhan akan kemasan produk di bidang otomotif di Indonesia sangat tinggi. Salah satunya untuk kemasan pelumas kendaraan bermotor. Di Jakarta menurut data Dinas Pekerjaan Umum jumlah sepeda motor sampai Maret 2007 mencapai 3.325.790 unit, sehingga akan ada banyak limbah plastik yang dihasilkan dari produk kemasan itu. Akan tetapi kita tahu limbah plastic tersebut dapat di daur ulang.
Botol plastik pelumas kendaraan bermotor merupakan polimer dari jenis polyethylene dengan nama kimiawinya High Density Polyethylene (HDPE) yang diproduksi melalui polimerisasi ethylane (C2H4) dengan variabel proses seperti energi panas, tekanan, dan katalis. Mempunyai Berat jenis antara 0.941-0.965 dan akan mengeras bila dipanaskan.
Berdasarkan karakteristik fisik dari HDPE, dalam studi ini telah dilakukan penelitian limbah botol plastik HDPE sebagai bahan baku pembuatan agregat kasar ringan dan menggunakannya dalam campuran beton ringan.
Agregat kasar ringan dihasilkan dari pembakaran botol HDPE sisa kemasan pelumas kendaraan bermotor, hasil pembakaran diperoleh agregat dengan bentuk tidak beraturan dan bersudut dengan tekstur permukaan halus, licin dan mengkilap dan berwarna abu-abu, coklat dan hijau.
Pengujian sifat fisik agregat diperoleh berat jenis sebesar 0,952, penyerapan air 0,817%, berat isi 545 kg/m3, dan keausan agregat 29,64%. Dari pengujian kuat tekan hancur agregat terhadap 2 ukuran spesimen kubus diperoleh kuat tekan hancur agregat plastik kubus (5×5×5) cm lebih besar 3,74 kali dibandingkan dengan kubus (15×15×15) cm, data tersebut tidak representatif karena benda uji telah mengalami retak sebelum di tes tekan.akibat dari susut yang ekstrim pada saat pengeringan sampel kubus plastik (15x15x15) cm.
Dalam studi ini, agregat ringan plastik dan agregat halus normal (pasir alam) diklasifikasikan berdasarkan ukuran spesimen kubus yang digunakan yaitu kubus beton (5×5×5) cm dan (15×15×15) cm sehingga diperoleh beton ringan agregat bergradasi normal dan beton ringan agregat bergradasi modifikasi. Dari pengujian kuat tekan beton ringan agregat plastik terhadap 2 ukuran specimen kubus beton ringan, dihasilkan angka perbandingan rata-rata sebesar 1,07.
Dari hasil pengujian beton ringan agregat plastik meliputi pengujian beton segar dan beton yang telah mengeras memperlihatkan beton segar agregat plastik mempunyai kelecakan yang sedang, berat isi kering 1607 kg/m3, kuat tekan rata-rata kubus beton ringan bergradasi normal (12,22 ? 12,44) MPa dan kuat tekan rata-rata kubus beton ringan bergradasi modifikasi (10,89 ? 12,33) MPa. Kuat tekan beton yang didapat dengan menggunakan kuat tekan mortar maksimum masih dibawah kuat tekan target rencana sebesar 28,72 MPa, modulus elastisitas sebesar (2609-2701) MPa, Poisson?s Ratio (0,1592-0,1632).
Pengaruh bentuk, tekstur permukaan dan gradasi agregat kasar ringan berpengaruh terhadap kuat tekan yang akan dihasilkan. Semakin kecil ukuran agregat kasar ringan maka kekuatan agregat kasar ringan tipe HDPE juga semakin rendah. Karena telah terjadi perlemahan pada ikatan mikro struktur agregatnya pada saat proses pemecahan yang berulang-ulang.
The needs of product packaging in Automotive industry in Indonesia are very high. One of the examples is lubricant plastic bottle for motor cycle. Based on information from Public Work Department the sum of motor cycle until March 2007 has increased significantly to 3.325.790 units, thus it means that there are lots of wastes from the lubricant packs. However we know that plastic is a material that can be recycled.
The Lubricant Plastic Bottle is classified as Polyethylene polymer as known as High Density Polyethylene (HDPE) that produces by ethylene polymerization with variable process like thermal energy, pressure, and catalyze. It has specific gravity range between 0,941-0,965 and become hardened if heated.
This Research is to analyze HDPE that recycling as basic raw material for lightweight coarse aggregates and the usage of these aggregates in lightweight concrete base on its physical characteristic.
First of all, burn the lubricant bottle to be a coarse lightweight aggregate so we will have aggregate with irregular and angular shape, smooth surface, shiny with grey, brown and green colors.
The results of physical properties of aggregates are: specific gravity is 0,952, water absorption 0,817 %, density is 545 kg/m3, and the resistance of abrasion is 29,64%. The crushing test between 2 cube size show that crushing test of cube size (5x5x5)cm is 3,74 more larger than cube size (15x15x15) cm but this data isn?t representative, the sample had crack before doing crushing and it because extreme shrinkage of cube size (15x15x15) cm.
In this study, plastic lightweight aggregate and fine normal aggregate (sand) were classified according to cube specimen used (5x5x5 cm & 15x15x15 cm) so we got two different type of aggregate, they are normal gradation and modification gradation aggregate. The crushing test between 2 lightweight concrete cube size sample show the average ratio point is 1,07.
From the test result of lightweight concrete including fresh and hardened concrete show that the fresh concrete has middle workability, dry weight of concrete 1607 kg/m3, the average strength of lightweight concrete with a normal grade were ranging between (12,22 ? 12,44) MPa and a modification grade were ranging between (10,89 ? 12,33) MPa, Concrete strength that we got with the used of maximum mortar strength were still below the target strength equal to 28,72 MPa, modulus of elasticity was ranging between (2609-2701) MPa, and Poisson?s ratio was ranging between (0,1592-0,1632).
The study shows that the effect of shape and surface texture of lightweight coarse aggregate has influenced crushing test result. Smaller size of lightweight coarse aggregate has resulted in lower strength of HDPE aggregate. In order to produce smaller size of lightweight coarse aggregate repetition of impact on bigger size aggregate were conducted resulting in weakening of micro structure bond of the aggregates."
2008
S35787
UI - Skripsi Open  Universitas Indonesia Library
cover
Sirait, Altamira Neni Saur Augustine
Pengaruh komposisi serbuk limbah proses powder coating sebagai pengisi terhadap sifat mekanis, termal, dan morfologi komposit bermatriks high density polyethylene (HDPE) = Effect of powder coating wastes as filler on mechanical, thermal, and morphological properties of high density polyethylene (HDPE) composites.
"High Density Polyethylene (HDPE) digunakan sebagai matriks dari komposit dengan zat penggabung PP-g-MA, dan pengisi yang digunakan berasal dari industri powder coating, berupa serbuk limbah poliester dan poliester-epoksi sebagai salah satu bentuk usaha daur ulang. Penelitian ini bertujuan untuk mempelajari pengaruh komposisi serbuk limbah poliester dan poliester-epoksi sebagai pengisi terhadap sifat mekanis, sifat termal, dan morfologi komposit bermatriks HDPE. Penelitian ini menggunakan HDPE sebagai matriks dengan penambahan variasi komposisi pengisi 20%, 30%, dan 40% dengan 5% PP-g-MA. Selain itu, untuk mengetahui pengaruh komposisi PP-g-MA sebagai zat penggabung, dilakukan penambahan PP-g-MA dengan variasi komposisi 0%, 2%, 5%, dan 10% dalam komposit dengan komposisi matriks 70% dan pengisi 30%. Pencampuran dilakukan menggunakan metode hot melt mixing dengan kondisi temperatur 180oC, kecepatan pencampuran sebesar 60 rpm, dan total waktu 9 menit. Karakterisasi dan pengujian yang dilakukan adalah pengukuran nilai tegangan permukaan dengan metode sessile drop, FTIR, SEM, TGA dan DSC, serta uji tarik mikro. Kompatibilitas pencampuran terbaik didapatkan pada pengisi poliester dengan komposisi 30% dan 40% untuk pengisi poliester-epoksi. Untuk komposisi PP-g-MA, didapatkan pada komposisi 10% dengan pengisi serbuk limbah poliester dan poliester-epoksi. Morfologi komposit menunjukkan seiring penambahan komposisi pengisi serbuk limbah poliester dan poliester-epoksi, semakin terlihat dan meningkatkan jumlah pengisi dalam matriks, serta adanya pengaruh penambahan PP-g-MA dalam berkurangnya pori-pori dalam komposit. Sifat mekanis terbaik diperoleh dengan komposisi pengisi 20% dan 5% PP-g-MA, baik dengan pengisi serbuk limbah poliester maupun poliester-epoksi. Sedangkan, untuk mendapatkan sifat termal terbaik dengan pengisi serbuk limbah poliester adalah 30% dengan 5% PP-g-MA dan untuk pengisi poliester-epoksi sebesar 20% dengan 0% PP-g-MA.
High Density Polyethylene (HDPE) was used as matrix for composites with PP-g-MA as coupling agent, and the fillers used were from the powder coating industry, in the form of polyester and polyester-epoxy waste powder as a resort of recycling. This study aims to study the effect of polyester and polyester-epoxy waste powder as fillers on mechanical, thermal, and morphological properties of High Density Polyethylene composites. This study used HDPE as matrix with various compositions of fillers, 20%, 30%, and 40% with 5% of PP-G-MA. To further determine the effect of PP-g-MA as coupling agent, PP-g-MA was added in variations of 0%, 2%, 5%, and 10% in the composite with 70% matrix and 30% filler. Mixing was done using hot melt mixing method with a temperature of 180oC, mixing speed of 60 rpm, and total time of 9 minutes. The characterizations and tests carried out were the measurement of surface tension using sessile drop test, FTIR, SEM, TGA and DSC, as well as micro-tensile test. The best mixing compatibility was found with polyester fillers with a composition of 30% and 40% for polyester-epoxy filler. For PP-g-MA composition, it was found at a composition of 10% with polyester and polyester-epoxy waste powder. The morphology of the composites showed that along with the addition of polyester and polyester-epoxy waste powder fillers, the more visible and increased the amount of filler in the matrix, as well as the effect of adding PP-g-MA in reducing voids in the composites. The best mechanical properties were obtained with a filler composition of 20% and 5% PP-g-MA, both with polyester and polyester-epoxy waste fillers. Meanwhile, to get the best thermal properties with polyester waste filler was 30% with 5% PP-g-MA and for polyester-epoxy filler it was 20% with 0% PP-g-MA."
Depok: Fakultas Teknik Universitas Indonesia, 2021
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UI - Tesis Membership  Universitas Indonesia Library
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