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"[Blowout dan muncul serta tersebarnya gas Hidrogen Sulfida merupakan bahaya khusus dari kegiatan pemboran (NIOSH, 1983). Sehingga dibutuhkan petugas khusus untuk penanganan bahaya paparan gas H2S yang disebut H2S engineer yang melakukan pekerjaan H2S Safety Monitoring. Pekerjaan ini berisiko tinggi sehingga H2S Engineer dituntut memiliki pengetahuan yang lebih mendalam tentang bahaya paparan gas H2S serta pengendaliannya. Tesis ini membahastentang evaluasi pengetahuan kerja H2S Engineer pada pekerjaan H2S safety monitoring di PT.DE. Tujuannya adalah untuk mengetahui dan mengevaluasi gambaran pengetahuan kerja H2S engineer pada pekerjaan H2S safety monitoring. Penilaian pengetahuan dilakukan dengan memberikan kuesioner tentang pengetahuan kerja h2s safety monitoring kepada 30 orang h2s engineer PT.DE. Berdasarkan hasil penelitian diketahui tingkat pengetahuan kerja H2S Engineer masuk dalam kategori tingkat pengethauan sedang, boleh dikatakan belummaksimal. Dengan adanya gambaran tingkat pengetahuan kerja H2S Engineer diharapkan nantinya dapat dilakukan perbaikan yang dapat meningkatkan prestasi kerja perusahaan maupun H2S Engineer itu sendiri. Diperlukan pelatihan rutin, supervisi, serta penelitian-penelitian untuk mengetahui perkembangan pengetahuan kerja H2S Engineer secara berkala.;Blowout and H2S poison gas release both are specific hazard for drilling activities (NIOSH, 1983). Its important to required special personnel as a H2S Engineer to provide H2S Safety Monitoring work at drilling site. H2S Engineer must have a good working knowledge about H2S Safety Monitoring work related the high risk job. This thesis discusses the evaluation of H2S Engineer job knowledge in H2S safety monitoring work. Research conducted at PT. DE as a H2S safety monitoring services company. The objective is to describe the job knowledge of H2S Engineer. Assessment conducted by distributing questionnaires about H2S Safety Monitoring work to all of H2S Engineer PT.DE. Based on the results of research known levels of H2S Engineer working knowledge in the category of medium-level knowledge, arguably not maximized. The level of working knowledge H2S Engineer expected to improving company performance and H2SEngineer itself. Required regular training, supervision, and research to determine the development of H2S Engineer working knowledge regularly.;Blowout and H2S poison gas release both are specific hazard for drilling activities(NIOSH, 1983). Its important to required special personnel as a H2S Engineer toprovide H2S Safety Monitoring work at drilling site. H2S Engineer must have agood working knowledge about H2S Safety Monitoring work related the high riskjob. This thesis discusses the evaluation of H2S Engineer job knowledge in H2Ssafety monitoring work. Research conducted at PT. DE as a H2S safetymonitoring services company. The objective is to describe the job knowledge ofH2S Engineer. Assessment conducted by distributing questionnaires about H2SSafety Monitoring work to all of H2S Engineer PT.DE. Based on the results ofresearch known levels of H2S Engineer working knowledge in the category ofmedium-level knowledge, arguably not maximized. The level of workingknowledge H2S Engineer expected to improving company performance and H2SEngineer itself. Required regular training, supervision, and research to determinethe development of H2S Engineer working knowledge regularly;Blowout and H2S poison gas release both are specific hazard for drilling activities(NIOSH, 1983). Its important to required special personnel as a H2S Engineer toprovide H2S Safety Monitoring work at drilling site. H2S Engineer must have agood working knowledge about H2S Safety Monitoring work related the high riskjob. This thesis discusses the evaluation of H2S Engineer job knowledge in H2Ssafety monitoring work. Research conducted at PT. DE as a H2S safetymonitoring services company. The objective is to describe the job knowledge ofH2S Engineer. Assessment conducted by distributing questionnaires about H2SSafety Monitoring work to all of H2S Engineer PT.DE. Based on the results ofresearch known levels of H2S Engineer working knowledge in the category ofmedium-level knowledge, arguably not maximized. The level of workingknowledge H2S Engineer expected to improving company performance and H2SEngineer itself. Required regular training, supervision, and research to determinethe development of H2S Engineer working knowledge regularly, Blowout and H2S poison gas release both are specific hazard for drilling activities(NIOSH, 1983). Its important to required special personnel as a H2S Engineer toprovide H2S Safety Monitoring work at drilling site. H2S Engineer must have agood working knowledge about H2S Safety Monitoring work related the high riskjob. This thesis discusses the evaluation of H2S Engineer job knowledge in H2Ssafety monitoring work. Research conducted at PT. DE as a H2S safetymonitoring services company. The objective is to describe the job knowledge ofH2S Engineer. Assessment conducted by distributing questionnaires about H2SSafety Monitoring work to all of H2S Engineer PT.DE. Based on the results ofresearch known levels of H2S Engineer working knowledge in the category ofmedium-level knowledge, arguably not maximized. The level of workingknowledge H2S Engineer expected to improving company performance and H2SEngineer itself. Required regular training, supervision, and research to determinethe development of H2S Engineer working knowledge regularly]"

"Produksi hidrogen dengan menggunakan metanol atau gliserol sebagai elektron donor pada fotokatalis TiO2, TiNT, Pt/TiO2 dan Pt/TiNT pada suhu reaksi dari 30 oC sampai dengan 70 oC telah diteliti. Metanol dan gliserol efektif sebagai elektron donor untuk produksi hidrogen secara fotokatalisis. Penggunaan metanol lebih unggul 10% dari gliserol pada semua katalis dalam total produksi hidrogen. Produksi hidrogen terbaik ditunjukkan oleh fotokatalis Pt(1%)/TiNT dengan metanol sebagai elektron donor, yaitu sebesar 2306 µmol/gcat, sementara total hidrogen dengan gliserol sebesar 2120 µmol/gcat. Penggunaan dopan Pt pada fotokatalis menghasilkan produksi hidrogen dua kali lebih besar dibandingkan dengan tanpa dopan.

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Hidrogen production with methanol or glycerol as sacrificial agent using TiO2, TiO2 Nanotubes, Pt/TiO2 and Pt/TiO2 Nanotubes photocatalysts at reaction temperature 30 oC to 70 oC have been investigated. Methanol and glycerol were effective for hydrogen production and the best result was methanol with Pt(1%)/TiO2 that have 2306 µmol/gcat, meanwhile with glycerol only produce 2120 µmol/gcat. The other photocatalyst also have the same pattern, which metanol give 10% higher result on total hydrogen production. Catalyst with Pt give twice higher hydrogen production rather than with no Pt."

"Telah diteliti pengaruh modifikasi fotokatalis TiO2 Degussa P-25 dalam memproduksi hidrogen dari gliserol dan air. Modifikasi yang dilakukan berupa perubahan morfologi menjadi nanotubes, pemberian dopan Pt, dopan N, dan penumbuhan fasa kristalin masing-masing melalui perlakuan hidrothermal (130oC, 12 jam), photo-assisted deposition, impregnasi dan kalsinasi 500oC selama 1 jam. Analisa SEM-EDS dan XRD menunjukkan bahwa katalis Pt-N-TiO2 nanotubes dengan tingkat kristalinitas dengan fasa anatase menyerupai TiO2 Degussa P-25. Berdasarkan uji kinerja fotokatalis di bawah sinar tampak, konsentrasi gliserol yang paling optimal adalah 50%. Morfologi nanotubes, dopan N, dopan Pt, dan dopan Pt dan N masing-masing memberikan kenaikan total produksi hidrogen sebanyak 2; 3; 11; dan 13,5 kali secara berurutan dibandingkan TiO2 Degussa P25.

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The effects of modified TiO2 Degussa P-25 in hydrogen generation from water and glycerol have been observed. The photocatalyst was formed to nanotubes, doped with Pt, doped with N and crystallized each by hydrothermal treatment (130oC, 12 hours), photo-assisted deposition, impregnation, and calcination (500oC) respectively. Result of SEM-EDS and XRD show that Pt-N-TiO2 nanotubes composite crystallinity with anatase phase similar to TiO2 Degussa P-25 was successfully obtained. The effects of glycerol and water composition have also been observed under visible light resulting 50% of glycerol as the optimum concentration. Nanotubes morfology, N doped, Pt doped, and Pt-N doped catalyst increase the hydrogen production each by 2, 3, 11, and 13.5 times respectively compare to TiO2 Degussa P-25. "

"ABSTRAKProses elektrolisis air dapat menghasilkan gas hidrogen dan gas oksigen namun pada kali ini keberadaan gas hidrogen lebih diperhatikan karena kelebihan sifatnya sebagai bahan bakar. Pada penelitian ini dirancang sebuah alat elektrolisis yang memiliki luas area kontak antara katoda dan anoda sebesar 174 cm2. Uji produktivitas alat dilakukan dengan variasi jenis elektrolit (KOH dan NaOH), waktu proses elektrolisis, dan sumber listrik pada tegangan konstan (10 Volt), sehingga hasilnya dinyatakan sebagai laju mol hidrogen per satuan waktu. Pada variasi dan kondisi yang sama, hidrogen hasil elektrolisis diinjeksikan menuju ruang bakar motor genset. Sehingga diperoleh efisiensi bahan bakar setelah 60 menit sebesar 24,97% dengan rasio mol hidrogen 6,39 terhadap bahan bakar.

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ABSTRACTThe process of water electrolysis can produce hydrogen gas and oxygen gas, but at this paper is more concentrate in hydrogen because of its advantages as a fuel. In this study designed an electrolysis device that has a contact area between the cathode and anode of 174 cm2. Test of electrolysis device productivity conducted with electrolyte type variation (KOH and NaOH), the electrolysis process time, and power source DC at constant voltage (10 Volt), so the result expressed as the moles rate of hydrogen per unit time. The same variation and same condition, hydrogen gas injected into the combustion chamber in generator set motor. So that fuel efficiency is obtained after 60 minutes at 24.97% with 6.39 point ratio moles of hydrogen to fuel. "

"Sianida telah digunakan sejak lama dalam proses pengektrasian emas dengan metoda pelindian (leaching). Sianida juga dikenal sebagai bahan kimia berbahaya dan mematikan. Oleh karena itu, International Cyanide Management Code (ICMC) didirikan untuk mengontrol penggunaan siandia dalam industri. Kanowna Belle Gold Mine (KBGM) telah terdaftar dalam ICMC sejak tahun 2008 dan kemudian diperbaharui pada Desember 2012. Menurut ICMC, konsentrasi sianida yang dibuang ke tempat pembuangan akhir (tailings) harus 80% di bawah 50 ppm dan 95% di bawah 78 ppm. Pembuangan di atas 78 ppm yang berkepanjangan dapat menyebabkan pelanggaran atas kode yang sudah ditetapkan dan disepakati oleh perusahaan. Batas konsentrasi sianida yang dibuang ke tailings di KBGM lebih tinggi dari batas normal dikarenakan tipe air yang digunakan dalam proses adalah air dengan tingkat garam yang tinggi (hyper saline water). Tujuan utama skripsi ini adalah untuk meneliti dan memaksimalkan keefektifan dari hidrogen peroxida dalam proses penghancuran sianida di tailings KBGM selama berlangsungnya proses pelindian batuan refractory dan free milling. Penelitian dilakukan dengan menggunakan sampel yang diambil saat refractory dan free milling untuk kemudian dilakukan pengujian skala lab dan nyata (plant trial). Sampel yang diambil dari setiap eksperimen lalu dites menggunakan metoda picric acid, yaitu metoda yang menggunakan warna sebagai indikator tingkat konsentrasi sianida di dalam larutan. Semakin merah warna larutan, menunjukkan semakin tinggi konsentrasi sianida di dalam larutan tersebut. Dampak dari kombinasi penggunaan H2O2 dan CuSO4 sebagai katalis dalam proses penghancuran sianida dilakukan secara skala lab dan nyata menggunakan metoda yang sama dengan penelitian sebelumnya. Ditemukan bahwa kombinasi dari H2O2 dan CuSO4 ternyata dapat mempercepat proses penghancuran sianida sebanyak 20-32% dengan 100 g/t H2O2 dan skala perbandingan dari sianida terhadap CuSO4 sebesar 2:1. Perbedaan dalam karakteristik batuan dan kondisi pelindian pada pemprosesan batu refractory and free milling menyebabkan dua model berbeda yang harus diterapkan di dalam sistem DCS. Untuk model refractory, persamaan yang harus diterapkan adalah 𝒚 =(−𝟎. 𝟎𝟕𝟏𝟒𝒙 + 𝟔. 𝟎𝟔𝟏𝟗)𝟏. 𝟐𝟕𝟑, sedangkan persamaan untuk model free milling adalah 𝒚 =(−𝟎. 𝟗𝟎𝟒𝟒𝒙 + 𝟗𝟕. 𝟖𝟓𝟖)𝜶. Persamaan untuk model free milling masih harus diselidiki lebih lanjut dengan melakukan plant trial untuk mendapatkan correction factor (α).

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Cyanide has been widely used in gold leaching processing plants for over one hundred years and is known by its characteristic to be a deadly poisonous chemical. To control cyanide usage in the mining industry, the International Cyanide Management Code (ICMC) was established. Kanowna Belle Gold Mine (KBGM) has been certified under the ICMC since 2008 and has recently been re-certified in December 2012. Under the Code, 80% of the time WAD cyanide discharge must be below 50 ppm and 95% of the time must be below 78 ppm. Prolonged discharge above 78 ppm is considered a breach of the ICMC. Greater usage of cyanide allowed in KBGM due to the usage of hyper saline water as the processing plant results in higher WAD cyanide discharge concentration.

The main objective of this report was to determine the effectiveness of WAD cyanide detoxification using hydrogen peroxide in KBGM tailings slurries during refractory and free milling ore leaching. The experiment was conducted during refractory and free milling ore slurries for both lab experiment and plant trial. The sample solutions were than analysed using picric acid method, which is a colorimetric method where higher WAD cyanide concentration solution was represented with deeper orange-red colour.

The impacts of H2O2 concentration and copper sulphate (CuSO4) as a catalyst on WAD cyanide destruction were investigated using small scale laboratory bottle roll tests. A plant trial was then conducted. It was found that the WAD cyanide destruction was optimum when the H2O2 dose was 100 g/t with 2:1 WAD cyanide to CuSO4 ratio. The combination was able to increase the removal rate by 20-32%.

Different ore characteristics and leaching conditions between refractory and free milling slurries resulted in two separate detoxification model to be applied in the DCS system. The equation for the model that should be installed during refractory leaching is 𝒚 = (−𝟎. 𝟎𝟕𝟏𝟒𝒙 + 𝟔. 𝟎𝟔𝟏𝟗)𝟏. 𝟐𝟕𝟑 and the equation model that should be installed during free milling leaching is 𝒚 = (−𝟎. 𝟗𝟎𝟒𝟒𝒙 + 𝟗𝟕. 𝟖𝟓𝟖)𝜶. The equation for the free milling slurry still needs to be investigated further by conducting a plant trial to find the correction factor (α)."

"ABSTRAKKandungan biogas tidak hanya CH4 tetapi juga mengandung CO2, H2O, dan H2S yang merupakan pengotor. Salah satu pengotor yang paling umum adalah hidrogen sulfida. Meskipun secara komposisi jumlahnya relatif tidak dominan, keberadaan hidrogen sulfida dapat memicu korosi. Oleh karena itu, diperlukan pengurangan kadar hidrogen sulfida dari biogas yang dihasilkan agar nilai kalornya meningkat, tingkat korosi menurun, dan selanjutnya dapat dimanfaatkan dengan lebih baik. Tujuan dari penelitian ini adalah untuk mengidentifikasi karakteristik media steel wool serta mengetahui efisiensi media mengurangi kadar H2S dalam biogas hasil pengolahan Anaerobic Digestion. Penelitian dilakukan secara adsorpsi kimiawi menggunakan steel wool pada kolom PVC berukuran diameter 2 rdquo; 6 cm . Analisis gas H2S dilakukan menggunakan metode SNI 19-7117.7-2005. Hasil dari penelitian didapatkan bahwa media steel wool yang digunakan mengandung unsur aktif berupa Fe dan Zn dengan jumlah total mencapai 97,5 massa dan efisiensi penghilangan H2S hingga 100 rata-rata 95 pada ketinggian kolom 100 cm, serta hingga 100 pula rata-rata 97 pada laju aliran 0,1 L/menit.

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ABSTRACTThe biogas content is not only CH4 but also contains CO2, H2O, and H2S which are impurities. One of the most common impurities is hydrogen sulphide. Although the amount is relatively non dominant, the presence of hydrogen sulphide can trigger corrosion. Therefore, it is necessary to reduce the hydrogen sulphide content of the biogas produced so that the calorific value increases, the corrosion rate decreases, and furthermore can be utilized better. The purpose of this research is to identify characteristic of steel wool media and to know efficiency of media to reduce H2S level in biogas result of Anaerobic Digestion processing. The research was carried out by chemical adsorption using steel wool on PVC column of 2 6 cm diameter. H2S gas analysis is done using SNI 19 7117.7 2005 method. The result of the research shows that the steel wool media used contains the active elements of Fe and Zn with total amount reaching 97.5 mass and H2S removal efficiency up to 100 95 average at 100 cm column altitude, and also up to 100 97 average at flowrate 0,1 L minute."

"Aditif pelumas merupakan komponen utama dari pelumas. Aditif memiliki sifat anti-aus dan tahan pada tekanan tinggi. Pembuatan aditif dilakukan dengan proses sulfurisasi minyak biji kapuk randu dengan gas H2S. Proses sulfurisasi dimodifikasi dengan tambahan metode sirkulasi H2S yang berfungsi untuk meningkatkan efisiensi penggunaan H2S. Radiasi sinar UV dengan panjang gelombang 254 nm juga digunakan untuk mempercepat proses sulfurisasi. Proses sulfurisasi dinyatakan berhasil karena ada ikatan C-S pada hasil spektrum FTIR di puncak 581,25 cm-1. Hal ini diperkuat dengan hasıl kandungan sulfur tertinggi yang didapatkan pada sampel minyak biji kapuk randu tersulfurisasi 20 jam sebesar 32.682 ppm dengan viskositas 72,17 cSt dan densities 0,92 g/cm2. Pengujian performa aditif dilakukan dengan uji four-ball untuk melihat performa ketahanan anti-aus pada aditif. Pengujian performa dilakukan dengan mencampurkan minyak mineral sebagai minyak dasar dan aditif. Hasil uji keausan terbaik terdapat pada formulasi minyak mineral dan 10% aditif tersulfurisasi selama 20 jam yang meningkatkan performa keausan hingga 98% dan memiliki rasio sulfur sebesar 3.268 ppm. Rasio sulfur ini sudah sebanding dengan rasio aditif ZDDP yang umum digunakan sebesar 3.393 ppm. Selanjutnya dilakukan pengujian korosifitas pada formulasi minyak mineral dan aditif tersulfurisasi selama 20 jam dan dihasilkan bahwa formulasi tersebut sangat rendah terhadap korosi dan aman digunakan pada mesin kendaraan

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Lubricant additives are the main components of lubricants. These additives possess anti-wear properties and can withstand high pressure. The production of additives is carried out through the sulfurization process of kapok seed oil using H2S gas. The sulfurization process is modified with an additional H2S circulation method to enhance the efficiency of H2S usage. UV radiation with a wavelength of 254 nm is also used to accelerate the sulfurization process. The sulfurization process is deemed successful due to the presence of C-S bonds in the FTIR spectrum at the peak of 581.25 cm-1. This is further supported by the highest sulphur content found in the kapok seed oil sample sulfurized for 20 hours, which was 32,682 ppm with a viscosity of 72.17 cSt and a density of 0.92 g/cm2. Performance testing of the additive was also conducted using a four-ball test to evaluate the anti-wear performance of the additive. The performance test was carried out by mixing mineral oil as the base oil and the additive. The best wear test results were obtained from the formulation of mineral oil and 10% additive sulfurized for 20 hours, which improved wear performance by up to 98% and had a sulphur ratio of 3,268 ppm. This sulphur ratio is comparable to the commonly used ZDDP additive ratio of 3,393 ppm. Additionally, a corrosiveness test was conducted on the formulation of mineral oil and the additive sulfurized for 20 hours, and it was found that this formulation is very low in corrosion and safe for use in vehicle engines."

"Hidrogenasi dilakukan terhadap fraksi non-oksigenat bio-oil hasil slow co-pyrolysis bonggol jagung dan plastik polipropilena. Dalam reaksi hidrogenasi, terjadi proses adisi gas hidrogen pada ikatan rangkap bio-oil sehingga diperoleh biofuel dengan karakteristik berupa viskositas, disstribusi berat molekul, dan branching index yang kemudian dibandingkan dengan diesel komersial. Penjenuhan dengan hidrogenasi dilakukan dalam suatu tangki berpengaduk 300mL dengan jenis down-flow 45o pitched blade turbine pada tekanan rendah akibat dominasi bio-oil fasa cair Konfigurasi tersebut mampu menarik dan mempertemukan gas hidrogen dengan bio-oil dan katalis berupa Ni/Al2O3 yang memiliki selektivitas yang baik serta mampu memberikan yield yang tinggi. Percobaan dilakukan pada berbagai variasi tekanan gas hidrogen untuk menganalisis hubungan kedua variabel tersebut terhadap karakteristik biofuel yang dihasilkan. Variabel lain berupa durasi reaksi dikontrol selama 2 jam, sedangkan laju alir gas hidrogen dan temperatur hidrogenasi disesuaikan dengan nilai tekanan gas hidrogen. Pada variasi tekanan gas hidrogen bernilai antara 4 hingga 10 bar, peningkatan tekanan gas hidrogen menghasilkan biofuel dengan penurunan persentase senyawa alkena dari 4,14% hingga 0,00%, namun terjadi peningkatan nilai branching index dari 1,29 hingga 1,56, distribusi berat molekul, dan viskositas dari 9,06 hingga 10,86 cSt yang semakin menjauhi bahan bakar komersial.

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Hydrogenation is implemented on non-oxygenated fraction of bio-oil produced from slow co-pyrolysis of corncob and popypropylene plastic. The process is conducted by addition of hydrogen gas on bio-oil double bonds occured to produce biofuel whose quality is compared to those of commercial diesel fuel which is characterized by its viscosity, molecular weight distribution and branching number. The saturation process is conducted in 300 mL stirred tank reactor with down-flow 45o pitched blade turbine impeller operated in low pressure due to the domination of liquid phase of bio-oil. This configuration enables pullout and mixing of hydrogen gas with bio-oil and catalyst. Ni/Al2O3 catalyst is used to obtain high selectivity and yield of hydrogenation reaction.

The experiment is performed on several variation of hydrogen gas pressure to analyze their effects on characteristics of produced biofuel. The hydrogenation duration is controlled in 2 hours, while the hidrogen gas flow and hydrogenation temperatur are adjusted by the hydrogenation gas pressure. At the low pressure of hydrogen gas range from 4 to 10 bar, the increasing of hydrogen gas pressure produces biofuel with decreasing alkene compound from 4.14% to 0.00%, yet has increasing branching index from 1.29 to 1.56, low molecular weight distribution, and viscosity from 9.06 to 10.86 cSt which move further from commercial fuel characteristics."

"Elektrolisis plasma menjadi metode sintesis green hydrogen dan hidrogen peroksida yang memisahkan air menjadi gas H2 dan O2 dengan plasma katodik pada tegangan di atas elektrolisis konvensional akibat rekombinasi radikal H• dan •OH. Laju erosi elektroda akibat suhu plasma yang tinggi menjadi keterbatasan pada proses ini sehingga Stainless Steel SS – 201 yang memiliki laju erosi lebih kecil dibandingkan tungsten (Lukkes, et al. 2006) diteliti efektivitasnya dari jumlah mmol produk, energi spesifik (Wr), dan laju erosi. Penelitian dilakukan dengan melakukan uji rancang bangun reaktor elektrolisis plasma dan karakterisasi arus tegangan untuk menentukan kondisi operasi menggunakan elektrolit NaOH 0,02 M dan Na2SO4 pada konduktivitas serupa, serta konsentrasi aditif metanol sebagai scavenger radikal •OH. Hasil penelitian menunjukkan bahwa SS – 201 memiliki erosi yang lebih kecil sebesar 0,07 gram dibandingkan tungsten sebesar 1,05 gram setelah 60 menit proses. Pembentukan lapisan oksida pasif SS – 201 menambah luas kontak elektroda dan menghasilkan gas H2 sebanyak 104,55 mmol dibandingkan tungsten sebanyak 94,95 mmol. Penelitian ini juga membandingkan pengaruh penggunaan NaOH dan Na2SO4 dengan konduktivitas serupa yang menunjukkan NaOH menghasilkan lebih banyak H2 dibandingkan Na2SO4 sebanyak 97,55 mol karena cenderung mengarah pada produksi hidrogen peroksida karena komposisi elektrolit yang mendorong pembentukan radikal •OH. Selain itu, pengaruh variasi metanol diuji yang menunjukkan bahwa penambahan aditif metanol tidak hanya berperan sebagai scavenger radikal •OH namun terdekomposisi akibat plasma menghasilkan gas hidrogen dan radikal H•.

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Plasma electrolysis is a green hydrogen and hydrogen peroxide synthesis method that separates water into H2 and O2 gases with cathodic plasma at a voltage above conventional electrolysis due to the recombination of H• and •OH radicals. The electrode erosion rate due to high plasma temperature is a limitation in this process so that Stainless Steel SS – 201 which has a lower erosion rate than tungsten (Lukkes, et al. 2006) was examined for its effectiveness from the number of mmol of product, specific energy (Wr), and rate of erosion. The research was carried out by conducting design tests for plasma electrolysis reactors and characterizing current voltages to determine operating conditions using electrolytes of 0.02 M NaOH and Na2SO4 with similar conductivity, as well as the concentration of methanol additive as an •OH radical scavenger.

The results showed that SS-201 had less erosion of 0.07 gram compared to 1.05 gram of tungsten after 60 minutes of process. The formation of the SS-201 passive oxide layer increased the contact area of the electrodes and produced 104.55 mmol of H2 gas compared to 94.95 mmol of tungsten. This study also compared the effect of using NaOH and Na2SO4 with similar conductivity which showed that NaOH produced more H2 than Na2SO4 of 97.55 mmol because it tends to produce of hydrogen peroxide due to the electrolyte composition which encourages the formation of •OH radicals. In addition, the effect of methanol variations was tested which showed that the addition of additive methanol did not only act as an •OH radical scavenger but decomposed due to plasma to produce hydrogen gas and H• radicals."