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Tarigan, Olivia Cesarah
"ABSTRAK
Komposit biofilm-batu apung dan Titanium Oksida-batu apung telah disintesis untuk dekolorisasi limbah aktual Batik Pekalongan. Komposit biofilm-batu apung disintesis menggunakan bakteri dari konsorsium lambung sapi dan komposit titanium oksida-batu apung disintesis dengan metode dip coating menggunakan TiO2 P25 Evonic. Komposit biofilm-batu apung dikarakterisasi dengan TPC dan SEM, sedangkan komposit Titanium Oksida-batu apung menggunakan SEM/EDX. Uji dekolorisasi dilakukan pada limbah pewarna jenis Napthol dan Indigosol dengan variasi konsentrasi. Berdasarkan hasil uji, diperoleh proses fotobiodegradasi memiliki kemampuan dekolorisasi limbah pewarna Naphtol sebesar 34-44% dan limbah pewarna Indigosol sebesar 41-51% pada waktu uji 4 jam. Kecenderungan dekolorisasi pewarna masih meningkat tiap jamnya.

ABSTRACT
Biofilm-Pumice and Titanium Oxide-Pumice are synthesized for Batik Pekalongan’s waste decolorization. Biofilm-Pumice composite is synthesized using bacteria from Lambung Sapi Consortium and Titanium Oxide-Pumice is synthesized with dip coating methode using TiO2 P25 Evonic. Biofilm-Pumice is characterized by TPC and SEM, while Titanium Oxide-Pumice is characterized by SEM/EDX. Decolorization is performed in Naphtol and Indigosol waste dye. The result, combination process of photo-biodegradation had 34-44% decolorization of Naphtol and 41-51% decolorization of Indigosol in 4 hours. Tendency of decolorization is still rised with every hour."
2015
S59326
UI - Skripsi Membership  Universitas Indonesia Library
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Zahra
"ABSTRAK
Limbah lindi hitam memiliki nilai Chemical Oxygen Demand COD yang tinggi dan sukar untuk didekomposisi. Salah satu cara penanganan lindi hitam yang menjanjikan dan bersifat biodegradable yaitu dengan menggunakan jamur. Jamur yang digunakan dalam penelitian yaitu Trametes versicolor F200. Jamur ini dapat mendekolorisasi lindi hitam karena mengandung enzim ligninolitik. Dalam penelitian ini, dilakukan penentuan kondisi optimum dekolorisasi lindi hitam dengan cara membuat variasi agitasi, mediator dan inducer. Setelah didapatkan kondisi optimum dekolorisasi, selanjutnya dekolorisasi dilakukan dengan cara melakukan imobilisasi jamur dan imobilisasi isolat enzimnya. Hasil dekolorisasi lindi hitam menggunakan sel bebas jamur Trametes versicolor F200 akan dibandingkan hasil dari dekolorisasi dengan metode imobilisasi. Dalam penelitian ini, dilakukan pengukuran dekolorisasi, aktivitas enzim, konsentrasi glukosa, berat misel dan COD. Pengukuran dekolorisasi lindi hitam dengan menggunakan spektrofotometer UV-Vis, dimana merupakan perbandingan konsentrasi sebelum dan setelah dekolorisasi.

ABSTRACT
ABSTRACTBlack liquor has high Chemical Oxygen Demand COD value and difficult to decompose. One way for handling this waste that adventage and biodegradable is using mushrooms. The fungus used in this study is Trametes versicolor F200. This fungus can decolorize black liquor because containing ligninolytic enzymes. In this study, we will be determined the optimum condition for decolorization black liquor by variation of agitation, mediator and inducer. After obtaining the optimum condition of decolorization, then decolorization is done by immobilization of fungus and immobilization the isolate of enzyme.The result of decolorization black liquor using Trametes versicolor F200 will be compared with the result of decolorization with imobilization method. Decolorization, enzyme activity of fungus, glucose concentration, micelle weight and COD during decolorize black liquor also measured. Measurement of decolorization black liquor using UV Vis spectrophotometer, which the ratio of concentration before and after decolorization. "
2017
T47894
UI - Tesis Membership  Universitas Indonesia Library
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Miranda Hasanah
"Komposit batu apung-TiO2 dan komposit batu apung-biofilm digunakan untuk mengeliminasi fenol dalam fotobioreaktor. Komposit dikarakterisasi dengan FTIR dan SEM. Hasil karakterisasi menunjukkan bahwa komposit batu apung-biofilm terbentuk dengan baik menggunakan metode aerasi sedangkan komposit batu apung-TiO2 dapat disintesis dengan metode dip coating. Berdasarkan hasil uji, diperoleh kesimpulan bahwa biofilm yang dibentuk dari konsorsium bakteri memiliki kinerja degradasi yang lebih baik dibandingkan dengan Acinetobacter sp., tetapi tidak lebih baik bila dibandingkan dengan fotodegradasi dan biodegradasi tunggal. Treatment pencucian dan penjemuran sinar matahari merupakan teknik regenerasi yang sesuai untuk mengaktifkan kembali komposit batu apung ?TiO2 yang telah digunakan sedangkan penambahan nutrisi dan inkubasi kembali selama 24 jam tidak meningkatkan kinerja degradasi komposit ? biofilm.

Pumice-TiO2 composite and pumice-biofilm composite were used for phenol removal in photobioreactor. The composites were characterized by FTIR and SEM. It shown that the best method to synthesize pumice-biofilm composite is aeration while pumice-TiO2 composite could be synthesized by dip coating. Based of phenol removal experiments result, biofilm from bacteria consortium could remove phenol better than Acinetobacter sp., but worse than single photodegradation or single biodegradation. Washing and drying treatment by using sunlight was an appropriate regeneration technique for pumice-TiO2 composite reactivation whereas nutrition enhancing and reincubating for 24 hours could not improve the degradation performance of pumice-biofilm composite.
"
Depok: Fakultas Teknik Universitas Indonesia, 2014
S55071
UI - Skripsi Membership  Universitas Indonesia Library
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Jessica Tanuwijaya
"Pengaruh memodifikasi TiO2 dengan menggunakan dopan C dan batu apung dalam mendegradasi fenol dan Reactive Orange 7 telah di investigasi. Sumber dopan Carbon diperoleh dari 1-propanol. Pelapisan C-TiO2 pada batu apung diperoleh dari metode deep coating. Analisis UV-Vis DRS menunjukkan bahwa penurunan bandgap energy C-TiO2 menjadi 3,05 eV. Analisis BET menunjukkan luas permukan C-TiO2-batu apung adalah 3,539 m2/g. Konsentrasi fenol dan Reactive Orange 7 dianalisis dengan Spektrofotometer UV-Vis. Penambahan laju udara 100 ml/menit dapat meningkatkan kinerja komposit dengan tingkat degradasi mencapai 100% selama 2,5 jam. Konsentrasi awal fenol 10 ppm dapat didegradasi selama 0,8 jam dengan konstanta laju degradasi 1,26 menit-1.

Effect of TiO2 modified by using dopants C and pumice in degrading phenol and Reactive Orange 7 was investigated. Source of dopant Carbon was obtained from 1-propanol. Coating C-TiO2 on pumice stone was obtained by deep coating process. UV-Vis DRS analysis showed that bandgap energy of C-TiO2 is reducing to 3.05 eV. BET analysis showed surface area of composite is 3.54 m2/g. The concentration of phenol and Reactive Orange 7 was analyzed by UV-Vis spectrophotometer. The addition rate of air 100 mL/min to enhance the performance of composite with degradation rates reached 100% for 2.5 hours. Initial phenol concentration of 10 ppm for 0,86 hours can be degraded by the degradation rate constant 1.26 min-1."
Depok: Fakultas Teknik Universitas Indonesia, 2013
S45235
UI - Skripsi Membership  Universitas Indonesia Library
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Catur Nitya Vinaya Natawidha
"ABSTRAK
Pengaruh fotokatalis komposit berbasis TiO2 dan batu apung dalam mendegradasi
senyawa Linear Alkilbenzena Sulfonat (LAS) telah diinvestigasi. Prekursor yang
digunakan adalah TiO2 P25 yang diberi dopan C dan CuO serta penggunaan batu
apung sebagai penyangga. Penelitian ini mencakup variasi dopan, komposisi CuO,
perbedaan sumber foton, dan waktu degradasi agar didapat fotokatalis yang aktif
serta bekerja optimal untuk degradasi LAS. Konsentrasi LAS sesudah degradasi
dianalisis dengan Spektrofotometer UV-Vis dengan metode MBAS (Methtylene
Blue Active Substance). Hasil analisis menunjukkan fotokatalis 1%CuO-TiO2
adalah fotokatalis dengan komposisi CuO yang paling optimal dengan tingkat
degradasi lebih dari 94% setelah 20 menit reaksi menggunakan sinar UV-A.
Dopan C mampu meningkatkan aktivitas TiO2 di bawah sinar tampak dengan
tingkat degradasi lebih dari 85% setelah 20 menit reaksi menggunakan lampu
merkuri sebagai sumber foton.

ABSTRACT
Effects of composite photocatalysts based on TiO2 and pumice stone for
degradation of Linear Alkylbenzene Sulfonate (LAS) compound had been
investigated in this research. The precursor was TiO2 P25 doped by carbon and
CuO and also used pumice stone as support. This research investigated dope
variation, CuO composition, different photon source, and degradation time to get
photocatalyst which are active and give optimum work for degradation of Linear
Alkylbenzene Sulfonate. The concentration of Linear Alkylbenzene Sulfonate
after degradation was analyzed by UV-Vis Spectrophotometre with MBAS
(Methtylene Blue Active Substance) method. The results showed that 1%CuOTiO2
photocatalyst is the most optimum CuO doped photocatalyst with
degradation degree was more than 94% after 20 minutes reaction with UV-A
light. C doped could enhance TiO2 actvity under visible light with degradation
degree was more than 85% after 20 minutes reaction with mercury lamp.
"
Depok: Fakultas Teknik Universitas Indonesia, 2012
S43758
UI - Skripsi Open  Universitas Indonesia Library
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Wahyudi Maha Putra
"Fotokatalis C-N-TiO2 telah berhasil disintesis dengan urea sebagai sumber dopan nonlogam. Fotokatalis C-N-TiO2 juga berhasil diimobilisasi pada batu apung dengan metode dip coating. Komposit ini telah dikarakterisasi FTIR, SEM-EDX, BET, XRD, dan UV-vis DRS. Hasil karakterisasi ini menunjukkan bahwa penambahan dopan nonlogam C dan N berhasil menurunkan bandgap C-N-TiO2 dari 3,15 eV menjadi 2,95 eV sehingga lebih responsif terhadap cahaya tampak. Berdasarkan hasil uji penyisihan amonia, loading fotokatalis optimum yaitu 1,5-2,5% dari massa komposit C-N-TiO2/Batu Apung yang berhasil menyisihkan amonia dari 550 ppm menjadi 44 ppm dalam waktu 180 menit. Berdasarkan hasil uji efektivitas komposit, diperoleh pH optimum untuk penyisihan amonia yaitu pada pH 10. Selain itu, fotodegradasi amonia mengikuti kinetika Langmuir- Hinshelwood sehingga berpotensi untuk menyisihkan limbah cair amonia pada industri dalam waktu 5 jam.

Nonmetal doped photocatalyst, C-N-TiO2, has been successfully synthesized with urea as precursor of dopant. The photocatalyst has been immobilized on pumice stone by dip coating method. This composite is characterized by FTIR, SEM-EDX, BET, XRD, and UV-vis DRS. The result show that C-N-TiO2 photocatalyst narrow the energy bandgap from 3.15 eV to 2.95 eV, it is mean that this photocatalyst more responsive to visible light. Based on ammonia elimination experiments, it show optimum loading of C-N-TiO2 on composite is 1.5 -2.5%, which can eliminate ammonia from concentration 550 ppm to 44 ppm during 180 minutes. Based on experiment, the optimum pH to eliminate ammonia is 10. Furthermore, ammonia photodegradation rate is matched with Langmuir Hinshelwood equation, so that the photocatayst is potential to remove ammonia wastewater in less than 5 hour."
Depok: Fakultas Teknik Universitas Indonesia, 2014
S58903
UI - Skripsi Membership  Universitas Indonesia Library
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Moh. Azhar
"[ABSTRAK
Telah dilakukan penelitian pembuatan beton ringan atau lightweight
concrete (LWC) menggunakan batu apug (BA) dan abu sekam padi (ASP).
Sampel beton ringan yang dibuat mengandung BA dengan fraksi berbeda, adapun
material semen, pasir, dan abu sekam padi volumenya dijaga tetap. Terdapat dua
parameter utama yang menentukan sifat mekanik sampel LWC masing-masing
adalah densitas sampel dan rasio air/semen (w/c). Sifat mekanik yang paling
utama dari LWC adalah kekuatan tekan. Pada campuran dengan fraksi volume
batu apung terbesar (100%) menghasilkan densitas dan kekuatan tekan paling
rendah masing-masing sebesar (1389,6 kg/m3 dan 11,1 MPa). Diketahui bahwa
makin rendah fraksi batu apung dalam sampel beton makin tinggi nilai densitas
dan kekuatan tekannya, disebabkan oleh tingginya nilai fraksi pori baik pori
terbuka maupun pori tertutup dalam sampel beton. Observasi terhadap fotomikro
SEM batu apung menunjukkan bahwa terdapat sejumlah besar pori dengan bentuk
memanjang ke bagian dalam dari permukaan sampel beton. Pori hadir dengan
kerapatan jumlah pori relatif besar serta dengan ukuran yang bervariasi. Fakta ini
menjelaskan mengapa batu apung besifat ringan karena memiliki densitas massa
yang rendah. Pola difraksi sinar X sampel beton ringan memperlihatkan dominasi
fasa kristalin diidentifikasi sebagai fasa quartz (SiO2). Namun dapat dipastikan
sampel beton ringan terdiri dari fasa campuran antara fasa kristalin dan dengan
sedikit fasa amorph.
Fotomikro SEM beton ringan menunjukkan bahwa senyawa Kalsium Silikat
Hidrat (CSH) mulai tumbuh pada waktu awal proses hidrasi dan terus
berkembang sampai umur beton mencapai umur hidrasi 28 hari yang ditandai
dengan sifat fisik yang padat dan peningkatan kekuatan beton. Dapat dipastikan
bahwa senyawa CSH ini memiliki peranan penting terhadap pengaturan sifat
mekanik seperti kekuatan tekan. Penelitian ini menyimpulkan bahwa batu apung
dan abu sekam padi adalah material berbasis silika amorph yang memiliki densitas
lebih rendah terutama dibandingkan dengan material pembentuk beton lainnya.
Baik densitas dan kekuatan tekan sampel beton ringan ditentukan oleh rasio antara
batu apung dan abu sekam padi. Ditemukan rasio terkecil BA/ASP yaitu 8
menghasilkan nilai densitas dan kekuatan tekan optimal, masing-masing pada usia
beton 28 hari sebesar 1891 kg/m3 dan 23 MPa. Komposisi beton ringan yang
terbaik diperoleh dari hasil penelitian ini adalah komposisi campuran PCC (1,00) :
Pasir (1,00) : ASP (0,05) : BA (0,50) dengan nilai Slump 8 cm ditandai oleh nilai
rasio antara kuat tekan dan densitas tertinggi adalah 1285.;

ABSTRACT
Research studies on the manufacture of lightweight concrete (LWC) using
pumice and rice husk ash (RHA) materials have been done. LWC samples were
made of pumice materials with a different mass fraction, while the cement, sand,
and rice husk ash materials were keep fixed. It was found that there are two main
parameters that determine the mechanical properties of LWC which are density
and the water and cement ratio (w/c ratio). The main mechanical properties of
LWC sample is the power press. Samples with the largest volume fraction of
pumice (100%) resulted in lightest density (1389.6 kg/m3) and the smallest
strength of LWC (11.1 MPa). It was found that, the lower the mass fraction of
pumice in LWC samples, the higher the density values and compressive strength
were obtained. This was caused by the high mas fraction value of pores, which
were both open and closed pores. Scanning electron micorscopy (SEM) images
for the pumice showed that the there are a large number of regular and structured
pores extending deep inside the surface of the sample. It was observed that pores
present with pore size does not vary significantly but with the density of the
relatively large number of pores, indicating pumice has a low mass density. The
XRD pattern of the lightweight concrete samples indicated that the samples were
dominated by crystalline phases in which the quartz (SiO2) is the main phase and
a small fraction of amorphous phase was also obtained.
SEM images of lightweight concrete samples showed that the structure of
Calcium Silicate Hydrates (CSH) started growing at the beginning of hydration
time and continue to evolve into a more solid structure until the age of 28 days,
where the compound has an important role to the mechanical properties such as
compressive strength. The study concluded that the pumice and rice husk ash is
are amorphous silica-based material which has a lower density compared to other
concrete forming material such as cement and sands. Both density and light
weight concrete compressive strength are determined by the ratio between pumice
and rice husk ash, in which the smallest ratio 8 resulted in the largest density and
compressive strength, which are 1890.5 kg/m3 and 23.2 MPa respectively at the
age of 28 days. The study concluded that the best composition for lightweight
concrete samples was the following: PCC (1,00): Sand (1,00): ASP (0,05): BA
(0,50) with a slump value of 8 cm resulted in the largest value of a ratio between
compressive strength and density of 1285.;Research studies on the manufacture of lightweight concrete (LWC) using
pumice and rice husk ash (RHA) materials have been done. LWC samples were
made of pumice materials with a different mass fraction, while the cement, sand,
and rice husk ash materials were keep fixed. It was found that there are two main
parameters that determine the mechanical properties of LWC which are density
and the water and cement ratio (w/c ratio). The main mechanical properties of
LWC sample is the power press. Samples with the largest volume fraction of
pumice (100%) resulted in lightest density (1389.6 kg/m3) and the smallest
strength of LWC (11.1 MPa). It was found that, the lower the mass fraction of
pumice in LWC samples, the higher the density values and compressive strength
were obtained. This was caused by the high mas fraction value of pores, which
were both open and closed pores. Scanning electron micorscopy (SEM) images
for the pumice showed that the there are a large number of regular and structured
pores extending deep inside the surface of the sample. It was observed that pores
present with pore size does not vary significantly but with the density of the
relatively large number of pores, indicating pumice has a low mass density. The
XRD pattern of the lightweight concrete samples indicated that the samples were
dominated by crystalline phases in which the quartz (SiO2) is the main phase and
a small fraction of amorphous phase was also obtained.
SEM images of lightweight concrete samples showed that the structure of
Calcium Silicate Hydrates (CSH) started growing at the beginning of hydration
time and continue to evolve into a more solid structure until the age of 28 days,
where the compound has an important role to the mechanical properties such as
compressive strength. The study concluded that the pumice and rice husk ash is
are amorphous silica-based material which has a lower density compared to other
concrete forming material such as cement and sands. Both density and light
weight concrete compressive strength are determined by the ratio between pumice
and rice husk ash, in which the smallest ratio 8 resulted in the largest density and
compressive strength, which are 1890.5 kg/m3 and 23.2 MPa respectively at the
age of 28 days. The study concluded that the best composition for lightweight
concrete samples was the following: PCC (1,00): Sand (1,00): ASP (0,05): BA
(0,50) with a slump value of 8 cm resulted in the largest value of a ratio between
compressive strength and density of 1285., Research studies on the manufacture of lightweight concrete (LWC) using
pumice and rice husk ash (RHA) materials have been done. LWC samples were
made of pumice materials with a different mass fraction, while the cement, sand,
and rice husk ash materials were keep fixed. It was found that there are two main
parameters that determine the mechanical properties of LWC which are density
and the water and cement ratio (w/c ratio). The main mechanical properties of
LWC sample is the power press. Samples with the largest volume fraction of
pumice (100%) resulted in lightest density (1389.6 kg/m3) and the smallest
strength of LWC (11.1 MPa). It was found that, the lower the mass fraction of
pumice in LWC samples, the higher the density values and compressive strength
were obtained. This was caused by the high mas fraction value of pores, which
were both open and closed pores. Scanning electron micorscopy (SEM) images
for the pumice showed that the there are a large number of regular and structured
pores extending deep inside the surface of the sample. It was observed that pores
present with pore size does not vary significantly but with the density of the
relatively large number of pores, indicating pumice has a low mass density. The
XRD pattern of the lightweight concrete samples indicated that the samples were
dominated by crystalline phases in which the quartz (SiO2) is the main phase and
a small fraction of amorphous phase was also obtained.
SEM images of lightweight concrete samples showed that the structure of
Calcium Silicate Hydrates (CSH) started growing at the beginning of hydration
time and continue to evolve into a more solid structure until the age of 28 days,
where the compound has an important role to the mechanical properties such as
compressive strength. The study concluded that the pumice and rice husk ash is
are amorphous silica-based material which has a lower density compared to other
concrete forming material such as cement and sands. Both density and light
weight concrete compressive strength are determined by the ratio between pumice
and rice husk ash, in which the smallest ratio 8 resulted in the largest density and
compressive strength, which are 1890.5 kg/m3 and 23.2 MPa respectively at the
age of 28 days. The study concluded that the best composition for lightweight
concrete samples was the following: PCC (1,00): Sand (1,00): ASP (0,05): BA
(0,50) with a slump value of 8 cm resulted in the largest value of a ratio between
compressive strength and density of 1285.]"
2015
D2054
UI - Disertasi Membership  Universitas Indonesia Library
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Davin Philo
"TiO2 nanotube (TNT) telah disintesis dengan metode hydrothermal pada suhu 130 °C, dengan kecepatan pengadukan sebesar 600 rpm, selama 6 jam menggunakan bahan dasar TiO2 P25. Sampel TNT dikarakterisasi dengan SEM/EDX, XRD, UV-Vis DRS, dan BET. Hasil komposit TNT-Batu apung diuji kinerjanya dalam aplikasi degradasi limbah fenol. Uji kinerja dilakukan pada limbah sintetis fenol dengan konsentrasi 10 ppm (300 mL).
Hasil karakterisasi menunjukkan bahwa fotokatalis TNT berhasil disintesis, dimana sampel TNT mempunyai struktur kristal anatase dengan ukuran kristal sebesar 11 nm, band gap (Eg) sebesar 3,2 eV, dan luas permukaan aktif sekitar 101 m2/g. Berdasarkan uji kinerja, disimpulkan bahwa loading TNT optimal pada komposit TNT-Batu apung adalah 2,5 % dengan tingkat degradasi limbah fenol hingga 54 % pada menit ke-150.

TiO2 nanotube (TNT) were synthezised by hydrothermal method at temperature 130 °C, with stirring speed of 600 rpm, for 6 hours, using TiO2 P25 as raw materials. TNT samples were characterized by SEM/EDX, XRD, UV-Vis DRS, and BET. The composites TNT-Pumices were tested in the application of phenol waste degradation. The performance tests were held by using the phenol waste synthetic (10 ppm, 300 mL).
The characterizations showed that TNT photocatalysts were successfully synthesized, where TNT samples had the anathase crystall structure with size of 11 nm, band gap (Eg) of 3,2 eV, and surface area of 100,661 m2/g. Based on the performance test, we could concluded that the optimum loading of TNT is 2,5 %, which could degrade the phenol to 54 % at the minute of 150.
"
Depok: Fakultas Teknik Universitas Indonesia, 2013
S46382
UI - Skripsi Membership  Universitas Indonesia Library
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Ardelia Ramadani
"Komposit Batu Apung-TiO2 telah disintesis dengan metode sol-gel dan digunakan untuk penyisihan fenol dan E.coli. Komposit ini dikarakterisasi dengan FTIR, SEM-EDX, XRD, BET, dan UV-Vis DRS. Hasil karakterisasi tersebut menunjukkan bahwa Komposit Batu Apung-TiO2 memiliki kristalinitas yang tinggi dan band gap yang rendah. Berdasarkan hasil uji penyisihan fenol dan E.coli, diperoleh komposisi komposit optimum sebesar 5%massa TiO2 dan 95%massa batu apung. Waktu penyisihan fenol dari konsentrasi awal 1 hingga 0,01 ppm terjadi sekitar 4,5 jam, sedangkan penyisihan E.coli dari jumlah koloni awal 4x103 hingga 10 CFU/ml berlangsung selama 2 jam. Air sungai yang mengandung fenol dan E.coli berpeluang untuk disisihkan secara simultan hingga baku mutu air bersih. Treatment pencucian dan pengeringan menggunakan hair dryer atau penjemuran sinar matahari merupakan teknik regenerasi yang sesuai untuk mengaktifkan kembali komposit yang telah digunakan.

Pumice-TiO2 composite has been synthesized by sol-gel method and used for phenol and E.coli removal. This composite was characterized by FTIR, SEMEDX, XRD, BET, and UV-Vis DRS. It shown that Pumice-TiO2 composite has high crystallinity and low band gap. Based of phenol and E.coli removal experiments result, the optimum composition of composite were 5% mass of TiO2 and 95%mass of pumice. Time duration of phenol removal from 1 to 0,01 ppm was about 4,5 hours, while E.coli removal from 4x103 to 10 CFU/ml spent 2 hours. River water which contained phenol and E.coli was able to be removed simultaneously up to clean water standard. Washing and drying treatment by using hair dryer or sunlight was an appropriate regeneration technique for composite reactivation.
"
Depok: Fakultas Teknik Universitas Indonesia, 2013
S52899
UI - Skripsi Membership  Universitas Indonesia Library
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Imam Hidayat Nurwahid
"Pemanfaatan bahan yang berlimpah di alam sebagai bahan baku alternatif yang lebih ekonomis dan dapat pula mengurangi limbah padat yang dihasilkan oleh berbagai industri dengan mengubahnya menjadi produk yang bermanfaat. Pada penelitian ini, dilakukan ekstraksi SiO2 dari ampas tebu dan batu apung dengan menggunakan metode ekstraksi alkali suhu rendah dan proses presipitasi asam. SiO2 yang telah diekstraksi kemudian dikarakterisasi menggunakan X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), dan Ultraviolet/Visible Diffuse Reflectance Spectroscopy (UV/VIS DRS). Hasil yang diperoleh menunjukkan bahwa SiO2 telah berhasil diekstraksi dari ampas tebu dan batu apung dengan tingkat kemurnian yang tinggi, yang dikonfirmasi oleh hasil XRF (98,4% dan 96,3%). Data karakterisasi XRD dan FTIR mengkonfirmasi bahwa hasil ekstraksi SiO2 memiliki struktur amorf dan terdapat gugus siloksan dan silanol. Ukuran partikel SiO2 hasil ekstraksi dari ampas tebu dan batu apung adalah 4,95 nm dan 6,19 nm. Modifikasi SiO2 dilakukan dengan penambahan logam perak untuk membentuk katalis Ag2O/SiO2. Hasil modifikasi dikarakterisasi menggunakan XRD, FTIR, SEM, Transmission Electron Microscopy (TEM), dan UV/VIS DRS. Katalis yang telah disintesis digunakan dalam aplikasi reduksi 4-nitrophenol (4-NP) yang menunjukkan bahwa waktu yang diperlukan untuk mereduksi 4-NP dengan katalis Ag2O/SiO2 dari batu apung lebih cepat dibandingkan dengan katalis Ag2O/SiO2 dari ampas tebu. Aktivitas katalitiknya yang diamati menggunakan spektroskopi UV/VIS (Ultraviolet/Visible) dan dihasilkan bahwa katalis Ag2O/SiO2 dari batu apung lebih baik daripada katalis Ag2O/SiO2 dari ampas tebu.

Utilization of materials that are abundant in nature as an alternative raw material that is more economical and can also reduce solid waste generated by various industries by turning it into a useful product. In this study, SiO2 was extracted from sugarcane bagasse and pumice stone by using a low-temperature alkaline extraction method and acid precipitation process. The extracted SiO2 was then characterized using X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), and Ultraviolet/Visible Diffuse Reflectance Spectroscopy (UV/VIS DRS). The results obtained showed that SiO2 was successfully extracted from sugarcane bagasse and pumice stone with high purity, which was confirmed by XRF results (98.4% and 96.3%). The XRD and FTIR characterization data confirm that the extraction of SiO2 has an amorphous structure and has siloxane and silanol groups. The particle size of SiO2 extracted from sugarcane bagasse and pumice stone is 4.95 nm and 6.19 nm. Modification of SiO2 is done by adding silver metal to form Ag2O/SiO2 catalyst. The modification results were characterized using XRD, FTIR, SEM, Transmission Electron Microscopy (TEM), and UV/VIS DRS. The synthesized catalyst is used in the 4-nitrophenol (4-NP) reduction which shows that the time needed to reduce 4-NP with Ag2O/SiO2 catalyst from pumice stone is faster than Ag2O/SiO2 catalyst from sugarcane bagasse. The catalytic activity was observed using UV/VIS (Ultraviolet/Visible) spectroscopy and it was found that the Ag2O/SiO2 catalyst from pumice stone was better than the Ag2O/SiO2 catalyst from sugarcane bagasse.
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Depok: Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Indonesia, 2020
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