Hasil Pencarian  ::  Simpan CSV :: Kembali

"[ABSTRAKTesis ini membahas pengaruh penambahan aditif pemodifikasi gesekan serbuk MoS2 ukuran 1 5 m dengan jumlah mulai 0 05 0 1 0 5 1 dan 2 berat dan ukuran 90 nm sebesar 0 05 0 1 0 5 pada minyak lumas dasar mineral HVI 60 terhadap karakteristik gesekan dan perlindungan keausannya Aditif ukuran 90 nm dan minyak lumas dasar dicampur dan diaduk menggunakan magnetik stirrer selama enam puluh menit pada suhu 50oC setelah itu dimasukkan ke dalam ultrasonic homogenizer selama satu jam sedangkan aditif ukuran 1 5 m pada suhu 75oC tanpa menggunakan ultrasonic homogenizer Campuran yang dihasilkan diuji karakteristik gesekan dan perlindungan keausannya menggunakan mesin uji four ball dan mesin uji SRV Analisis dilakukan pada material bola uji menggunakan optical emission spectroscopy OES goresan permukaan bola uji menggunakan scanning electron microscope SEM dan minyak lumas sisa pengujian dengan alat uji rotating disk electrode RDE Hasil penelitian menunjukkan bahwa penambahan aditif meningkatkan perlindungan keausan dengan dosis optimal sebesar 0 1 berat dengan rincian ukuran 1 5 m perbaikannya sebesar 23 dan ukuran 90 nm sebesar 11 Pengamatan permukaan goresan menunjukkan mekanisme keausan terjadi secara adesif dan abrasif Data yang diperoleh dari penelitian ini bisa digunakan sebagai dasar dalam pembuatan minyak lumas untuk aplikasi tertentu dengan mutu yang lebih baik

---

ABSTRACTThis thesis discusses the influence of MoS2 friction modifier FM addition in the form of powder with two different mesh sizes i e 90 nm and 1 5 um on the friction and wear characteristic of HVI 60 base oil The variation of MoS2 were 0 05 0 1 0 5 weight whereas MoS2 1 5 um were 0 05 0 1 0 5 1 and 2 weight MoS2 additive 90 nm was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 50oC and homogenized in ultrasonic homogenizer for 1 hour For the MoS2 1 5 um the additive was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 75oC without using ultrasonic homogenizer Friction and wear characteristic of these mixtures were tested using four ball and SRV test rig Ball specimen surfaces were analyzed by using optical emission spectroscopy OES the wear scars were analyzed by using scanning electron microscope SEM while used mixtures from the test were analyzed by using rotating disk electrode RDE The results of the tests showed that the addition of 0 1 weight MoS2 additive both in 90 nm and 1 5 um resulted in an optimum increase in friction and wear characteristic of 23 and 11 respectively Observation on the wear scar showed that adhesive and abrasive wear mechanism were involved in the wear process The results of this research could be applied in production of lubricating oils for certain applications to improve their quality ;This thesis discusses the influence of MoS2 friction modifier FM addition in the form of powder with two different mesh sizes i e 90 nm and 1 5 um on the friction and wear characteristic of HVI 60 base oil The variation of MoS2 were 0 05 0 1 0 5 weight whereas MoS2 1 5 um were 0 05 0 1 0 5 1 and 2 weight MoS2 additive 90 nm was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 50oC and homogenized in ultrasonic homogenizer for 1 hour For the MoS2 1 5 um the additive was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 75oC without using ultrasonic homogenizer Friction and wear characteristic of these mixtures were tested using four ball and SRV test rig Ball specimen surfaces were analyzed by using optical emission spectroscopy OES the wear scars were analyzed by using scanning electron microscope SEM while used mixtures from the test were analyzed by using rotating disk electrode RDE The results of the tests showed that the addition of 0 1 weight MoS2 additive both in 90 nm and 1 5 um resulted in an optimum increase in friction and wear characteristic of 23 and 11 respectively Observation on the wear scar showed that adhesive and abrasive wear mechanism were involved in the wear process The results of this research could be applied in production of lubricating oils for certain applications to improve their quality ;This thesis discusses the influence of MoS2 friction modifier FM addition in the form of powder with two different mesh sizes i e 90 nm and 1 5 um on the friction and wear characteristic of HVI 60 base oil The variation of MoS2 were 0 05 0 1 0 5 weight whereas MoS2 1 5 um were 0 05 0 1 0 5 1 and 2 weight MoS2 additive 90 nm was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 50oC and homogenized in ultrasonic homogenizer for 1 hour For the MoS2 1 5 um the additive was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 75oC without using ultrasonic homogenizer Friction and wear characteristic of these mixtures were tested using four ball and SRV test rig Ball specimen surfaces were analyzed by using optical emission spectroscopy OES the wear scars were analyzed by using scanning electron microscope SEM while used mixtures from the test were analyzed by using rotating disk electrode RDE The results of the tests showed that the addition of 0 1 weight MoS2 additive both in 90 nm and 1 5 um resulted in an optimum increase in friction and wear characteristic of 23 and 11 respectively Observation on the wear scar showed that adhesive and abrasive wear mechanism were involved in the wear process The results of this research could be applied in production of lubricating oils for certain applications to improve their quality ;This thesis discusses the influence of MoS2 friction modifier FM addition in the form of powder with two different mesh sizes i e 90 nm and 1 5 um on the friction and wear characteristic of HVI 60 base oil The variation of MoS2 were 0 05 0 1 0 5 weight whereas MoS2 1 5 um were 0 05 0 1 0 5 1 and 2 weight MoS2 additive 90 nm was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 50oC and homogenized in ultrasonic homogenizer for 1 hour For the MoS2 1 5 um the additive was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 75oC without using ultrasonic homogenizer Friction and wear characteristic of these mixtures were tested using four ball and SRV test rig Ball specimen surfaces were analyzed by using optical emission spectroscopy OES the wear scars were analyzed by using scanning electron microscope SEM while used mixtures from the test were analyzed by using rotating disk electrode RDE The results of the tests showed that the addition of 0 1 weight MoS2 additive both in 90 nm and 1 5 um resulted in an optimum increase in friction and wear characteristic of 23 and 11 respectively Observation on the wear scar showed that adhesive and abrasive wear mechanism were involved in the wear process The results of this research could be applied in production of lubricating oils for certain applications to improve their quality ;This thesis discusses the influence of MoS2 friction modifier FM addition in the form of powder with two different mesh sizes i e 90 nm and 1 5 um on the friction and wear characteristic of HVI 60 base oil The variation of MoS2 were 0 05 0 1 0 5 weight whereas MoS2 1 5 um were 0 05 0 1 0 5 1 and 2 weight MoS2 additive 90 nm was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 50oC and homogenized in ultrasonic homogenizer for 1 hour For the MoS2 1 5 um the additive was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 75oC without using ultrasonic homogenizer Friction and wear characteristic of these mixtures were tested using four ball and SRV test rig Ball specimen surfaces were analyzed by using optical emission spectroscopy OES the wear scars were analyzed by using scanning electron microscope SEM while used mixtures from the test were analyzed by using rotating disk electrode RDE The results of the tests showed that the addition of 0 1 weight MoS2 additive both in 90 nm and 1 5 um resulted in an optimum increase in friction and wear characteristic of 23 and 11 respectively Observation on the wear scar showed that adhesive and abrasive wear mechanism were involved in the wear process The results of this research could be applied in production of lubricating oils for certain applications to improve their quality , This thesis discusses the influence of MoS2 friction modifier FM addition in the form of powder with two different mesh sizes i e 90 nm and 1 5 um on the friction and wear characteristic of HVI 60 base oil The variation of MoS2 were 0 05 0 1 0 5 weight whereas MoS2 1 5 um were 0 05 0 1 0 5 1 and 2 weight MoS2 additive 90 nm was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 50oC and homogenized in ultrasonic homogenizer for 1 hour For the MoS2 1 5 um the additive was mixed with base oil and stirred with magnetic stirrer for 60 minutes at 75oC without using ultrasonic homogenizer Friction and wear characteristic of these mixtures were tested using four ball and SRV test rig Ball specimen surfaces were analyzed by using optical emission spectroscopy OES the wear scars were analyzed by using scanning electron microscope SEM while used mixtures from the test were analyzed by using rotating disk electrode RDE The results of the tests showed that the addition of 0 1 weight MoS2 additive both in 90 nm and 1 5 um resulted in an optimum increase in friction and wear characteristic of 23 and 11 respectively Observation on the wear scar showed that adhesive and abrasive wear mechanism were involved in the wear process The results of this research could be applied in production of lubricating oils for certain applications to improve their quality ]"

"Friksi yang tidak dikendalikan pada mesin dapat mengakibatkan keausan yang tinggi, menyebabkan maintenance yang sering, dan membuat umur pendek serta memiliki efisiensi energi yang rendah. Lubrikasi merupakan solusi untuk masalah ini dengan membentuk lapisan pelumas yang mencegah kontak langsung antara permukaan material, mengurangi gesekan dan keausan pada mesin. Material nanopartikel timah oksida dan graphene digunakan sebagai aditif pada lubrikan PAO karena masing-masing material sudah menunjukkan performa yang baik dalam menurunkan coefficient of friction (COF) dan wear scar dimension (WSD) pada minyak PAO. Selain itu usaha pemanfaatan SnO2 dilakukan guna memaksimalkan hilirasi tambang dan industri timah dengan usaha pengolahan limbah solder dross. Sintesis SnO₂ dilakukan dari limbah solder dross menggunakan metode leaching dengan asam nitrat berkonsentrasi 68%. Hasil sintesis menunjukkan kemurnian SnO₂ sebesar 98.4%. Karakterisasi XRD mengindikasikan fase kristal rutile dengan ukuran kristal sekitar 21.7 nm. SEM-EDS mengungkapkan partikel SnO₂ berukuran rata-rata 198.5 nm² yang cenderung beraglomerasi. Graphene yang digunakan menunjukkan kemurnian tinggi dengan kandungan karbon 99.4% berdasarkan berat. Pengujian HFRR dilakukan untuk menilai kinerja tribologi dari berbagai sampel pelumas. Penambahan 0.05 wt% graphene dan variasi konsentrasi SnO₂ (1 wt%, 3 wt%, dan 5 wt%) secara signifikan menurunkan COF dan WSD dibandingkan dengan PAO murni. Penambahan 1 wt% SnO₂ dan 0.05 wt% graphene memberikan hasil paling optimal dengan penurunan COF sebesar 44.59% dan WSD sebesar 71.53% dibandingkan PAO murni.

---

Uncontrolled friction in machinery can lead to high wear, frequent maintenance, short lifespan, and low energy efficiency. Lubrication addresses these issues by forming a lubricating layer that prevents direct contact between material surfaces, reducing friction and wear. Tin oxide nanoparticles and graphene are used as additives in PAO lubricants due to their proven performance in reducing the coefficient of friction (COF) and wear scar dimension (WSD) in PAO oil. Additionally, the utilization of SnO₂ aims to optimize downstream mining and the tin industry by processing solder dross waste. SnO₂ was synthesized from solder dross waste using a leaching method with 68% nitric acid. The synthesis resulted in SnO₂ with a purity of 98.4%. XRD characterization indicated a rutile crystal phase with a crystal size of approximately 21.7 nm. SEM-EDS revealed SnO₂ particles with an average size of 198.5 nm², which tended to agglomerate. The graphene used exhibited high purity with a carbon content of 99.4% by weight. HFRR testing was conducted to evaluate the tribological performance of various lubricant samples. The addition of 0.05 wt% graphene and varying concentrations of SnO₂ (1 wt%, 3 wt%, and 5 wt%) significantly reduced COF and WSD compared to pure PAO. The optimal results were achieved with the addition of 1 wt% SnO₂ and 0.05 wt% graphene, resulting in a 44.59% reduction in COF and a 71.53% reduction in WSD compared to pure PAO."

"Molibdenum disulfida merupakan aditif gemuk yang terkenal karena memiliki sifat ketahanan aus yang sangat baik. Ukuran partikel memengaruhi kinerja aditif, dimana semakin kecil ukuran partikel akan memberikan sifat ketahanan aus yang semakin baik. Namun diperlukan biaya yang semakin besar untuk memperoleh partikel berukuran kecil. Oleh karena itu, dibutuhkan penelitian terkait kombinasi ukuran partikel aditif molibdenum disulfida terhadap efektivitas kerja pelumasan gemuk untuk memaksimalkan efisiensi biaya yang diperlukan. Pembuatan gemuk dilakukan melalui reaksi saponifikasi minyak sawit sebagai bahan dasar dengan asam 12-hidroksi stearat, kalsium hidroksida, dan asam asetat sebagai pengental. Hasil bio-gemuk kalsium kompleks NLGI 2 selanjutnya dicampur dengan bubuk aditif molibdenum disulfida 1% b/b. Ukuran partikel aditif divariasikan menjadi 5 μm (Mb), 2 μm (Mk), dan 100 nm (N). Selain itu, dilakukan variasi kombinasi dua ukuran meliputi Mb+Mk, Mb+N, Mk+N, serta kombinasi tiga ukuran dengan komposisi berbeda. Partikel dikarakterisasi ukurannya menggunakan TEM dan PSA. Sedangkan gemuk dikaraktersasi menggunakan uji penetrasi, dropping point, dan four-ball. Hasil penelitian menunjukkan bahwa penambahan aditif molibdenum disulfida dapat mencegah keausan. Selanjutnya, kombinasi tiga ukuran terbukti efektif dalam meningkatkan performa anti-wear, diikuti dengan kombinasi dua dan satu ukuran, dimana hasil paling optimum yaitu dengan komposisi 1:1:1. Namun, penambahan aditif tidak memengaruhi tingkat penetrasi dan dropping point.

---

Molybdenum disulfide is a grease additive known for its excellent anti-wear properties. Its performance is affected by particle size, where the smaller the particle will provide better anti-wear performance. In consequence, higher costs are needed. Therefore, research is needed on the particle size combination of molybdenum disulfide particles on tribological performance to achieve cost efficient grease. The grease is made through the saponification reaction of palm oil as base material with 12-hydroxystearic acid, calcium hydroxide, and acetic acid as thickener. The resulting NLGI 2 calcium complex bio-grease was then mixed with 1% w/w molybdenum disulfide powder. The additive particle size was varied into 5 μm (Mb), 2 μm (Mk), and 100 nm (N). Various combinations of two sizes were also carried out, while three sizes were varied by its compositions. Particles were characterized using TEM and PSA, meanwhile bio-grease using penetration, drop point, and four ball tests. The results showed that the addition of molybdenum disulfide could prevent wear. Furthermore, combination of three sizes was proven to be effective in increasing anti-wear performance, followed by combination of two and one size, with optimal results of 1:1:1. However, the addition of additives did not affect the penetration rate and drop point."

"Minyak pelumas Mesran Super SAE 20W/50 yang telah dipakai akan mengalami berbagai proses dan kontak dengan material yang lain. Dengan demikian setelah mencapai periode pemakaian tertentu minyak pelumas akan mengalami pembahan nilai-nilai spesifikasinya. Dalam hal ini pengamatan dilakukan terhadap penurunan kekentalan (viskositas) minyak pelumas Mesran Super SAE 20W/50, yang telah dipakai selama 0 km, 1000 km, 2000 km dan 3000 km. Akibat penurunan viskositas ini terjadi tendensi/kecenderungan perubahan daerah pelumasan dari pelumasan hidrodinamika (hydrocivnamic Iubricalion) ke pelumasan batas (boundary lubrication) pada celah antara poros dan bantalan. Terjadi keausan pada permukaan poros pada putaran rendah Pengamatan keausan ini dilakukan dengan mengamati perubahan kekasaran permukaan pada permukaan poros, foto permukaan poros, dan rnelakukan uji laju keausan yang terlumasi pada kecepatan rendah. Hasil pengamatan menunjukkan bertambahnya laju keausan sesuai dengan berlambahnya umur pakai pelumas."

"Spent Bleaching Earth dan minyak jelantah merupakan limbah industri dengan jumlah produksi yang sangat besar di Indonesia hingga 600.000 ton/tahun. SBE memiliki kadar SiO2 sebesar 55-80 hal inilah yang dapat dijadikan potensi untuk pembuatan gemuk sebagai pengentalnya. Gemuk berfungsi untuk mengurangi gesekan dan keausan pada permukaan benda yang bersinggungan serta memiliki kemampuan untuk menempel di dekat permukaan gesek. Gemuk yang beredar dipasaran umumnya menggunakan NLGI grade 2 karena memiliki daya kelengketan lebih baik serta dropping point dan anti wear yang tinggi. NLGI grade 2 disebut gemuk multipurpose karena dapat digunakan pada hampir seluruh alat mesin pada otomotif, industri, konstruksi, manufaktur dll.Penelitian ini bertujuan untuk menghasilkan gemuk NLGI grade 2 dengan memformulasikan SBE, minyak jelantah, dan kalsium sulfonat. Kalsium sulfonat dipilih karna dapat meningkatkan konsistensi dan performa gemuk serta jenis sabun yang biayanya paling murah. Pre-treatment dalam proses pembuatan adalah dilakukan filtrasi dan pemanasan pada minyak jelantah serta pengayakkan untuk SBE. Pembuatan Gemuk melalui proses saponifikasi dengan suhu maksimal 66°C dan homogenisasi hingga 8 jam. Komposisi optimum yang didapat yaitu dengan perbandingan SBE dan minyak jelantah 70:30 serta penambahan kalsium sulfonat 12 menghasilkan nilai bleeding 0,7 ; nilai keausan 0,23 mg; dan nilai dropping point 267°C. Dari hasil penelitian ini dapat disimpulkan gemuk berbahan dasar limbah industri dengan tambahan kalsium sulfonat memiliki kualitas yang setara dengan gemuk komersil sebagai pembanding.

---

Spent Bleaching Earth and Waste Cooking Oil is industrial waste with an enormous amount of production in Indonesia up to 600,000 tons year. SBE contains 55 ndash 80 of SiO2 that can be used for the formulation of grease as the thickening agent. The function of grease is to decrease the friction and the wear on the surface of the intersecting object and has the ability to stick near to friction surface. Grease available in market generally use NLGI grade 2 because it has better adhesiveness and high dropping point and antiwear value. NLGI Grade 2 is commonly called as multipurpose grease due to its ability to be applied to almost all machine tools in automotive, construction, manufacture, industries, etc.

This study aims to produce NLGI Grade 2 by formulating SBE, Waste Cooking Oil, and Calcium Sulfonate. Calcium Sulfonate is selected to be used because it can improve the consistency and performance of the grease and the type of soap with affordable price. Pre treatment in the manufacturing process is filtration and heating the Waste Cooking Oil and sifting for SBE. The Grease is produced through saponification process with maximum temperature 66°C and homogenization up to 8 hours. The optimum composition obtained by the composition of SBE and cooking oil 70 30 and the addition of 12 calcium sulfonate yields, 0.7 bleeding value wear value is 0.23 mg and dropping point value is 267°C. The results of this study can be concluded that Industrial waste based Grease with additional calcium sulfonate has a quality equivalent to commercial Grease as a comparison."

"Kualitas kerja bantalan sangat dipengaruhi oleh sistem pelumasannya. Pengembangan sistem pelumasan dilakukan dengan pembentukan sistem interlocking ? adsorbsi yang digabungkan dalam pelumas padat, dibentuk melalui pelapisan komposit Zn3(PO4)2 / MoS2 / MWCNT / nanografit / Na2SiO3 secara pencelupan kimiawi. Teknik one mixing layer menunjukkan kemampuan pembentukan lapisan tipis yang homogen. Kombinasi kristal phospat, phosphophyllite dan hopeite, terbentuk di matriks komposit. Permukaan kasar terbentuk pada bola komposit, tingkat kekasaran bola komposit I: 1,350 m, komposit II: 1,000 m dan komposit III: 0,475 m. Ketebalan komposit berada pada daerah 5 ? 6 m. Pelumas dapat teradsorb dalam lapisan komposit, terjadi interaksi ikatan hidrogen antara pelumas dan kristal phosphat. Multi walled carbon nanotube mempunyai kemampuan interlocking dan pelumas padat yang lebih baik dibandingkan grafit ketjenblack. Bola komposit memiliki ketahanan friksi yang lebih baik dibanding bola tanpa pelapisan ataupun bola berlapis MoS2; bola komposit II memiliki rasio umur pakai tertinggi (17,92) untuk uji friksi satu kali pelumasan, sedangkan umur pakai tertinggi uji friksi simulasi pelumasan berkala dimiliki oleh kedua bola komposit II dan III (rasio > 28,3).

---

Work quality of bearing is strongly influenced by its lubrication system. Development of lubrication system can be done by create an interlocking and adsorbtion system which is combined by solid lubricants. It was formed through a coating of Zn3(PO4)2 / MoS2 / MWCNT / nanografit / Na2SiO3 composite by chemical immersing. One mixing layer technique show good ability to produce homogeneous thin layer. Combinations of phosphate crystals, phosphophyllite and hopeite, was formed in the composite matrix. Rough surface was formed on composite ball, roughness of composite I ball: 1.350 m, composites II ball: 1.000 m and composites III ball: 0.475 m. Thickness of composite is in the region of 5 - 6 m. Lubricants can be adsorbed in composite layer, lubricants and phosphate crystals have hydrogen bonding interaction. Multi walled carbon nanotube has better interlocking and solid lubricants capabilities than its graphite ketjenblack. Composite ball has a better friction resistance than no coating ball and MoS2 coated balls; composite II ball has the highest lifetime ratio (17.92) for a one-time lubrication friction test, while the highest lifetime friction test simulating periodic lubrication is owned by both of composites II and III ball (ratio> 28.3)."