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"Material berbasis DMSs menarik perhatian yang cukup besar beberapa tahun terakhir dimana modifikasi dapat dilakukan dengan menyisipkan atom dari golongan logam transisi pada posisi atom utama. Salah satu kandidat material DMSs oksida logam terbaik adalah ZnO. ZnO dengan energy gap yang besar dapat digunakan untuk aplikasi peralatan spintronik. Sekarang ini, banyak penelitian mengenai ZnO berbasis DMSs dengan penambahan logam transisi dilakukan, ketika penelitian sebelumnya mendapati sifat ferromagnetik diatas temperatur ruang.Pada penelitian ini dipelajari efek penambahan atom mangan pada nanopartikel ZnO terhadap struktural, sifat optik dan magnetik. Semua sampel disintesa pada temperatur rendah dengan metode ko-presipitasi hingga konsentrasi dopant sebesar 30 at.%. Komposisi sampel diinvestigasi dengan karakterisasi Energy dispersive X-ray (EDX). Dari hasil analisis pola XRD, keseluruhan sampel memiliki struktur hexagonal wurtzite. Dari refinement Rietveld spektrum XRD, diketahui dengan meningkatnya konsentrasi doping, parameter kisi dan volume sel berubah seiring perubahan radius ionik atom.Analisis sifat optik dari sampel menunjukkan pergeseran kearah frekuensi merah pada absorption band edge dengan penambahan mangan pada ZnO. Spektroskopi Fourier Transform Infrared dilakukan untuk mengkonfirmasi formasi sampel dan mengidentifikasi jenis-jenis absorbansi pada kristal. Sifat magnetik dari sampel dikarakterisasi dengan Electron Spin Resonance (ESR) and Vibrating Sample Magnetometes (VSM). Keseluruhan hasil dari karakterisasi XRD, UV-Vis, FT-IR, ESR dan VSM akan didiskusikan lebih lanjut.

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Diluted magnetic semiconductor (DMSs) materials have attracted a great attention in the recent years, which the transition metal atoms replace the host atoms. One of the best candidates in semiconducting metal oxides is Zinc Oxide (ZnO). ZnO with wide band gap (3.37 eV) can use for optoelectronic device applications. Currently, many research on ZnO-based DMSs with most of transition metal elements have been carried out when previous studies invented ferromagnetism (RT) above room temperature (RT).

In this research, we studied effect of manganese inclusion on structural, optical and magnetic properties of nanocrystalline Mn- doped ZnO particles. All samples were carefully prepared at low temperature by co-precipitation method with dopant concentration up to 30 at.%. The composition of these samples was investigated by Energy dispersive X-ray (EDX) measurement.

From the analysis of XRD pattern, all samples are identified to be a hexagonal wurtzite structure. From the Rietveld refined XRD spectra, as the doping concentrations were increased, the lattice parameters and unit cell volume shifted more proportional to the ionic radii. Optical absorption analysis of all samples showed a red shift in absorption band edge with manganese doping in ZnO. Fourier Transform Infrared spectroscopy were undertaken for all samples to confirm the formation of Mndoped ZnO particles and to identify any adsorbed species into the crystals. Magnetic properties of these samples has been characterized using Electron Spin Resonance (ESR) and Vibrating Sample Magnetometes (VSM). The results from XRD, UV-Vis, FT-IR, ESR and VSM will be correlated and discussed."

"Nanopartikel Ni doped ZnO dengan empat variasi konsentrasi ( 3, 6, 10, dan 20 %) telah berhasil disintesa menggunakan metode kopresipitasi menggunakan reagen zinc sulfate heptahydrate (ZnSO4.7H2O) dan nickel (II) nitrate hexahydrate (N2NiO6.6H2O). Semua sampel dikarakterisasi dengan menggunakan spektroskopi EDX (Energy Dispersive X-ray spectroscopy), XRD (X-ray Diffraction), dan spektroskopi UV-Vis. Pengukuran nilai crystallite size telah dilakukan menggunakan metode Scherrer dan Williamson-Hall. Nilai crystallite size mengalami penurunan seiring dengan bertambahnya konsentrasi atom Ni pada nanopartikel ZnO. Tiga metode Williamson-Hall juga digunakan untuk menghitung nilai strain, stress, dan energy density. Nilai celah pita energi nanopartikel Ni doped ZnO cenderung berkurang dengan peningkatan persen atom Ni.

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A series of Ni doped ZnO nanoparticles ( 3, 6, 10, and 20 %) are successfully synthesized by coprecipitation technique with zinc sulfate heptahydrate (ZnSO4.7H2O) and nickel (II) nitrate hexahydrate (N2NiO6.6H2O). The composition, structural and optical characterizations were performed by EDX (Energy Dispersive X-ray spectroscopy), XRD (X-ray Diffraction), and UV-Visible. Crystallite size were determined from X-ray peak broadening using Scherrer and Williamson-Hall. The presence of Ni tends to reduce crystallite size. A modified W-H plot has been worked out and accepted as determining not only the crystallite size but also strain, stress, and energy density. The presence of Ni tends to reduce the width of the optical gap associated with increasing of Ni dopants."

"Upaya kodoping ZnO dengan dua jenis unsur logam transisi yang berbeda diyakini mampu meningkatkan kualitas sifat room temperature ferromagnetic (RTFM) dari diluted magnetic semiconductor (DMS) ZnO yang didoping menggunakan satu jenis logam transisi saja. Oleh sebab itu pada penelitian ini, dilakukan studi mengenai efek penambahan unsur Mangan (Mn), Kobalt (Co), Nikel (Ni) dan Tembaga (Cu) pada nanopartikel Fe - doped ZnO terhadap perubahan struktur, sifat optik dan sifat magnetiknya.Pembuatan sampel dilakukan dengan metode ko-presipitasi pada temperatur ruangan. Analisis struktur sampel dilakukan menggunakan pengukuran Energy Dispersive X-ray (EDX), X-ray diffraction (XRD), dan Fourier Transform Infrared (FT-IR), sedangkan studi mengenai sifat optiknya dilakukan berdasarkan hasil spektroskopi Uv-vis. Adapun sifat magnetik dari sampel dipelajari melalui pengukuran Electron Spin Resonance (ESR) dan Vibrating Sample Magnetometer (VSM).Pola difraksi XRD menunjukkan bahwa keempat sampel masih memiliki struktur hexagonal wurtzite ZnO dalam batas sensitivitas alat ukur. Hasil pengukuran Uv-vis menunjukkan adanya penurunan nilai celah energi akibat pembentukan mid-gap. Sementara itu, hasil pengukuran ESR menunjukkan adanya pengaruh ion-ion dopan sekunder (Mn, Co, Ni, dan Cu) dalam menentukan sifat magnetik sampel. Dan hasil pengukuran VSM menunjukkan adanya penguatan sifat RTFM yang signifikan.

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The attempt of codoping ZnO with two different kinds of transition metal elements is believed to be the key to enhance the room temperature ferromagnetism (RTFM) of single transition metal - doped ZnO diluted magnetic semiconductor (DMS). Therefore, within the scope of this research, the effects of adding Manganese (Mn), Cobalt (Co), Nickel (Ni), and Cooper (Cu) regarding to the structural, optical, and magnetic properties change of Fe - doped ZnO nanoparticles have been studied.

The synthesis of the samples was done by co-precipitation method at room temperature. The structural analysis had been performed by Energy Dispersive X- ray (EDX), X-ray Diffraction (XRD), and Fourier Transform Infrared (FT-IR) measurements, meanwhile the optical properties were studied based on the result of Uv-vis spectroscopy. The magnetic properties were studied through Electron Spin Resonance (ESR) and Vibrating Sample Magnetometer (VSM) measurements.

The diffraction pattern of XRD shows that all of the samples still possess hexagonal wurtzite ZnO structure within the sensitivity limit of the spectrometer. The Uv-vis measurement results indicate the decrease in band gap due to the forming of mid-gaps. Meanwhile, ESR measurement results reveal the influence of secondary dopant ions (Mn, Co, Ni, and Cu) that affects the magnetic behavior. Moreover, the VSM measurement result shows a significant enhancement of RTFM."

"Satu seri nanopartikel TiO2 didop Ni dengan variasi konsentrasi Ni dibuat dengan metode kopresipitasi. Komposisi elemen, sifat strukFtur, dan optik dikarakterisasi menggunakan X-Ray Diffraction, Electron Dispersive X-Ray dan UV-VIS diffuse reflectance spectroscopy. Identifikasi spesies paramagnetik dilakukan menggunakan Electron Spin Resonance. Berdasarkan pola difraksi XRD, hanya fase tunggal anatase yang muncul karena radius ionik Ni2+ dan Ti4+ yang hampir sama sehingga dapat menggantikan ion-ion Ti4+ pada kristal TiO2. Ukuran kristal rata-rata menurun seiring dengan peningkatan konsentrasi Ni.Fenomena ini kemungkinan terjadi akibat kehadiran ion-ion Ni2+ yang menghambat pertumbuhan kristal. Spektrum reflektansi difus UV-VIS menunjukkan bahwa penyerapan UV bergeser ke arah panjang gelombang sinar merah dan celah pita energi menurun. Hal ini disebabkan oleh atom-atom Ni yang membentuk levellevel energi localized dibawah pita konduksi pada kristal TiO2. Studi ESR pada nanopartikel TiO2 didop Ni menunjukkan adanya kehadiran Ni+, Ti3+, dan defek oksigen pada semua sampel.

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A series Ni doped TiO2 nanoparticles with different Ni dopant concentration were facricated by coprecipitation method. The element composition, structural, and optical properties were characterized using X-Ray Diffraction, Electron Dispersive X-Ray and UV-VIS diffuse reflectance spectroscopy. Identification of paramagnetic species are conducted using Electron Spin Resonance. Based on XRD pattern, only single phase of anatase were appeared because the almost similar ionic radius of Ni2+ to that of Ti4+ which was found to replace some portion of Ti4+ ions in TiO2 lattice. The crystallite size decreases with increasing Ni content.

This phenomena probably arisen from introducing of Ni2+ ions which decrease crystalline growth. The UV-VIS diffuse reflectance spectra showed that the UV absorption moved to a longer wavelength (red shift) and the band gap energy was decreased. It caused the doped Ni atoms formed a localized energy states below conduction band of TiO2 lattice. ESR studies of Ni doped TiO2 nanoparticles revealed the presence of Ni+, Ti3+, and oxygen defects in all samples."

"ZnO nanopartikel dengan berbagai variasi konsentrasi dopan Co2+ (3, 6, 15 dan 17 at.%) disintesis dengan metode ko-presipitasi. Karakerisasi yang dilakukan meliputi pengukuran EDX, XRD dan UV-VIS untuk mengamati struktur dan sifat optis dari ZnO didop Co nanopartikel. Komposisi Co dalam sample dikatahui dari karakterisasi EDX,. Hasil difraksi sinar X (XRD) menunjukkan bahwa sampel memiliki fase wurtzite dan tidak ditemaknnya fase sekunder. Hasil tersebut membuktikan bahwa ion Co2+ telah berhasil mensubtitusi Zn2+ dalam matrix ZnO. Analisis pelebaran puncak sinar X dilakukan untuk menilai crystalline size dan lattice strain dengan menggunakan metode analisis Williamson-Hall (W-H). Seluruh parameter terkait seperti strain, stress dan nilai energy density turut ditentukan nilainya dengan menggunakan berbagai model dari analisis W-H, yakni uniform deformation model (UDM), uniform stress deformation model (USDM) dan uniform deformation energy density model (UDEDM). Ketiga model analisis tersebut akan menghasilkan nilai strain yang berbeda diakibatkan pendekatan-pendekatan yang dilakukan. Sifat optis seperti celah pita energy dikarakterisasi dengan spektroskopi UV-VIS menunjukan penurunan seiring dengan bertambahnya konsentrasi dopan yang diberikan.

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ZnO nanoparticles with different Co2+ doping concentrations (3,6,15 and 17 at.%) were synthesized by co-precipitation method. Characterization technique of EDX, XRD and UV-Visible spectra measurement were done to investigate the effects of the doping concentration on the structural and optical properties of Co doped ZnO nanoparticles (NP). The compositional analysis was carried out by Energy Dispersive X-Ray (EDX) measurement. X-Ray diffraction analysis reveals that the Co doped ZnO NP crystallize in wurzite structure without any impurity phase and Co2+ ion were successfully incorporated into the lattice position of Zn2+ ions in ZnO matrix. The wurzite structure (lattice constant) is decreasing with increasing Co doping concentration, it show their crystallization decrease with the increase of Co2+ doping Concentration. The crystalline development in the Co doped ZnO NP was investigated by X-Ray peak broadening. The Williamson-Hall (WH) analysis was used to study the individual contribution of crystallize size and lattice strain on the peak broadening. All other relevant physical parameter such as strain, stress and energy density values were also calculated using W-H plot analysis with different model, viz, uniform deformation model, uniform stress deformation model and uniform deformation energy density model, the three models yield different strain values, it may be due to anisotropic nature or the material. The optical studies show that the band gap of Co doped ZnO NP decreases with increase doping concentration."

"Barium atau Strontium Hexaferrite (SrFe12O19 , SHF) telah digunakan secara luas sebagai magnet permanen karena memiliki sifat kemagnetan yang baik dan stabil secara kimia sehingga memenuhi persyaratan pada berbagai aplikasi. Pada penelitian ini, telah dilakukan rekayasa struktur internal material untuk peningkatan sifat kemagnetan material SHF terutama remanen dan koersifitasnya dengan membuat suatu komposit sistem SHF+(a-Fe). Metode yang digunakan dalam preparasi material SHF adalah metode Mechanical Alloying (MA) yang diikuti oleh perlakuan sintering atau pemanasan pada temperatur tinggi mencapai 1100 oC. Sebelum hadirnya partikel a-Fe, material dengan fasa tunggal SrFe12O19 memperlihatkan loop histeresis magnet permanen dengan magnetisasi remanen sebesar ~0,16 T dan koersifitas ~ 350 kA.m-1. Perlakuan sintering dalam suasana steril terhadap material komposit sistem SHF+(a-Fe) baik itu dengan partikel a-Fe berukuran partikel rata-rata dalam orde mikron maupun nanometer yang diterapkan telah menyebabkan dekomposisi dan oksidasi fasa. Kontak antar partikel penyusun komposit telah memfasilitasi oksidasi fasa Fe oleh kandungan atom oksigen yang terdapat dalam fasa utama. Pembentukan fasa oksida Fe berlangsung relatif mudah disertai dekomposisi fasa kaya atom oksigen menjadi fasa minim oksigen Sr2Fe2O5. Sifat kemagnetan material komposit, yang terdiri dari fasa dekomposisi Sr2Fe2O5 dan oksidasi fasa Fe menjadi FeO dan Fe3O4, bersifat magnet lunak.

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Barium or Strontium Hexaferrite (SrFe12O19, SHF) has been widely used as permanent magnets because it has good magnetic properties and chemically stable which are then suitable for various applications. In the current studies we report our recent findings on improvement of magnetic properties especially remanent magnetization and coercivity of composite SHF+(a-Fe) system. The method used in the preparation of SHF material is mechanical alloying (MA) followed by sintering treatments at high temperatures up to 1100 oC. Before the presence of a-Fe particles which was indicated by a single-phase structure material, SrFe12O19 based sample showed a typical permanent magnet hysteresis loop with remanent magnetization of ~ 0.16 T and the coercivity ~ 350 kA.m-1. Although, sintering treatments have been carried out under sterile atmospheres to the composite magnets, the decomposition of SHF and oxidation of a-Fe were unavoidable. The oxidation occurred in composites with a-Fe particles of average particle size in the order of microns and nanometers. Physical contact between the a-Fe particles and SHF was responsible to the effects. As the sintering treatment was applied to the composite, the contact has facilitated the oxidation of Fe phases together with decomposition of SrFe12O19 phase into Sr2Fe2O5 and thus the internal material was enriched with oxygen. It is concluded that the formation of Fe oxides phase within the composite structure is relatively easy that occurred simultaneously with the formation of reduced SrFe12O19 phase and have lead to the new composite structure consisted of Sr2Fe2O5, FeO and Fe3O4. Consequently, the magnetic properties of composite magnets changed from hard to soft. "