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"Metana adalah salah satu dari gas rumah kaca yang berkontribusi sekitar 19%. Metana memiliki potensi pemanasan global 28 kali lebih besar dibandingkan gas karbondioksida. Sehingga, diperlukan suatu metode untuk mengonversi metana menjadi bahan kimia lain yang bermanfaat. Salah satunya adalah dengan oksidasi parsial metana menjadi metanol. Pada penelitian ini, Co3O4/ZSM-5 disintesis melalui dua metode, yaitu Bottom Up dan Top Down, lalu diimpregnasi dengan oksida kobalt dengan variasi persen loading sebesar 2,5, 5, dan 10%. Co3O4/ZSM-5 Bottom Up dan Top Down dikarakterisasi dengan XRD, FTIR, BET, SEM, dan XRF. Katalis yang diperoleh digunakan untuk reaksi oksidasi parsial metana menggunakan batch reactor. Reaksi dilakukan dengan perbandingan feed CH4 : N2 sebesar 0,75 bar : 2 bar, dengan suhu 150oC dan waktu reaksi selama 60 menit. Hasil reaksi menunjukkan bahwa Co3O4/ZSM-5 Bottom Up dengan persen loading 5% menghasilkan persen yield metanol terbesar, yaitu 62,08%. Sedangkan Co3O4/ZSM-5 Top Down dengan persen loading 2,5% menghasilkan persen yield metanol sebesar 0,016%. Variasi waktu dilakukan terhadap Co3O4/ZSM-5 5% Bottom Up dan Co3O4/ZSM-5 2,5% Top Down. Hasil yang diperoleh berupa formaldehida atau tidak terbentuk produk sama sekali, sehingga diketahui bahwa waktu reaksi yang optimum adalah 60 menit, dengan persen loading logam optimum sebesar 5% untuk metode Bottom Up dan 2,5% untuk metode Top Down.

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Methane is one of the greenhouse gases that contributes about 19%. Methane has a global warming potential 28 times greater than carbon dioxide gas. Thus, a method is needed to convert methane into other useful chemicals. One of them is by partial oxidation of methane to methanol. In this study, Co3O4/ZSM-5 was synthesized through two methods, namely Bottom Up and Top Down, then impregnated with cobalt oxide with variations in percent loading of 2,5, 5, and 10%. Co3O4/ZSM-5 Bottom Up and Top Down characterized by XRD, FTIR, BET, SEM, and XRF. The catalyst obtained was used for the partial oxidation of methane using a batch reactor with ratio of feed CH4 : N2 of 0.75 bar: 2 bar, with a temperature of 150o and a reaction time of 60 minutes. The reaction results show that Co3O4/ZSM-5 Bottom Up with a loading 5% produces the largest percentage yield, which is 62.08%. Meanwhile, Co3O4/ZSM-5 Top Down with a loading 2.5% produces yield of 0.016%. Time variations were carried out on Co3O4/ZSM-5 5% Bottom Up and Co3O4/ZSM-5 2.5% Top Down. The results obtained are formaldehyde or no product is formed, so it is known that the optimum reaction time is 60 minutes, with the optimum metal loading percent of 5% for the Bottom Up method and 2.5% for the Top Down method."

"Penelitian-penelitian terkait permodelan pertumbuhan CNT masih menganggap pertumbuhan CNT tersebut konstan terhadap fungsi waktu. Padahal, pertumbuhan CNT tersebut tidak konstan terhadap waktu karena adanya persitiwa deaktivasi katalis. Pada penelitian ini, akan dilakukan variasi komposisi metana dan hidrogen dalam umpan dan juga temperatur operasi untuk melihat pengaruh parameterparameter tersebut terhadap laju pertumbuhan CNT. Fenomena perpindahan yang diwakili oleh penurunan neraca perpindahan massa, energi dan kinetika reaksi tersebut akan disusun menjadi sebuah model dan disimulasi dengan menggunakan software COMSOL Multiphysics sehingga penelitian ini menghasilkan sebuah model laju pertumbuhan daripada CNT sebagai fungsi waktu pada inti aktif katalis Ni/Al2O3.

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Modelling studies related to the growth of CNT still considered that the growth rate of CNT is constant. At the fact, the growth rate of CNT wouldn?t be constant because there is an effect of catalyst deactivation. In this study, we will vary the composition of methane and hydrogen on feed and the temperatur operation to study the effect of that parameters on the CNT growth rate. The transport phenomenon which is represented by differentiation of mass transfer balance, energy and reaction kinetic will be organized to create a model and simulated with the software COMSOL Multiphysiscs so that this study will produce a growth model of CNT as a function of time on Ni/Al2O3 catalyst."

"Reaktor berkatalis pelat sejajar merupakan salah satu reaktor untuk dekomposisi katalitik metana dimana reaktor ini memiliki pressure drop yang rendah serta hasil karbon nanotube yang seragam (well-aligned). Dalam rangka merealisasikan suatu reaktor komersial, diperlukan beberapa informasi mengenai perilaku fluida di dalam reaktor tersebut. Penelitian ini bertujuan untuk mendapatkan informasi mengenai hidrodinamik, pola aliran serta fenomena perpindahan dan mengetahui pengaruh kondisi operasi terhadap kinerja dari reaktor berkatalis pelat sejajar. Dalam penelitian ini akan divariasikan temperatur, laju alir, tekanan serta komposisi umpan untuk melihat pengaruh variabel-variabel tersebut terhadap naiknya pembentukan karbon yang diwakili oleh penurunan konsentrasi metana.

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Parallel-plate-structured-catalyst reactor is one of the reactors for the catalytic decomposition of methane which has low pressure drop and the carbon nanotubes are uniform (well-aligned). In order to build a commercial reactor, we need some information about the behavior of the fluid within the reactor.

This research aimed to obtain information about the hydrodynamics, flow pattern and transport phenomena and the effect of operating conditions on the performance of the reactor. In this study, some variable will be vary such as temperature, flow rate, pressure and composition of the feed to see the impact of these variables to increase the formation of carbon are represented by decrease concentration of methane."

"Gas sintesis (syngas) dari gas bumi merupakan bahan baku masa depan untuk industri energi dan kimia dalam teknologi Gas to Liquid (GTL). Konsep produksi syngas melalui reformasi autotermal ditemukan oleh Lurgi and Haldor Topsoe (1996) untuk mengatasi masalah konsumsi energi dengan cara menggabungkan proses oksidasi dan reformasi kukus metana dalam satu reaktor. Dalam penelitian ini dilakukan pemodelan dan simulasi reaktor unggun tetap untuk reformasi autotermal dengan menggunakan kinetika Xu dan Froment (1989) untuk reformasi Metana dan Ma dkk (1996) untuk oksidasi Metana. Penelitian ini dilakukan karena dalam melakukan desain, optimisasi dan scale-up reaktor perlu dilakukan prediksi dan estimasi untuk mengetahui berbagai parameter yang terlibat dalam sistem sehingga dapat merekayasa sistem pada kondisi yang seefisien mungkin. Validasi model dilakukan dengan data-data eksperimen skala laboratorium (Scognamiglio dkk., 2009) dan simulasi dilakukan dengan bantuan program COMSOL. Hasil validasi pada temperatur 970 K, tekanan 2 atm dan rentang laju alir 2,5x10-4 - 1x10-4 Nm3/s menunjukkan deviasi rata-rata sebesar 0,74% pada konversi Metana dan kesesuaian yang bagus untuk selektivitas produk. Hasil simulasi menunjukkan kondisi optimum yaitu pada laju alir 1x10-4 Nm3/s, tekanan 400 kPa dan rasio S/C = 0 dengan perolehan konversi metana dan yield syngas masing-masing 0,96 dan 0,66.

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Synthesis gas (syngas) from natural gas is a future energy and chemical industry feedstock in Gas To Liquid technology. Syngas production concept via autothermal reforming is found by Lurgi and Topsoe to overcome energy consumption by combining oxidation and steam reforming process in one reactor. In this research, packed bed reactor modeling and simulation conducted for autothermal reforming using kinetics model and parameter suggested by Xu and Froment (1989) for reforming reactions and Ma et al (1996) for oxidation reaction.

This research held because in reactor design, optimization and scale-up, it is necesarry to predict the reactor performance so that the design can be done efficienly. Model validation conducted using laboratory scale experimental data (Scognamiglio et al, 2009) and the simulation aimed by COMSOL Multiphysics software.

The validation result at 970 K, 2 atm, flow range 2,5x10-4 - 1x10-4 Nm3/s shows average deviation 0,74% on methane conversion and good agreement on the product selectivity. The simulation result shows that the optimum condition is at flow rate 1x10-4 Nm3/s, pressure 400 kPa and S/C ratio = 0 with methane conversion and syngas yield attained respectively 0,96 and 0,66."

"[ABSTRAKPemodelan numerik berdasarkan komputasi dinamika fluida (CFD) pada reaktor autothermal diteliti untuk meningkatkan kinerja unit industri gas sintesis dari bahan baku metana. Seluruh reaktor monolit yang dimodelkan memiliki bagian channel dan pelat. Pemodelan Simulasi dilakukan dengan memvariasikan komposisi umpan, temperatur umpan serta tekanan. Hasil simulasi menunjukkan bahwa profil konsentrasi metana dipengaruhi oleh temperatur umpan, rasio umpan dan tekanan gas. Berdasarkan hasil simulasi didapatkan konversi metana dan yield syngas optimal pada temperatur umpan 1200 K , rasio umpan O2/CH4 0,5-0,6 dan tekanan 1 bar.

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ABSTRACTNumerical modeling based on computational fluid dynamics (CFD) in the autothermal reactor unit investigated to improve the performance of industrial gas methane synthesis of raw materials. The whole reactor monolith being modeled has a channel section and plate. Simulation modeling is done by varying the feed composition, feed temperature and pressure. The simulation results show that the methane concentration profile is influenced by the feed temperature, feed ratio and gas pressure. Based on simulation results obtained conversion of methane and syngas yield optimum feed temperature 1200 K, the feed ratio of O2 / CH4 0.5-0.6 and a pressure of 1 bar.;Numerical modeling based on computational fluid dynamics (CFD) in the autothermal reactor unit investigated to improve the performance of industrial gas methane synthesis of raw materials. The whole reactor monolith being modeled has a channel section and plate. Simulation modeling is done by varying the feed composition, feed temperature and pressure. The simulation results show that the methane concentration profile is influenced by the feed temperature, feed ratio and gas pressure. Based on simulation results obtained conversion of methane and syngas yield optimum feed temperature 1200 K, the feed ratio of O2 / CH4 0.5-0.6 and a pressure of 1 bar.;Numerical modeling based on computational fluid dynamics (CFD) in the autothermal reactor unit investigated to improve the performance of industrial gas methane synthesis of raw materials. The whole reactor monolith being modeled has a channel section and plate. Simulation modeling is done by varying the feed composition, feed temperature and pressure. The simulation results show that the methane concentration profile is influenced by the feed temperature, feed ratio and gas pressure. Based on simulation results obtained conversion of methane and syngas yield optimum feed temperature 1200 K, the feed ratio of O2 / CH4 0.5-0.6 and a pressure of 1 bar., Numerical modeling based on computational fluid dynamics (CFD) in the autothermal reactor unit investigated to improve the performance of industrial gas methane synthesis of raw materials. The whole reactor monolith being modeled has a channel section and plate. Simulation modeling is done by varying the feed composition, feed temperature and pressure. The simulation results show that the methane concentration profile is influenced by the feed temperature, feed ratio and gas pressure. Based on simulation results obtained conversion of methane and syngas yield optimum feed temperature 1200 K, the feed ratio of O2 / CH4 0.5-0.6 and a pressure of 1 bar.]"