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"Elektrokatalis OER merupakan komponen penting dalam penyimpanan energi, konversi energi, dan elektrolisis air. Penelitian ini bertujuan untuk mendapat elektrokatalis berbasis BaFe12O19 (BHF) dan BaTiO3(BTO) terdoping nikel dengan komposit polianilina. Material elektrokatalis BaFe12O19 terdoping Ni dibuat melalui teknik kopresipitasi pada suhu 4oC dengan suhu sintering 750oC. Material BaTiO3 terdoping Ni dibuat melalui teknik sinter berbantuan hidrotermal tekanan rendah. Komposit BHF dengan polianilina (PANI) dan BTO dengan polianilina dilakukan dengan teknik polimerisasi in situ. Berdasarkan pengukuran XRD, diperoleh BHF fase tunggal dan ada pengotor Fe2O3 pada BHF terdoping Ni (BHFNi) dan kompositnya dengan PANI. Doping Ni dan komposit PANI meningkatkan volume unit sel dari BHF. BTO fase tunggal diperoleh pada suhu sinter 800oC selama 2 jam, sedangkan pada BTO doping Ni terdapat fase BaCO3 dan pada komposit PANI terdapat pengotor BaSO4. Kinerja elektrokatalis Oxygen Evolution Reaction (OER) dalam medium NaOH meningkat dengan adanya doping Ni dan komposit polianilina pada BHF dan BTO. Campuran BHFNi-BTONi-PANI (25:75) menunjukkan kinerja elektrokatalis OER terbaik dalam medium NaOH berdasarkan parameter nilai densitas arus dan potensial berlebihnya. Sistem redoks Ni3+/2+, Fe4+/3+, Ti4+/3+ dan sistem lokalisasi elektron dalam PANI menjadi faktor yang mempengaruhi kinerja OER yang baik.

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Oxygen Evolution Reaction (OER) electrocatalyst is an important component in energy storage, energy conversion and electrolysis of water. This study was aimed to obtain oxygen evolution reaction electrocatalyst based on BaFe12O19 (BHF), BaTiO3 (BTO), Ni-doped BaFe12O19 (BHFNi), and Ni-doped BaTiO3 (BTONi), and its composite with polyaniline. Electrocatalyst of BHF and BHFNi were synthesized by co-precipitation at 4oC with sintering temperature of 750oC. BTO and BTONi were prepared through a low pressure hydrothermal assisted sintering technique. the polyaniline composites were carried out by in situ polymerization at 0-4oC. A single phase BHF was obtained on undoped BHF, and Fe2O3 impurities were presence on BHFNi and its composite with PANI. Ni doping decrease on cell unit volume of BHF, while PANI composite increases cell unit volume of BHF. Single phase BTO was obtained through sintering at 800oC during 2 hours, while BaCO3 phase was appeared on Ni-doped BTO and BaSO4 was appeared on its PANI composite.

Based on overpotential and charge transfer coefficient, BHF and BTO performances as OER electrocatalytic in the NaOH medium were increased with present nickel and composite of polyaniline. The mixture of BHFNiPANI-BTONiPANI (25:75) shows the best performance of OER electrocatalyst in NaOH medium based on the parameters of current density and overpotential. The Ni3+/2+, Fe4+/3+, Ti4+/3+ redox systems and the electron localization system in PANI are factors that influence the good performance of there OER electrocatalysts"

"ABSTRAKTelah dilakukan Pemeriksaan Biológis Membran Li9f iiisasiEpidermis Dan Dermis Kulit Babi Steril Setelah PerlakuanKimia Dan Radiasi Pada Luka Terbuka Buatan. Membrandibuat dengan alat derniatoirt yang diatur pada ketebalan0,25 mm. Kedua meinbran di rendain dalain larutan natriumhipoklorit 0,2 % selama 30 menit dan setelah dibilas,diliofilisasi. selania 7 jam. Membran kemudian diradiasidengan dosis 25 KGray pada kecepatan 5 KGray perjain.Penieriksaan biologis dilakukan pada luka terbuka yangdibuat pada kelinçi percobaan. Pada punggung tiapkelincidibuat empat huah luka dengan kedalainan hingga paniculuscarnosus. Masing-inasing luka tersebut diperlakukan denganmembran epidermis, menibran dermis, sofratulle sebagai peinbandingdan kasa kontrol. Keberhasilan penyembuhan lukadihitung dengan caa inengukur persentase luas luka yangtinggal pada hari tertentu, dan mengukur kecepatan kontraksiinenurut nietode Billingham-Russel yang diinpdifikasi.Hasil percobaan inenunjukkan bahwa tidak ada perbedaanbenmakna pada rata-rata persentase luas luka yang tinggaldan rata-rata kecepatan kontraksi antara membran liof illsasi.epidermis dan menibran liofjlj.sasj dermis kulit babipada p.0,05.

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ABSTRACTA Biological Examination of Lyophilized Porcine SkinEpidermal And Dermal Membranes After Chemical And IrradiationTreatments On Artificial Open Wound has been carriedout. Membranes were made by dermatxne set at 0.25 mm.After soaking in 0.2% sodium hipochioric for 30 minutesand cleansing with water s these membranes were lyophilizedfor 7 hours and irradiated with dose 25 Kray at rate of 5KGray per hour.Biological examination was carried out on artificialopen wound in white rabbits. Four wokinds with depththrough paniculus carnosus were made on the back of therabbit. Each wound was treated with subsequently epidermlmembrane, dermal membrane, sofratulle and controlgauze. The success of the treatment was measured with thepercentage of the left-wound area on certain observationday and contraction rate according to Billinghaiu-Russe].method.The result of this experiment showed that there isno significant difference f9r the mean percentage of theleft-wound area and the mean contraction rate between porcineskin epidermal membrane and porcine skin dermal membranefor p.0.05

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"Bahaya kimia dari berbagai sumber dan jenis zat kimia sebagian besar memiliki efek akumulasi di dalam tubuh manusia terutama pada masyarakat yang mengonsumsi air mengandung logam berat. Penelitian ini bertujuan untuk mengetahui tingkat risiko pajanan logam berat yang akan menimbulkan gangguan kesehatan terhadap masyarakat. Penelitian ini menggunakan Metode ARKL jenis kajian lapangan dilakukan pemeriksaan di Laboratorium Fisika Kimia Air BBTKLPP Yogyakarta dengan jumlah sampel manusia 110 responden usia dewasa 18-55 tahun dan sampel lingkungan 20 titik mata air. Pengumpulan data terhadap responden melalui wawancara langsung menggunakan kuisioner dan pengukuran antropometri, pada sumber mata air dilakukan pemeriksaan terhadap kandungan Cd dan Pb di Desa Krinjing dan Sewukan bulan Mei-Juni 2019. Konsentrasi Cd dan Pb di Desa Krinjing lebih rendah dibandingkan di Desa Sewukan.Hasil semua kadar logam berat masih di bawah nilai baku mutu sesuai dengan Peraturan Menteri Kesehatan Nomor 492/Menkes/Per/IV/2010 tentang Persyaratan Kualitas Air Minum. Apabila kadar logam berat melebihi dari nilai baku mutu efek yang ditimbulkan mulai dari timbulnya gejala ringan seperti gatal-gatal, batuk, iritasi ringan hingga kanker, mutasi gen bahkan kematian. Dari konsentrasi Cd dan Pb didapatkan intake dan nilai RQ. Risiko ada dan perlu dikendalikan jika RQ>1 dan tidak perlu dikendalikan apabila RQ≤1. Variabel yang terdapat perbedaan proporsi besarnya tingkat risiko terhadap gangguan kesehatan responden adalah variabel berat badan responden dan variabel durasi pajanan pada konsentrasi Cd.Dari hasil penelitian didapatkan 13 responden dengan RQ>1 pada Cd dan 8 responden pada Pb. RQ>1 didapatkan di Desa Sewukan artinya penduduk Desa Sewukan memiliki risiko mengalami gangguan kesehatan akibat pajanan Cd dan Pb pada air minum dibandingkan pada penduduk Desa Krinjing sehingga perlu dilakukan pengelolaan risiko dengan menentukan batas aman konsumsi, melakukan inovasi pengelolaan risiko dengan pendekatan teknologi pengolahan/penyaringan air seperti Teknologi Tepat Guna (TTG) untuk menurunkan kadar logam berat pada sumber air yang mengandung logam berat.

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Most of hazards from various sources and types of chemicals have the accumulation effects in human body, especially in people who consume water containing heavy metals. This study aims at determining the risk level of heavy metal exposure which will cause health problems to the community. This study uses the ARKL Method type of field study which carried out an examination at the Water Chemistry Physics Laboratory of BBTKLPP Yogyakarta. It brings samples of 110 respondents aged 18-55 years and environmental samples of 20 springs. Respondents data is collected through direct interviews using questionnaires and anthropometric measurements. The researcher has an examination onthe content of Cd and Pb at the source of the spring in Krinjing and SewukanVillage in May-June 2019. The concentration of Cd and Pb in Krinjing Village is lower than in Sewukan Village.

The results of all levels of heavy metals are still below the value of quality standards in accordance with the Regulation of the Minister of Health Number 492/Menkes/Per/IV/2010 about Drinking Water Quality Requirements. If the levels of heavy metals exceed the value of the quality standard, it will have very effects from the onset of mild symptoms such as itching, coughing, mild irritation to cancer, gene mutations and even death. From the concentration of Cd and Pb, the intake and RQ values were obtained. Risk exists and needs to be controlled if RQ>1 and does not need to be controlled if RQ≤1. There are variables that have differences in the proportion of to respondents risk level of health problems: the variable weight of the respondent and the variable duration of exposure to the concentration of Cd.

From the results of the study, it is found that 13 respondents with RQ>1 in Cd and 8 respondents in Pb. While, RQ>1 was found in Sewukan Village, which means that the residents of Sewukan Village have a higher risk of health problems due to exposure to Cd and Pb in drinking water compared to Krinjing Village residents. So, the risk management is needed by determining safe consumption limits, innovating risk management with an approacg of water processing/filtering technology such as Appropriate Technology (TTG) to reduce levels of heavy metals in water sources containing heavy metals."