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"This book describes the origins and evolution of the chemical elements we and the cosmos are made of. The story starts with the discovery of the common elements on Earth and their subsequent discovery in space. How do we learn the composition of the distant stars? How did progress in quantum theory, nuclear physics, spectroscopy, stellar structure and evolution, together with observations of stars, converge to provide an incredibly detailed picture of the universe? How does research in the micro-world explain the macro-world? How does progress in one affect the other, or lack of knowledge in one inhibit progress in the other? In short, Shaviv describes how we discovered the various pieces of the jigsaw that form our present picture of the universe, and how we sometimes put these in the wrong place before finding in the right one.En route we meet some fascinating personalities and learn about heated controversies. Shaviv shows how science lurched from one dogma to the next, time and again shattering much of what had been considered solid knowledge, until eventually a stable understanding arose. Beginning with generally accepted science, the book ends in today’s terra incognita of nuclear physics, astrophysics and cosmology. "

"Senyawa kimia yang terkandung dalam kulit batang tumbuhan jawura (Garcinia lateriflora BL ) diekstraksi dengan n-heksana. Senyawa tersebut diisolasi dengan cara kromatografi kolom cepat (flash column chromatography) dengan larutan pengelusi campuran n-heksana : EtOAc, yang polaritasnya dinaikan secara bertahap.Dari fraksi 11-13 diperoleh senyawa GA, kristal jarum berwarna putih, transparan sebanyak 10 mg. Dari fraksi 20-22 diperoleh senyawa GB merupakan kristal jarum berwarna kuning, transparan sebanyak 300 mg.Struktur molekul senyawa GA dan GB ditentukan berdasarkan data spektroskopi (inframerah, FAB-MS, 1H-NMR, 13C-NMR serta spektra dua dimensi) dan difraksi sinar- X. Dari data spektroskopi diketahui, bahwa senyawa GA adalah stigmasterol, dengan rumus molekul C29H46D (8M=412), sedangkan senyawa GB merupakan turunan benzoquinon dengan rumus molekul C33H3809 (BM=578), adalah suatu senyawa Baru yang diberi nama laterimasoton.Daftar pustaka 20 0981-1997)

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Chemical constituents contained in the stem bark of Jawura (Garcinia laterilora BL) were extracted by n-hexane, the compounds were separated and isolated with flash column chromatography using silica gel as the stationary phase, n-hexane and ethyl acetate as the mobile phase.

From 11-13 fraction was given rise GA compound, as white needle crystal, weight 10 mg. And from 20-23 fraction was isolated GB compound as yellow needle crystal, weight 300 mg. The structure of GA and GB were established using spectroscopy data (IR, 1H-NMR, 13C-NMR with 2D and X-ray diffraction).

Based on spectroscopy data the GA compound was identified as stigmasterol with formula molecular C29H480 (Mr = 412), while the GB compound was established as benzoquinon derivative with formula C33H3809 (Mr = 578), the GB compound is a new compound, named laterimasoton."

"Tujuan Mengetahui efektifitas krim EMLA dalam mengurangi kekerapan dan derajat nyeri saat dilakukan pungsi epidural.Metode Up Klinik Acak Ganda Penelitian dilakukan di Insta1asi Bedah Pusat RSCM pada bulan Februari sampai dengan Maret 2006 dengan jumlah sampel 64 pasien dewasa yang menjalani operasi berencana dan anestesia epidural Pasien dibagi secara acak ke dalam 2 kelompok 32 pasien mendapatkan 2 5 gram krim EMLA dioleskan pada daerah L45 90 menit sebelum dilakukan pungsi epidural dan 32 pasien lainnya mendapatkan 20 mg Lidokain infiltrast 2 menit sebelum pungsi epidural Dilakukan pencatatan nilai Visual Analogue Scale dan derajat nyeri secara obyektifsaatjarum epidural mencapai kedalaman 0 5 1 cm dan permukaan kulit dan pada saat engaged Analisa statistik untuk melihat perbedaan kekerapan antara kedua perlakuan menggunakan up Chi Square sedangkan untuk membandingkan derajat nyeri kedua perlakuan menggunakan up Kolmogorov Smirnov.Hasil Tidak terdapat perbedaan yang bermakna secara statistik antara kedua kelompok perlakuan dalam hal kekerapan dan derajat nyeri yang dihasilkan saat pungsi epidural.

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Objective To observe the effectiveness of EMLA cream in reducing the frequency and degree of pain in epidural punctureMethods Non blinded randomized clinical trial The study was conducted at Cipto Mangunkusumo Hospital Central Surgery Room from February until March 2006 to 64 adult patients who went to elective surgery and were planned to be under epidural anesthesia Patients were divided randomly into two groups The EMLA group was consist of thirty two patients rubbed with 25 gram EMLA cream on their L45 area ninety minutes before the epidural puncture began The other thirty two patients was infiltrated with 20 mg Lidocaine two minutes before the epidural puncture. When the epidural needle-puncture reached the depth 0f05 1 cm from the skin surface and when engaged Visual Analogue Scale and degree ofpazn was recorded objectively Chi Square method was performed to identify the frequency difference between the two groups While at the same time Kolmogorov-Smirnov method was also performed to identify the degree of pain difference between the two groups.Conclusion There were no significant statistical differences between the two groups in a matter offrequency and degree ofpazn in epidural puncture"

"Telah dilakukan sintesis dan karakterisasi polimerisasi oksidasi kimia dari monomer pirol menggunakan oksidan amonium persulfat (APS) dalam media pelarut air, melalui teknik polimerisasi emulsi metode batch selama 4 jam dengan kecepatan agitasi 900 rpm dalam temperatur ruang. Surfaktan yang digunakan diantaranya, surfaktan anionik: Sodium dedocyl sulfate (SDS) dan surfaktan nonionik: Nonylphenol Ethoxylate (NP.EO) dengan 10 mol EO. Senyawa PPy dalam penelitian ini berbentuk padatan (serbuk) berwarna hitam. Terbentuknya PPy dapat diindentifikasi berdasarkan hasil spektra FTIR terlihat munculnya serapan puncak polimer konduktif PPy dengan intensitas yang kuat pada bilangan gelombang 3001 cm-1, 1503 cm-1, 1428 cm-1, 1175 cm-1 dan 1087 cm-1. Berdasarkan profil perubahan temperatur dan perubahan warna selama proses polimerisasi terlihat polimerisasi emulsi relatif lebih lama kecepatan reaksinya dibandingkan dengan polimerisasi sedimentasi. Nilai pH sistem reaksi polimerisasi dengan surfaktan lebih tinggi (penambahan larutan SDS pH sistem 3.3) dibandingkan polimerisasi tanpa surfakan (1.8). Nilai konduktifitas (σ) PPy dengan surfaktan lebih tinggi (mencapai 186 kali) dibandingkan tanpa surfaktan. Polimerisasi emulsi menggunakan surfaktan anionik, SDS sangat efektif meningkatkan nilai konduktivitas PPy.

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A conductive Polypyrrole (PPy) has been successfully synthesized and characterized. The PPy was prepared through oxidative chemical polymerization using ammonium persulfate (APS) as an oxidizing agent in aqueous media. Anionic and non-ionic emulsifiers, sodium dodecyl sulfate (SDS), nonylphenol (NP) ethoxylate (EO) with 10 mole EO were respectively used during polymerization to increase the electrical conductivity. In this research is produced PPy which is formed as black powder. The FTIR spectrum of PPy indicates a change in the absorbance peaks of pyrrole monomer, emergence of strong absorbtion peaks specially at 3001 cm-1, 1503 cm-1, 1428 cm-1, 1175 cm-1 and 1087 cm-1 which is indicating the conductive polymer polypyrrole is formed.

Based on color changing and temperature changing during the polimerization process, the reaction rate of emulsion polymerization is shown relatively slower than sedimentation polymerization. The pH value of SDS added solution was 3.3 higher than that of SDS free solution (1.8). The final characteristic of PPy was carry out by measuring the electrical conductivity (σ) value. It is concluded that the presence of surfactant in a polymerization reaction increased the electrical conductivity of PPy (reached 186 times higher) compared with that obtained of emulsifier free solution. Anionic surfactant, SDS is more effective to enhance the electrical conductivity value of PPy."

"Cekungan Jawa Barat Utara terbukti merupakan penghasil hidrokarbon yang cukup besar di Indonesia. Reservoir target merupakan resevoir karbonat formasi baturaja yang diendapkan pada kala Miosen.Pada reservoar karbonat perlu dilakukan karakterisasi untuk mengetahui jenis Fasies,lingkungan pengendapan, kualitas petrofisika dan penyebaran Impedansi Akustik dan penyebaran Porositas dengan parameter berupa analisa thin section dan data core, analisa wireline log, interpretasi seismik dan analisa inversi untuk mengetahui proses Diagenesa porositas, penyebaran porositas zona hidrocarbon dan ketebalan reservoar tersebut untuk mendapatkan informasi reservoar.Data penelitian terdiri dari 412 inline dan 2160 xline seismik tiga dimensi (3D) serta data log sumuran (UI-1,UI-2 dan UI-3). Hasil dari penelitian ini adalah pada lapangan Bimo ditemukan 3 fasies yatu Mudstone,Wackestone dan Packedstone berdasarkan klasifikasi dari dunham, didapatkan pula diagenesa nya adalah dolomitisasi, sementasi, mikritisasi dan disolusi. Sementara lingkungan pengendapannya dalah Lagoon dan Back reef dengan lingkungan diagenesa nya adalah freatik dan pencampuran.Dari klasifikasi Dunham fasies dan lingkungan pengendapan yang ditemukan mengindikasikan lingkungan laut dangkal. Pada analisa petrofisika didapat porositas pada sumur UI-1,UI-2, dan UI-3 yaitu 0.16,0.22 dan 0.2 dengan ketebalan reservoar 3.5, 2 dan 37 ft menunjukan pada sumur UI-3 yang memiliki reservoar yang tebal. Sementara pada nilai AI yaitu 16250-24000  ft/s*gr/cc pada sumur UI-1,18750-23475 ft/s*gr/cc pada sumur UI-2 dan juga 16175 dan 18175 ft/s*gr/CC pada sumur UI-3.Hasil tersebut menunjukan pada litologi karbonat memiliki nilai Impedansi Akustik yang lebih besar daripada litologi shale. Penelitian ini menyimpulkan bahwa zona reservoar dipengaruhi oleh diagenesa dari batuan Karbonat dan juga penyebaran nilai Impedansi Akustik dimana saat Impedansi Akustik kecil porositas besar dikarenakan semakin besar Impedansi Akustik maka nilai densitas batuan semakin besar.

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The North West Java Basin is proven to be a large hydrocarbon producer in Indonesia. With reservoar Carbonate which is a hydrocarbon producer of 60% in the world it is necessary to characterize it to determine the quality of the reservoar. This basin is deposited in baturaja formations in the miocene age. Carbonate reservoars need to be analyzed by analyzing thin section and core data, wireline log analysis, seismic interpretation and inversion analysis to determine the porosity formation process, the spread of hydrocarbon zone porosity and the thickness of the reservoar.The research data consisted of 412 inline and 2160 xline three-dimensional seismic (3D) and well log data (UI-1, UI-2 and UI-3).

The results of this study were found in field Bimo 3 facies of Mudstone, Wackestone and Packestone based on the classification of dunham. Then the diagenesis was obtained as dolomitization, cementation, micritization and dissolution. While the depositional environment is Lagoon and Back Reef with its diagenetic environment is Phreatic and mixing. In petrophysical analysis obtained porosity in wells UI-1, UI-2, and UI-3 namely 0.16.0.22 and 0.2 with reservoar thickness 3.5, 2 and 37 ft while at AI value is 16250-24000 Ft / s * gr / cc at well UI-1,18750-23475 ft / s * gr / cc in wells UI-2 and also 16175 and 18175 Ft / s * gr / CC in well UI-3. This study concludes that the reservoar zone is influenced by the diagenesis of carbonate rocks and also the spread of AI values where when large AI is a large porosity due to large AI feeds, the value of the rock descent is greater."