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"The hydrogenolysis and isomerization of methyloxirane and cis- and trans-2,3-dimethyloxirane were studied on Pt, Pd, and Ni catalysts in static and pulse microreactors. On Pt and Pd catalysts, considerable differences could be demonstrated between the rates of transformation of the cis and trans isomers, whereas on Ni catalyst there was scarcely any difference. It may be assumed that in the transformation of the trans isomer on Pt and Pd catalysts the rate-determining step is the formation of the 1,3-diadsorbed surface species; on the Ni catalyst, however, as in the case of 2-methyloxirane and the cis isomer on any of the three catalysts, the rate-determining step is the further reaction of the adsorbed surface species. The results obtained by the pulse reaction technique are indicative of the irreversible adsorption of the reactants. Besides contributing to the clarification of the mechanisms and stereochemistry of the reactions examined, the data obtained give a possibility for the explanation of the fundamental differences in regioselectivity on the Pt, Pd, and Ni catalysts. On Pt and Pd catalysts, the mechanism of formation of 1,3-diadsorbed surface species differs from the mechanism obtained on Ni catalyst."

"The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade."